Rate constants for the reaction of hydronium ions with hydrated electrons up to 350 °C

Radiation Physics and Chemistry

Volumn 79, Issue 1, 2010, Pages 64-65

  Stanisky, Christopher M ^a   Bartels, David M ^a   Takahashi, Kenji ^b  

^a UNIVERSITY OF NOTRE DAME   (United States)

^b KANAZAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

HIGH-TEMPERATURE WATER; HYDRATED ELECTRON; HYDRONIUM IONS;

HYDRATES; HYDRATION; ION SOURCES;

RATE CONSTANTS;

HYDRONIUM ION;

ARTICLE; CHEMICAL REACTION KINETICS; ELECTRON RADIATION; HIGH TEMPERATURE; RADIATION ABSORPTION; WATER TEMPERATURE;

EID: 70350423042     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2009.08.032     Document Type: Article

References (9)

1. Christensen H. Remodeling of the oxidant species during radiolysis of high-temperature water in a pressurized-water reactor. Nuclear Technology 109 3 (1995) 373-382
2. Elliot A.J. Modeling of radiolysis of reactor cooling water-a comparative study. Radiation Physics and Chemistry 36 6 (1990) 863-865
3. Elliot, A.J., 1994. Rate Constants and G-Values for the Simulation of the Radiolysis of Light Water over the Range 0-300 °C. AECL-11073, COG-94-167, AECL, Chalk River, Ontario, CA.
4. Elliot, A.J., Ouellette, D.C., Stuart, C.R., 1996. The Temperature Dependence of the Rate Constants and Yields for the Simulation of the Radiolysis of Heavy Water. AECL-11658, AECL, Chalk River, Ontario, Canada.
5. McCracken, D.R., Rasewych, J.B., Shorter, W.R., 1989. Coolant Radiolysis and Boiling in Water-Cooled Reactors. Water Chemistry of Nuclear Reactor Systems 5, London, BNES.
6. Shiraishi H., Sunaryo G.R., and Ishigure K. Temperature-dependence of equilibrium and rate constants of reactions inducing conversion between hydrated electron and atomic-hydrogen. Journal of Physical Chemistry 98 19 (1994) 5164-5173
7. -, and hydronium ions as a function of temperature from 125 to 380 degrees C. Chemical Physics Letters 357 5-6 (2002) 358-364
8. Takahashi K., Cline J.A., Bartels D.M., and Jonah C.D. Design of an optical cell for pulse radiolysis of supercritical water. Review of Scientific Instruments 71 9 (2000) 3345-3350
9. Takiguchi H., Ullberg M., and Uchida S. Optimization of dissolved hydrogen concentration for control of primary coolant radiolysis in pressurized water reactors. Journal of Nuclear Science and Technology 41 5 (2004) 601-609