Chains of alkaline metal cations and tetracyanidoborato anions - Syntheses, structures and properties of the new [AI(18-crown-6)][B(CN) 4] (AI = Cs, Rb)

European Journal of Inorganic Chemistry

Volumn , Issue 29-30, 2009, Pages 4547-4553

  Bernsdorf, Arne ^a   Köckerling, Martin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Alkali metals; Borates; Crown compounds; Structure elucidation

Indexed keywords

CESIUM COMPOUNDS; CHAINS; CROWN ETHERS; INDIUM COMPOUNDS; NEGATIVE IONS; RUBIDIUM COMPOUNDS;

18-CROWN-6; ALKALINE METAL; COORDINATION CHAINS; CROWN COMPOUNDS; METAL CATION; MONOCLINIC CRYSTAL SYSTEMS; SLOW EVAPORATION; STRUCTURE ELUCIDATION; STRUCTURES AND PROPERTIES; TRANSPARENT CRYSTALS;

POSITIVE IONS;

EID: 70350167207     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900285     Document Type: Article

References (46)

1. G. Wittig, P. Raff, Z. Naturforsch., Teil B 1951, 6, 225-226.
2. H. Landesmann, R. E. Williams, J. Am. Chem. Soc. 1961, 55, 2663-2666.
3. E. Bessler, I Goubeau, Z. Anorg. Allg. Chem. 1967, 352, 67-76.
4. E. Bessler, Z. Anorg. Allg. Chem. 1977, 430, 38-42.
5. E. Bernhardt, G. Henkel, H. Willner, Z. Anorg. Allg. Chem. 2000, 626, 560-568.
6. E. Bernhardt, M. Finze, H. Willner, Z. Anorg. Allg. Chem. 2003, 629, 1229-1234.
7. T Küppers, E. Bernhardt, H. Willner, H.W. Rohm, M. Köckerling, Inorg. Chem. 2005, 44, 1015-1022.
8. M. Berkei, E. Bernhardt, M. Schürmann, M. Mehring, H. Willner, Z. Anorg. Allg. Chem. 2002, 625, 1734-1740.
9. M. Neukirch, S. Tragi, H.-J. Meyer, T. Küppers, H. Willner, Z. Anorg. Allg. Chem. 2006, 632, 939-944.
10. C. Nitschke, M. Köckerling, Z. Anorg. Allg. Chem. 2009, 635, 503-507; and references cited therein.
11. D. Williams, B. Pleune, J. Kouvetakis, M. D. Williams, R. A. Andersen, J. Am. Chem. Soc. 2000, 122, 7735-7741.
12. T. Küppers, M. Köckerling, H. Willner, Z. Anorg. Allg. Chem. 2007, 633, 280-284.
13. a) U. Welz-Biermann, N. V. Ignatiev, E. Bernhardt, M. Finze, H. Willner, Merck Patent GmbH, Darmstadt, WO 2004/ 072089 Al, 2004
14. b) N. V. Ignatiev, U. Welz-Biermann, A. Kuchceryna, G. Bissky, H. Willner, J. Fluorine Chem. 2005, 126, 1150-1159
15. c) D. Kuang, P. Wang, S. Ito, S. M. Zakeeruddin, M. Gräzel, J. Am. Chem. Soc. 2006, 125, 7732-7733.
16. A. Flemming, M. Hoffmann, M. Köckerling, so far unpublished results.
17. M. L. Kuhlmann, H. Yao, T.B. Rauchfuss, Chem. Commun. 2004, 1370-1371.
18. B. H. Hamilton, C. J. Ziegler, Chem. Commun. 2002, 842-843.
19. E. Bernhardt, G. Henkel, H. Willner, G. Pawelke, H. Bürger, Chem. Eur. J. 2001, 7, 4696-4705.
20. M. Finze, E. Bernhardt, A. Terheiden, M. Berkei, H. Willner, D. Christen, H. Oberhammer, F. Aubke, J. Am. Chem. Soc. 2002, 124, 15385-15398.
21. A. Terheiden, E. Bernhardt, H. Willner, F. Aubke, Angew. Chem. 2002, 114, 823-825;
22. Angew. Chem. Int. Ed. 2002, 41, 799-801.
23. J. O. M. Bockris, A. K. N. Reddy, M. Gamboa-Aldeco (Eds.), Modern Electrochemistry: An Introduction to an Interdisciplinary Area, 2nd ed., Kluwer Academic/Plenum Publishers, New York, 2000.
24. a) S. R. Cooper, Crown Compounds - Toward Future Applications, VCH, Weinheim, 1992
25. b) B. Dietrich, P. Viout, J.-M. Lehn, Macrocyclic Chemistry, 1993, VCH, Weinheim
26. c) C. J. Pederson, J. Am. Chem. Soc 1967, 59, 7017-7036
27. d) C. J. Pedersen, H. K. Frensdorff, Angew. Chem. 1972, 84, 16-26;
28. Angew. Chem. Int. Ed. Engl. 1972, 11, 16-25.
29. a) B. Wilde, A. Jaenschke, F. Olbrich, Z. Anorg. Allg. Chem. 2008, 634, 166-172
30. b) J.J. Christensen, D. J. Eatough, R. M. Izatt, Chem. Rev. 1974, 74, 351-384
31. c) E. V. Dehmlow, Angew. Chem. 1977, 89, 521-533;
32. Angew. Chem. Int. Ed. Engl. 1977, 16, 493-505.
33. T. Küppers, E. Bernhardt, C.W. Lehmann, H. Willner, Z. Anorg. Allg. Chem. 2007, 633, 1666-1672.
34. J. D. Dunitz, M. Dobler, P. Seiler, R. P. Phizackerley, Acta Crystallogr., Sect. B 1974, 30, 2733-2738.
35. a) M. Dobler, R. P. Phizackerley, Acta Crystallogr., Sect. B 1974, 30, 2746-2748
36. b) M. Dobler, R. P. Phizackerley, Acta Crystallogr., Sect. B 1974, 30, 2748-2750
37. c) E. D. Glendening, D. Feller, M. A. Thompson, J. Am. Chem. Soc. 1994, 116, 10657-10669
38. d) B. Wilde, A. Jaenschke, F. Olbrich, Z. Anorg. Allg. Chem. 2008, 634, 166-172
39. e) M. Gjikaj, A. Adam, Z. Anorg. Allg. Chem. 2006, 632, 2475-2480
40. f) I. Heldt, T. Borrmann, U. Behrens, Z. Anorg. Allg. Chem. 2003, 629, 1980-1985.
41. a) R. D. Shannon, C.T. Prewitt, Acta Crystallogr., Sect. B 1969, 25, 925-946
42. b) R. D. Shannon, Acta Crystallogr., Sect. A 1976, 32, 751-767.
43. H. Takeuchi, T Arai, I. Harada, J. Mol. Struct. 1986,146, 197-212.
44. Apex-2, vers. 1.6-8, Saint, vers. 6.25a, SADABS- Software for the CCD Detector System, Bruker-Nonius Inc., Madison, WI, 2003.
45. a) G. M. Sheldrick, SHELX97 - Programs for Crystal Structure Analysis (Release 97-2), University of Göttingen, 1997
46. b) G. M. Sheldrick, Acta Crystallogr., Sect. A 2008, 64, 112-122.