Batch experiments versus soil pore water extraction - What makes the difference in isoproturon (bio-)availability?

Chemosphere

Volumn 77, Issue 6, 2009, Pages 756-763

  Folberth, Christian ^a   Suhadolc, Metka ^b   Scherb, Hagen ^a   Munch, Jean Charles ^a   Schroll, Reiner ^a  

^a INSTITUTE OF EPIDEMIOLOGY   (Germany)

^b UNIVERSITY OF LJUBLJANA   (Slovenia)

Author keywords

In situ pesticide sorption; Microbial availability; Saturation of sorption sites; Soil extraction; Soil pore water; TOC

Indexed keywords

BINDING SITES; LINEAR REGRESSION; PESTICIDES; PORE STRUCTURE; RISK ANALYSIS; RISK ASSESSMENT; SOIL SURVEYS; SOILS; SORPTION; WATER;

BATCH EXPERIMENTS; DISTRIBUTION COEFFICIENT; MULTIPLE LINEAR REGRESSION ANALYSIS; SOIL EXTRACTION; SOIL PORE WATERS; SORPTION BEHAVIORS; SORPTION SITES; UNDISTURBED SOILS;

EXTRACTION;

ISOPROTURON;

ADSORPTION; BIOAVAILABILITY; CONCENTRATION (COMPOSITION); CORRELATION; EXPERIMENTAL STUDY; MICROBIAL ACTIVITY; MULTIPLE REGRESSION; PARAMETERIZATION; PESTICIDE; POREWATER; RISK ASSESSMENT; SOIL DEGRADATION; SOIL WATER; TOTAL ORGANIC CARBON; WATER CONTENT;

ADSORPTION KINETICS; ARTICLE; BIOAVAILABILITY; CHEMICAL ANALYSIS; CONTROLLED STUDY; EXTRACTION; INTERMETHOD COMPARISON; SOIL AGGREGATION; SOIL ANALYSIS; SOIL WATER CONTENT;

EID: 70350547762     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2009.08.029     Document Type: Article

References (26)

1. Berger B.M. Factors influencing transformation rates and formation of products of phenylurea herbicides in soil. J. Agric. Food Chem. 47 (1999) 3389-3396
2. Beulke S., Brown C.D., Dubus I.G., Fryer C.J., and Walker A. Evaluation of probabilistic modelling approaches against data on leaching of isoproturon through undisturbed lysimeters. Ecol. Model. 179 (2004) 131-144
3. Boivin A., Cherrier R., and Schiavon M. A comparison of five pesticides adsorption and desorption processes in thirteen contrasting field soils. Chemosphere 61 (2005) 668-676
4. Braida W.J., White J.C., Ferrandino F.J., and Pignatello J.J. Effect of solute concentration on sorption of polyaromatic hydrocarbons in soil: uptake rates. Environ. Sci. Technol. 35 (2001) 2765-2772
5. d) for the herbicides isoproturon and trifluralin in five UK agricultural soils. Environ. Pollut. 132 (2004) 541-552
6. de Lipthay J.R., Sørensen S.R., and Aamand J. Effect of herbicide concentration and organic and inorganic nutrient amendment on the mineralization of mecoprop, 2,4-D and 2,4,5-T in soil and aquifer samples. Environ. Pollut. 148 (2007) 83-93
7. de Wilde T., Mertens J., Spanoghe P., Ryckeboer J., Jaeken P., and Springae D. Sorption kinetics and its effects on retention and leaching. Chemosphere 72 (2008) 509-516
8. Ertli T., Marton A., and Földényi R. Effect of pH and the role of organic matter in the adsorption of isoproturon on soils. Chemosphere 57 (2004) 771-779
9. Folberth C., Scherb H., Suhadolc M., Munch J.C., and Schroll R. In situ mass distribution quotient (iMDQ) - a new factor to compare bioavailability of chemicals in soils?. Chemosphere 75 (2009) 707-713
10. Fouqué-Brouard C.M., and Fournier J.M. Adsorption-desorption and leaching of phenylurea herbicides on soils. Talanta 43 (1996) 1793-1802
11. Hartley D., and Kidd H. The Agrochemicals Handbook. third ed. (1991), The Royal Society of Chemistry Information Services, Cambridge, UK
12. Hawthorne S.B., Grabanski C.B., Martin E., and Miller D.J. Comparisons of Soxhlet extraction, pressurized liquid extraction, supercritical fluid extraction and subcritical water extraction for environmental solids: recovery, selectivity and effects on sample matrix. J. Chromatogr. A 892 (2000) 421-433
13. Johnson A.C., Besien T.J., Bhardwaj C.L., Dixon A., Gooddy D.C., Haria A.H., and White C. Penetration of herbicides to groundwater in an unconfined chalk aquifer following normal soil applications. J. Contam. Hydrol. 53 (2001) 101-117
14. Kah M., and Brown C.D. Changes in pesticide adsorption with time at high soil to solution ratios. Chemosphere 68 (2007) 1335-1343
15. Latawiec A.E., Swindell A.L., and Reid B.J. Environmentally friendly assessment of organic compound bioaccessibility using sub-critical water. Environ. Pollut. 156 (2008) 467-473
16. OECD, 2000. OECD guideline 106 - OECD guideline for the testing of chemicals: adsorption-desorption using a batch equilibrium method.
17. Pignatello J.J. Soil organic matter as a nanoporous sorbent of organic pollutants. Adv. Colloid Interface Sci. 76-77 (1998) 445-467
18. Reid B.J., Jones K.C., and Semple K.T. Bioavailability of persistent organic pollutants in soils and sediments - a perspective on mechanisms, consequences and assessment. Environ. Pollut. 108 (2000) 103-112
19. Ruoss, J. 2005. Einfluss bodenphysikalischer und mikrobiologischer Faktoren auf das Abbauverhalten der Modellchemikalien Benazolin-Ethyl und Benzo(a)pyren in Böden und Methoden zur Steuerung des in-situ-Abbaus. PhD thesis, Technical University of Munich, Germany.
20. Schroll R., Becher H., Dörfler U., Gayler S., Grundmann S., Hartmann H.P., and Ruoss J. Quantifying the effect of soil moisture on the aerobic microbial mineralization of selected pesticides in different soils. Environ. Sci. Technol. 40 (2006) 3305-3312
21. 14C-labelled substances in soil-plant-atmosphere systems under field conditions. Environ. Sci. Technol. 38 (2004) 1537-1544
22. Spark K.M., and Swift R.S. Effect of soil composition and dissolved organic matter on pesticide sorption. Sci. Total Environ. 298 (2002) 147-161
23. Tyess D.L., Shea P.J., and Parkhurst A.M. Mineralization potential of atrazine and degradation intermediates from clustered characteristics in inoculated soils. Soil Sediment Contam. 15 (2006) 87-102
24. Wauchope R.D., Yeh S., Linders J.B.H.J., Kloskowski R., Tanaka K., Rubin B., Katayama A., Kördel W., Gerstl Z., Lane M., and Unsworth J.B. Review - pesticide soil sorption parameters: theory, measurement, uses, limitations and reliability. Pest. Manage. Sci. 58 (2002) 419-445
25. Worrall F., Parker A., Rae J.E., and Johnson A.C. Equilibrium adsorption of isoproturon on soil and pure clays. Eur. J. Soil Sci. 47 (1996) 265-272
26. Xing B., and Pignatello J.J. Competitive sorption between 1,3-dichlorobenzene and 2,4-dichlorophenol and natural aromatic acids in soil organic matter. Environ. Sci. Technol. 32 (1998) 614-619