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70350572133
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note
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4-aminothiophene hydrochloride can be directly copulated on the 4-butyl aniline diazonium salt, the metal group acting as a protector group in the synthesis of the azo bridge. The subsequent second step is again the condensation of this intermediate with 4-formyl-3-hydroxyphenyl 4-(octyloxy)benzoate to produce ligand 2.
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20
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21
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70350571584
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note
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-1, and no Bragg diffraction signal corresponding to any smectic periodicity was observed for lattice distances lower than about 41 Å.
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22
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