Preparation and characterization of poly (N-isopropylacrylamide)/ polyvinylamine core-shell microgels

Colloid and Polymer Science

Volumn 287, Issue 11, 2009, Pages 1339-1346

  Chen, Qiang ^a,b   Xu, Kun ^a   Zhang, Wende ^a   Song, Chunlei ^a   Wang, Pixin ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b HENAN POLYTECHNIC UNIVERSITY   (China)

Author keywords

Core shell microgel; pH sensitive; Temperature sensitive

Indexed keywords

CORE-SHELL MICROGEL; CORE-SHELL MICROGELS; CORE-SHELL MORPHOLOGIES; CROSSLINKED; GRAFT COPOLYMERIZATION; HYDROGEN BONDING INTERACTIONS; INTERMOLECULAR INTERACTIONS; INTRAMOLECULAR INTERACTIONS; METHYLENE BISACRYLAMIDE; MICRO-GELS; MICROGEL; MICROGEL PARTICLES; N-ISOPROPYLACRYLAMIDES; PH SENSITIVE; POLYMER CHAINS; POLYVINYLAMINES; POSITIVELY CHARGED; SEM; TEM IMAGES; TEMPERATURE SENSITIVE; TURBIDITY MEASUREMENTS; ZETA POTENTIAL MEASUREMENTS;

ACRYLIC MONOMERS; AMIDES; BIOMATERIALS; GRAFTING (CHEMICAL); HYDROGEN; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH SENSORS; SURFACE ACTIVE AGENTS; TURBIDITY;

SHELLS (STRUCTURES);

AMINE; N,N' METHYLENEBISACRYLAMIDE; POLY(N ISOPROPYLACRYLAMIDE); POLYVINYLAMINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; CROSS LINKING; HYDROGEN BOND; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; PARTICLE SIZE; PHYSICAL CHEMISTRY; POLYMERIZATION; PRIORITY JOURNAL; TURBIDITY;

EID: 70350376016     PISSN: 0303402X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00396-009-2095-z     Document Type: Article

References (30)

1. Liu RX, Fraylich M, Saunders BR (2009) Thermoresponsive copolymers: From fundamental studies to applications. Colloid Polym Sci 287:627-643
2. Bradley M, Vincent B (2008) Poly(vinylpyridine) core/poly(N -isopropylacrylamide) shell microgel particles: Their characterization and the uptake and release of an anionic surfactant. Langmuir 24:2421-2425
3. Berndt I, Pedersen JS, Richtering W (2006) Temperature-sensitive core-shell microgel particles with dense shell. Angew Chem Int ed 45:1737-1741
4. Berndt I, Popescu C, Wortmann F, Richtering W (2006) Mechanics versus thermodynamics: Swelling in multiple-temperature-sensitive core-shell microgels. Angew Chem Int Ed 45:1081-1085
5. Gan DJ, Lyon LA (2001) Tunable swelling kinetics in core-shell hydrogel nanoparticles. J Am Chem Soc 123:7511-7517
6. Garcia-Salinas MJ, Romero-Ccano MS, Nieves FJ (2002) Colloidal stability of a temperature-sensitive poly(N -isopropylacrylamide/ 2-acrylamido-2-methylpropanesulphonic acid) microgel. J Colloid Interface Sci 248:54-61
7. Kratz K, Lapp A, Eimer W, Hellweg T (2002) Volume transition and structure of triethyleneglycol dimethacrylate, ethylenglykol dimethacrylate, and N, N′-methylene bis-acrylamide cross-linked poly(N-isopropyl acrylamide) microgels: A small angle neutron and dynamic light scattering study. Colloids Surf A 197:55-67
8. Aslan K (2007) Preparation and characterization of N -isopropylacrylamide/acrylic acid copolymer core-shell microgel particles. J Colloid Interface Sci 313:697-704
9. Karg M, Santos IP, González BR, Klitzing RV, Wellert S, Hellweg T (2008) Temperature, pH, and ionic strength induced changes of the swelling behavior of PNIPAM-poly(allylacetic acid) copolymer microgels. Langmuir 24:6300-6306
10. Brazel CS, Peppas NA (1995) Synthesis and characterization of thermo- and chemomechanically responsive poly(N-isopropylacrylamide-co-methacrylic acid) hydrogels. Macromolecules 28:8016-8020
11. Zhou S, Chu B (1998) Synthesis and volume phase transition of poly(methacrylic acid-co- N -isopropylacrylamide) microgel particles in water. J Phys Chem B 102:1364-1371
12. Das M, Kumacheva E (2006) From polyelectrolyte to polyampholyte microgels: Comparison of swelling properties. Colloid Polym Sci 284:1073-1084
13. Zha L, Hu J, Wang C, Fu S, Elaissari A, Zhang Y (2002) Preparation and characterization of poly(N -isopropylacrylamide-co-dimethylaminoethyl methacrylate) microgel latexes. Colloid Polym Sci 280:1-6
14. Loxley A, Vincent B (1997) Equilibrium and kinetic aspects of the pH-dependent swelling of poly(2-vinylpyridine-co-styrene) microgels. Colloid Polym Sci 275:1108-1114
15. Blackburn WH, Lyon LA (2008) Size-controlled synthesis of monodisperse core/shell nanogels. Colloid Polym Sci 286:563-569
16. Xu JJ, Pelton R (2004) A new route to poly(N -isopropylacrylamide) microgels supporting a polyvinylamine corona. J Colloid Interface Sci 276:113-117
17. Xu JJ, Timmons AB, Pelton R (2004) N -Vinylformamide as a route to amine-containing latexes and microgels. Colloid Polym Sci 282:256-263
18. Li X, Zuo J, Guo YL, Yuan XH (2004) Preparation and characterization of narrowly distributed nanogels with temperature-responsive core and pH-responsive shell. Macromolecules 37:10042-10046
19. Li P, Zhu JM, Sunintaboon P, Harris FK (2002) New route to amphiphilic core-shell polymer nanospheres: Graft copolymerization of methyl methacrylate from water-soluble polymer chains containing amino groups. Langmuir 18:8641-8646
20. Li WY, Li P (2007) Synthesis of well-defined amphiphilic core-shell particles containing amine-rich shells. Macromol Rapid Commum 28:2267-2272
21. Kawaguchi H (2000) Functional polymer microspheres. Prog Polym Sci 25:1171-1210
22. Dyer MA, Ainslie KM, Pishko MV (2007) Protein adhesion on silicon-supported hyperbranched poly(ethylene glycol) and poly(allylamine) thin films. Langmuir 23:7018-7023
23. Roth I, Jbarah AA, Holze R, Friedrich M, Spange S (2006) 2-Nitro-1, 4-diaminobenzene-functionalized poly(vinyl amine)s as water-soluble UV-Vis-sensitive pH sensors. Macromol Rapid Commun 27:193-199
24. Chen Q, Liu XG, Yang QB, Xu K, Zhang WD, Song CL, Wang PX (2008) Low cationic proportion ampholytic polymer: Synthesis, solution properties and interaction with anionic surfactant. Polym Bull 60:545-554
25. Liu XG, Xiang S, Yue YM, Su XF, Zhang WD, Song CL, Wang PX (2007) Preparation of poly(acrylamide-co-acrylic acid) aqueous latex dispersions using anionic polyelectrolyte as stabilizer. Colloids Surf A 311:131-139
26. Willet N, Gohy J, Auvray L, Varshney S, Jérôme R, Leyh B (2008) Core-shell-corona micelles by PS-b-P2VP-b-PEO copolymers: Focus on the water-induced micellization process. Langmuir 24:3009-3015
27. Crassous JJ, Rochette CN, Wittemann A, Schrinner M, Ballauff M (2009) Quantitative analysis of polymer colloids by cryo-trasmission electron microscopy. Langmuir 25:7862-7871
28. Crassous JJ, Wittemann A, Siebenburger M, Schrinner M, Drechsler M, Ballauff M (2008) Direct imaging of temperature-sensitive core-shell latexes by cryogenic transmission electron microscopy. Colloid Polym Sci 286:805-812
29. 2O. Colloid Polym Sci 285:293-303
30. 1H NMR studies of poly(N -isopropylacrylamide) gels near the phase transition. Eur Polym J 39:1045-1050