A missing link between discrete POMs and the POMs as building blocks in extended structure

Inorganic Chemistry Communications

Volumn 12, Issue 11, 2009, Pages 1124-1127

  Shi, Shu Yun ^a,b   Pan, Cheng Ling ^c   Chen, Yan ^a   Xu, Jia Ning ^a   Cui, Xiao Bing ^a   Wang, Yan ^a   Xu, Ji Qing ^a  

^a JILIN UNIVERSITY   (China)

^b JILIN NORMAL UNIVERSITY   (China)

^c CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

Discrete POMs; Hydrothermal synthesis; Magnetic susceptibility; Missing link; Polyoxometalate; POMs in extended structure

Indexed keywords

EID: 70350565463     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.09.004     Document Type: Article

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32. 2(all data) = 0.1196. the reflection intensity data of the compound 1 were collected on a Bruker Apex II CCD diffractometer equipped with graphite monochromated Mo Kα (λ = 0.71073 Å) radiation at 23 K. All the non-hydrogen atoms except N9, N10 and C51 to C58 were refined anisotropically. The 4,4′-bpy in the compound 1 is disorderedly occupied by two halves bpys (Fig. S1). It should be noted that the positions of Mo5, Mo6 in POM 1 are disorderedly occupied by Mo5, V5 and Mo6, V6 with occupancy factors 0.5, respectively, also the positions of Mo11, Mo12 in POM 2 are disorderedly occupied by Mo11, V11 and Mo12, V12 with occupancy factors 0.5, respectively.
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