Nutrition labeling: Rapid determination of total trans fats by using internal reflection infrared spectroscopy and a second derivative procedure

JAOCS, Journal of the American Oil Chemists' Society

Volumn 86, Issue 11, 2009, Pages 1037-1045

  Mossoba, Magdi M ^a   Seiler, A ^a,e   Kramer, J K G ^b   Milosevic, V ^c   Milosevic, M ^c   Azizian, H ^d   Steinhart, H ^e  

^a CENTER FOR DRUG EVALUATION AND RESEARCH   (United States)

^b AGRICULTURE AND AGRI FOOD CANADA   (Canada)

^c MeV Photonics   (United States)

^d NIR Technologies   (Canada)

^e UNIVERSITY OF HAMBURG   (Germany)

Author keywords

Attenuated total reflection; Fats and oils; Food labeling; Infrared spectroscopy; Lipid analysis; Lipid chemistry; Trans fat

Indexed keywords

ATTENUATED TOTAL REFLECTION; FATS AND OILS; FOOD LABELING; LIPID ANALYSIS; TRANS FAT;

ACIDS; CHEMICAL BONDS; CHROMATOGRAPHIC ANALYSIS; ELECTROMAGNETIC WAVE REFLECTION; FATTY ACIDS; GAS CHROMATOGRAPHY; INFRARED SPECTROSCOPY; LABELING; NUTRITION; SPECTROSCOPIC ANALYSIS; SPECTRUM ANALYSIS;

OILS AND FATS;

EID: 70350211471     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-009-1444-x     Document Type: Article

References (23)

1. DHHS/FDA (July 11, 2003) Food labeling: trans Fatty acids in nutrition labeling, nutrient content claims, and health claims, 68 Fed. Reg. 41433
2. Citizen petition (1994) Docket No. 1994P-0036/CPI and LET3
3. DHHS/FDA (November 17, 1999) Food labeling: trans Fatty acids in nutrition labeling, nutrient content claims, and health claims, 64 Fed. Reg. 62746
4. Schrimpf-Moss J, Wilkening V (2005) trans Fat-new FDA regulations. In: Kodali DR, List GR (eds) Trans fat alternatives. AOCS Press, Champaign, IL, pp 26-33
5. N Sehat JKG Kramer MM Mossoba MP Yurawecz JAG Roach K Eulitz KM Morehouse Y Ku 1998 Identification of conjugated linoleic acid isomers in cheese by gas chromatography, silver ion-high-performance liquid chromatography and mass spectral reconstructed ion profiles. Comparison of chromatographic elution sequences Lipids 33 963 971 10.1007/s11745-998-0293-8 1:CAS:528: DyaK1cXnsVeru78%3D
6. JC Martin K Valeille 2002 Conjugated linoleic acids: all the same or to everyone its own function? Reprod Nutr Develop 42 525 536 10.1051/rnd:2002042 1:CAS:528:DC%2BD3sXit1ymsbo%3D
7. Ratnayake WMN, Zehaluk C (2005) trans Fatty acids in foods and their labeling regulations. In: Akoh CC, Lai O-M (eds) Healthful lipids. AOCS Press, Champaign, IL, pp 1-32
8. Mossoba MM, Kramer JKG, Delmonte P, Yurawecz MP, Rader JI (2005) Determination of trans fats by gas chromatography and infrared methods. In: Kodali DK, List GR (eds) Trans fats alternatives. AOCS Press, Champaign, IL, pp 47-70
9. American Oil Chemists' Society (AOCS) (1999) Official methods and recommended practices. In: Firestone D (ed) Official method Cd 14d-99, 5th edn. AOCS, Champaign, IL
10. M Adam MM Mossoba T Lee 2000 Rapid determination of total trans fat content by attenuated total reflection infrared spectroscopy: an international collaborative study J Am Oil Chem Soc 77 457 462 10.1007/s11746-000-0074-9 1:CAS:528:DC%2BD3cXjsVKgt7s%3D
11. AOAC International (2000) Official methods of analysis, Method 2000.10,17th edn. AOAC, Gaithersburg, MD
12. MM Mossoba M Adam T Lee 2001 Rapid determination of total trans fat content. An attenuated total reflection infrared spectroscopy international collaborative study J AOAC Int 84 1144 1150 1:CAS:528:DC%2BD3MXlslKrtb0%3D
13. MM Mossoba RE McDonald DJ Armstrong SW Page 1991 Identification of minor C18 triene and conjugated diene isomers in hydrogenated soybean oil and margarine by GC-MI-FTIR spectroscopy J Chromatogr Sci 29 324 330 1:CAS:528:DyaK3MXltlCgsbk%3D
14. MM Mossoba RE McDonald JT Chen DJ Armstrong SW Page 1990 Identification and quantitation of trans-9, trans-12-octadecadienoic acid methyl ester and related compounds in hydrogenated soybean oil and margarines by capillary gas chromatography/matrix isolation/Fourier transform infrared spectroscopy J Agri Food Chem 38 86 92 10.1021/jf00091a016 1:CAS:528:DyaK3cXnsFeqsg%3D%3D
15. MM Mossoba JKG Kramer V Milosevic M Milosevic H Azizian 2007 Interference of saturated fats in the determination of low levels of trans fats (below 0.5%) by infrared spectroscopy J Am Oil Chem Soc 84 339 342 10.1007/s11746-007-1038-4 1:CAS:528:DC%2BD2sXltFClsrk%3D (Pubitemid 46931864)
16. M Milosevic V Milosevic JKG Kramer H Azizian MM Mossoba 2004 Determining low levels of trans fatty acids in foods by an improved ATR-FTIR procedure Lipid Technol 16 252 255 1:CAS:528:DC%2BD2cXhtVGjsL3L
17. JKG Kramer M Hernandez C Cruz-Hernandez J Kraft MER Dugan 2008 Combining results of two GC separations partly achieves determination of all cis and trans 16:1, 18:1, 18:2, 18:3 and CLA isomers of milk fat as demonstrated using Ag-ion SPE fractionation Lipids 43 259 273 10.1007/s11745-007-3143-4 1:CAS:528:DC%2BD1cXjvFegtr4%3D
18. S Satchithanandam CJ Oles CJ Spease MM Brandt MP Yurawecz JI Rader 2004 trans, Saturated, and unsaturated fat in foods in the United States prior to mandatory trans-fat labeling Lipids 39 11 18 10.1007/s11745-004-1195-5 1:CAS:528:DC%2BD2cXhvFOltL8%3D (Pubitemid 38296121)
19. AOCS Official Method Ce 1h-05 (2005) Determination of cis-, trans-, saturated, monounsaturated and polyunsaturated fatty acids in vegetable or non-ruminant animal oils and fats by capillary GLC. AOCS, Champaign, IL
20. MM Mossoba V Milosevic M Milosevic JKG Kramer H Azizian 2007 Determination of total trans fats and oils by infrared spectroscopy for regulatory compliance Anal Bioanal Chem 389 87 92 10.1007/s00216-007-1262-7 1:CAS:528:DC%2BD2sXpsVarsb8%3D (Pubitemid 47325215)
21. D Precht J Molkentin 1997 trans-Geometrical and positional isomers of linoleic acid including conjugated linoleic acid (CLA) in German milk and vegetable fats Fett/Lipid 99 319 326 10.1002/lipi.19970990904 1:CAS:528:DyaK2sXmslamt7g%3D
22. D Precht J Molkentin 2000 Recent trends in the fatty acid composition, of German sunflower margarines, shortening and cooking fats with emphasis on individual C16:1, C18:1, C18:2, C18:3 and C20:1 trans isomers Nahrung 44 222 228 10.1002/1521-3803(20000701)44:4<222::AID-FOOD222>3.0.CO;2-9 1:CAS:528:DC%2BD3cXntFKqsbo%3D
23. D Precht J Molkentin 2003 Overestimation of linoleic acid and trans-C18:2 isomers in milk fats with emphasis on trans 9, trans 12-octadecadienoic acid Milchwissenschaft 58 30 34 1:CAS:528:DC%2BD3sXivVejsbo%3D