Polyoxometalates functioned as ligands: Synthesis and crystal structure of a new hybrid compound constructed from metatungstate and metal complex units

Inorganic Chemistry Communications

Volumn 12, Issue 11, 2009, Pages 1139-1141

  Yan, Bangbo ^a   Li, Yan Fen ^a   Zhao, Hou Yin ^a   Pan, Wei Ping ^a   Parkin, Sean ^b  

^a WESTERN KENTUCKY UNIVERSITY   (United States)

^b UNIVERSITY OF KENTUCKY   (United States)

Author keywords

Crystal structure; Hydrothermal synthesis; Polyoxotungstate; Zinc

Indexed keywords

EID: 70350572903     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.09.009     Document Type: Article

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18. 40 was 3:2:2. The resulting mixture was sealed in a Teflon bag and placed in a 45-mL Teflon-lined autoclave and heated at 120 °C for 72 h. After the autoclave was cooled to room temperature naturally, and the colorless crystals of 1 were filtered, washed with water, and dried in air. Yields: ca. 70% based on W. Anal. Calc. (%) for 1: C, 19.25; H, 1.44; N, 4.49. Found: C, 20.06; H, 1.52; N, 4.40.
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