Phase selection and energetics in chiral alkaline earth tartrates and their racemic and Meso analogues: Synthetic, structural, computational, and calorimetric studies

Journal of the American Chemical Society

Volumn 131, Issue 42, 2009, Pages 15375-15386

  Appelhans, Leah N ^a   Kosa, Monica ^b   Radha, A V ^c   Simoncic, Petra ^c   Navrotsky, Alexandra ^c   Parrinello, Michele ^c   Cheetham, Anthony K ^d  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b ETH ZURICH   (Switzerland)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINE EARTH; ELECTRONIC ENERGIES; ENTHALPIES OF SOLUTION; ENTROPIC CONTRIBUTIONS; HIGH TEMPERATURE; HYDROTHERMAL REACTION; KINETIC FACTORS; L-TARTARIC ACIDS; LOW TEMPERATURE PHASIS; LOW TEMPERATURES; MESO-TARTARIC ACID; PHASE SELECTION; PHASE TRANSFORMATION; RELATIVE PHASE; ROOM TEMPERATURE; TARTARIC ACIDS; TEMPERATURE RANGE; THERMODYNAMIC PRODUCTS; THERMODYNAMICALLY STABLE;

BARIUM; CALCIUM; CALCIUM ALLOYS; CALORIMETRY; CRYSTAL STRUCTURE; FARM BUILDINGS; HYDROTHERMAL SYNTHESIS; PHASE STABILITY; STRONTIUM; SYSTEM STABILITY; TEMPERATURE; THERMODYNAMIC STABILITY; THERMODYNAMICS;

TAR;

ALKALINE EARTH METAL; ALKALINE EARTH TARTRATE; BARIUM; CALCIUM; STRONTIUM; TARTARIC ACID; TARTARIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CALORIMETRY; CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ENERGY TRANSFER; ENTHALPY; ENTROPY; HIGH TEMPERATURE; ISOMERIZATION; LOW TEMPERATURE; MATHEMATICAL MODEL; MOLECULAR STABILITY; PHASE TRANSITION; RACEMIZATION; ROOM TEMPERATURE; SYNTHESIS; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 70350331092     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja905690t     Document Type: Article

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