2,2'-(methylimino)bis(N,N-dioctylacetamide) (MIDOA), a new tridentate extractant for technetium(VII), rhenium(VII), palladium(II), and plutonium(IV)

Solvent Extraction and Ion Exchange

Volumn 27, Issue 3, 2009, Pages 378-394

  Sasaki, Yuji ^a   Ozawa, Masaki ^a   Kimura, Takaumi ^a   Ohashi, Kousaburo ^a  

^a JAPAN ATOMIC ENERGY AGENCY   (Japan)

Author keywords

Diamide; MIDOA; Pd; Pu; Re; Solvent extraction; Tc; Tridentate

Indexed keywords

DIAMIDE; MIDOA; PD; PU; RE; TC; TRIDENTATE;

CHROMIUM; CHROMIUM COMPOUNDS; COMPLEXATION; ETHERS; METAL RECOVERY; OXYGEN; PALLADIUM; PALLADIUM COMPOUNDS; PLUTONIUM; RHENIUM; SMELTING; SOLVENTS; TECHNETIUM;

SOLVENT EXTRACTION;

EID: 70350340521     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290902821248     Document Type: Article

References (36)

1. Serrano-Purroy, D.; Baron, P.; Christiansen, B.; Malmbeck, R.; Sorel, C.; Glatz, J.-P. Recovery of minor actinides from HLLW using the DIAMIEX process. Radiochim. Acta 2005, 93, 351-355.
2. Takeuchi, M.; Tanaka, S.; Yamawaki, M. Solvent extraction of Tc(VII) and Re(VII) from nitric acid solution with the mixture of CMPO and TBP. Radiochim. Acta, 1993, 63, 97-100.
3. Pruett, D.J. The solvent extraction behavior of technetium. Radiochim. Acta 1981, 28, 153-157.
4. Suzuki, S.; Tamura, K.; Tachimori, S.; Usui, Y. Solvent extraction of technetium(VII) by cyclic amides. J. Radioanal. Nucl. Chem. 1999, 239, 377-380.
5. Boyd, G.E.; Larson, Q.V. Solvent extraction of heptavalent technetium. J. Phys. Chem. 1960, 64, 988-996.
6. Akopov, G.A.; Kranitsyn, A.P.; Tsarenko, A.F. Effect of uranium(VI) on extraction of technetium and zirconium(IV) by tributyl phosphate. Soviet Radiochemistry, 1990, 31, 681-685.
7. Suzuki, S.; Tachimori, S. Extrcation of Tc(VII) by monoamides in the presence of Zr(IV) and U(VI). Proc. Global 1995, Versaille, France, 2001, 1216-1221.
8. Cuillerdier, C.; Musikas, C.; Hoel, P.; Nigond, L.; Vitart, X. Malonamides as new extrcatants for nuclear waste solutions. Sep. Sci. Technol. 1991, 26, 1229-1244.
9. Maeck, W.J.; Booman, G.L.; Kussy, M.E.; Rein, J.E. Extraction of the elements as quarternary (propyl, butyl, and hexyl) amine complexes. Anal. Chem. 1961, 33, 1775-1780.
10. Souka, N.; Ali, A.S. Tc-Mo extraction by tetraphenyl arsonium from different mineral acid solutions. J. Radioanal. Chem. 1975, 26, 271-277.
11. Korpusov, G.V.; Krylov, Y.S.; Tsalon, S.I. Extraction of technetium by dicyclohexyl-18crown-6. Radiochemistry 1984, 26, 390-392.
12. Landgren, A.; Liljenzin, J-O. Extraction behavior of technetium and actinides in the aliquat-336/nitric acid system. Solvent Extr. Ion Exch. 1999, 17, 1387-1401.
13. Ludwig, R.; Dzung, N.T.K. Solvent extraction of Tc(VII) by calixarenes bearing pyridine groups. J. Nucl. Radiochem. Sci. 2005, 6, 227-231.
14. Kupsch, H.; Koch, H. Solvent extraction of heptavalent technetium, part I: solvent extraction of tetraphenylarsonium pertechnetate and tri-n-octylami-nopertechnetate. Isotopenpraxis 1981, 17, 2-6.
15. Sasaki, Y.; Kitatsuji, Y.; Kimura, T. Highly selective extraction of TcO42, ReO42 and MoO422 by the new ligand, 2,29-(methylimino)bis(N,N-dioctylacetamide) (MIDOA), Chem. Lett. 2007, 36, 1394-1395.
16. Sasaki, Y.; Tachimori, S. Extraction of Actinides(III), (IV), (V) and (VI) and Lanthanides(III) by structurally tailored diamides. Solvent Extr. Ion Exch. 2002,20,21-34.
17. Sasaki, Y.; Kimura, T.; Oguma, K. Solvent extraction of various metals including actinides by bidentate and tridentate diamides. J. Ion Exch. 2007, 18,210-215.
18. Sai, A.; Onuki, A.; Ohashi, K.; Motojima, K.; Yamamoto, K. Specific adsorption of molybdenum(VI) on activated carbon and oxine-impregnated active carbon. Bunseki Kagaku 1981, 30, 804-808.
19. Sai, A.; Ohashi, K.; Motojima, K.; Yamamoto, K. Adsorption behavior of chromium(III, VI) on activated carbon and oxine-impregnated carbon. Bunseki Kagaku 1982, 31, E361-366.
20. Ohashi, K.; Murakami, K.; Yamamoto, K. Adsorption behavior of tungsten(VI) onto active carbon. Bunseki Kagaku 1983, 32, E313-319.
21. Bailer, J.C.; Emelèus, H.J.; Nyholm, S.R.; Trotman-Dickenson, A.F. Comprehensive Inorganic Chemistry, Vol. 3, First Edition; Pergamon Press Ltd.: Oxford, England, 1973.
22. Siddall III, T.H.; Good, M.L. Proton magnetic resonance studies and extraction properties of some simple diamides. J. Inorg. Nucl. Chem. 1967, 29,149-158.
23. Sasaki, Y.; Choppin, G.R. Solvent extraction of Eu, Th, U, Np, and Am with N, N9-dimethyl-N,N9-dihexyl-3-oxapentanediamide and its analogous compounds, Anal. Sci. 1996, 12, 225-230.
24. Sasaki, Y.; Choppin, G.R. Extraction of Np(V) by N,N9-dimethyl-N,N9-dihexyl-3-oxapentanediamide. Radiochim. Acta 1998, 80, 85-88.
25. Gasparini, G. M.; Grossi, G. Long chain distributed aliphaic amides as extracting agents in industrial applications of solvent extraction. Solvent Extr. Ion Exch., 1986, 4, 1233-1271.
26. Sasaki, Y.; Sugo, Y.; Suzuki, S.; Kimura, T. A method for the determination of extraction capacity and its application to N,N,N9,N9-tetraalkylderivatives of diglycolamide-monoamide/n-dodecane media. Anal. Chim. Acta 2005, 543,31-37.
27. 3-n- dodecane system. Solvent Extr. Ion Exch. 2001, 19, 91-103.
28. Jasim, F.; Magee, R.J.; Wilson, C.L. New reagents for the detection of technetium. Talanta 1959, 2, 93-95.
29. Davison, A.; Jones, A.G.; Abrams, M.J. New 2,29-bipyridine and 1,10-phenanthroline oxohalide complexes of technetium(VII). Inorg. Chem. 1981, 20, 4300-4302.
30. Zhu, Z.-X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. Cumulative study on solvent extraction of elements by N,N,N9,N9-tetraoctyl-3-oxapantanedia-mide (TODGA) from nitric acid into n-dodecane, Anal. Chim. Acta 2004, 527, 163-168.
31. Shannon, R.D. Revised effective ionic radii and systematic studies on interatomic distances in halides and chalcogenides. Acta Crystallogr. 1976, A32, 751-767.
32. Schwochau, K.; Pleger, U. Basic coordination chemistry of technetium. Radiochim. Acta 1993, 63, 103-110.
33. Condamines, N.; Musikas, C.; Delmau, L.H. Comparative synergistic (technetium-actinide) extraction chemistry by tributylphosphate and some amide extractants. CEA-CONF-11456, 1993.
34. Lieser, K.H.; Kruger, A.; Singh, R.N. Extraction of Tc(VII) by tri-n-butyl phosphate. Radiochim. Acta 1981, 28, 97-101.
35. Yaita, T.; Herlinger, A.W.; Thiyagarajan, P.; Jensen, M.P. Influence of extractant aggregation on the extraction of trivalent f-element cations by a tetraalkyldiglycolamide. Solvent Extr. Ion Exch. 2004, 22, 553-571.
36. Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA system. Solvent Extr. Ion Exch. 2007, 25, 187-204.