Effect of carbon dioxide concentrations on asymmetric reduction of ketones with plant-cultured cells

Tetrahedron Letters

Volumn 50, Issue 50, 2009, Pages 7079-7081

  Kojima, Hideo ^a   Okada, Akiko ^a   Takeda, Satomi ^a   Nakamura, Kaoru ^b  

^a Osaka Prefecture University   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; CARBON DIOXIDE; GLUCOSE; KETONE;

ARTICLE; ASYMMETRIC CATALYSIS; ATMOSPHERE; CONTROLLED STUDY; DARKNESS; ENANTIOSELECTIVITY; FLUORESCENT LIGHTING; ILLUMINATION; NONHUMAN; PLANT CELL CULTURE; REDUCTION; TOBACCO;

EID: 70350498731     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2009.10.002     Document Type: Article

References (16)

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6. 2 concentration of global atmosphere is 0.03%.
7. -1).
8. d-l notation was adopted here since methyl and trifluoromethyl ketones were used in this Letter and (R)-configuration of (R)-1-phenyl-2,2,2-trifluoroethanol is the same configuration as (S)-1-phenylethanol by definition.
9. 2 (0.03%, v/v); glucose (1%, v/v); under dark conditions. The reaction mixture was extracted with ether. The chemical yields and ee were obtained from GC-analysis using a Varian Chirasil-DEX-CB (25 m × 0.32 mm) column (100 °C isotherm). The retention times of ketone 2a, the l-alcohol, and the d-alcohol were 1.64 min, 7.89 min, and 8.28 min, respectively.
10. Average data for more than 3-5 times.
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