Phase transitions in PbZrxHf1-xO3 determined by thermal analysis and impedance spectroscopy

IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control

Volumn 56, Issue 9, 2009, Pages 1799-1805

  De La Rubia, Miguel ^a,b   Alonso, Roberto Emilio ^c   López Garcia, Alberto R ^c   Frutos, Jose De ^a  

^a UNIVERSIDAD POLITÉCNICA DE MADRID   (Spain)

^b INSTITUTO DE CERÁMICA Y VIDRIO   (Spain)

^c FACULTAD DE CIENCIAS EXACTAS   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLINE MATERIALS; HAFNIUM COMPOUNDS; LEAD COMPOUNDS; PEROVSKITE; PHASE DIAGRAMS; THERMOANALYSIS;

COMPLEX IMPEDANCE; COMPOSITION RANGES; CRYSTALLINE STRUCTURE; ELECTRICAL CHARACTERIZATION; IMPEDANCE SPECTROSCOPY; PARTIAL SUBSTITUTION; TEMPERATURE RANGE; WIDE TEMPERATURE RANGES;

ZIRCONIUM COMPOUNDS;

EID: 70350161047     PISSN: 08853010     EISSN: None     Source Type: Journal    
DOI: 10.1109/TUFFC.2009.1252     Document Type: Article

References (23)

1. S . Kim, T. S. Kang, and J. H. Je, "Structural characterization of laser ablated epitaxial (Ba0.5Sr0.5)TiO3 thin films on MgO (001) by synchrotron x-ray scattering," J. Mater. Res., vol.14, no.7, pp. 2905-2911, 1999.
2. N . Singh and D. Pandey, "Diffuse ferroelectric transition and relaxational dipolar freezing in (Ba,Sr)TiO3: II. Role of Sr concentration in the dynamics of freezing," J. Phys. Condens. Matter, vol.8, no.23, pp. 4269-4287, 1996. (Pubitemid 126548057)
3. A . Lopez-Garcia, R. E. Alonso, P. de la Presa, and A. Ayala, "Hyperfine interactions in the Sr0.88Ba0.12HfO3 compound," Hyp. Interac., vol.136/137, no.3-8, pp. 541-547, 1999.
4. A . Lopez-Garcia and R. E. Alonso, "Interacciones cuadripolares en SrZrO3," Bol. Soc. Esp. Ceram. Vidrio, vol.43, no.4, pp. 695-697, 2004. (in Spanish)
5. M . J. Lopez-Robledo, A. R. Pinto Gomez, J. Martinez Fernandez, A. R. de Arellano Lopez, and A. Sayir, "Microestructura y propiedades mecanicas de conductores protonicos de alta temperatura crecidos por fusion de zona flotante," Bol. Soc. Esp. Ceram. Vidrio, vol.43, no.4, pp. 753-758, 2004. (in Spanish)
6. C . J. Howard, K. S. Knight, B. J. Kennedy, and E. H. Kisi, "The structural phase transitions in strontium zirconate revisited," J. Phys. Condens. Matter, vol.12, no.45, pp. L677-L683, 2000.
7. R . E. Alonso, J. de Frutos, M. A. de la Rubia, M. Taylor, and A. R. Lopez-Garcia, "Estudio de la estabilidad de fase en SrZrO3 en funcion de la temperatura de sinterizacion," Bol. Soc. Esp. Ceram. Vidrio, vol.46, no.6, pp. 311-315, 2007. (in Spanish)
8. G. Xu, H. Luo, and Z. Yin, "Third ferroelectric phase in PMNT single crystals near the morphotropic phase boundary composition," Phys. Rev. B, vol.64, no.2, pp. 201021-201023, 2001.
9. M . Glerup, K. S. Knight, and F. W. Poulsen, "High temperature phase transitions in SrSnO3 perovskite," Mater. Res. Bull., vol.40, no.3, pp. 507-520, 2005.
10. C . J. Howard and H. T. Stokesc, "Structures and phase transitions in perovskites-a group-theoretical approach," Acta Crystallogr. A, vol.61, pt. 1, pp. 93-111, Jan. 2005.
11. P . M. Woodward, "Octahedral tilting in perovskites. I. Geometrical considerations. II. Structure stabilizing forces. Acta Crystallogr. A, vol. 53, no. 1, pp. 32-43, 44-66, 1997.
12. D . L. Corker, A. M. Glazer, W. Kaminsky, R. W. Whatmore, J. Dec, and K. Rodeler, "Investigation into the crystal structure of the perovskite lead hafnate PbHfO3," Acta Crystallogr. B, vol.54, pp. 18-28, 1998.
13. G. Shirane, E. Sawaguchi, and Y. Takagi, "Dielectric properties of lead zirconate," Phys. Rev., vol.84, no.3, pp. 476-481, 1951.
14. A . F. Wells, Structural Inorganic Chemistry. London: Oxford University Press, 1950, p. 71.
15. D . F. Weirauch and V. J. Tennery, "Isothermal phase transitions in ceramic lead zirconate," J. Am. Ceram. Soc., vol.53, no.5, pp. 229-232, 1970.
16. R . W. Whatmore and A. M. Glazers, "Structural phase transitions in lead zirconate," J. Phys. C Solid State Phys., vol.12, no.8, pp. 1505-1519, 1979.
17. G. A. Samara, "Pressure and temperature dependence of the dielectric properties and phase transitions of the antiferroelectric perovskites: PbZrO3 and PbHfO3," Phys. Rev. B, vol.1, no.9, pp. 3777-3786, 1970.
18. G. Shirane and R. Pepinsky, "Phase transitions in antiferroelectric PbHfO3," Phys. Rev., vol.91, no.4, pp. 812-815, 1953.
19. J. Kwapulinski, M. Pawelczyk, and J. Dec, "On the Pb thermal vibrations in PbHfO3 crystals," J. Phys. Condens. Matter, vol.6, pp. 4655-4659, 1994.
20. Y . Kuroiwa, H. Fujiwara, A. Sawada, S. Aoyagi, E. Nishibori, M. Sakata, M. Takata, H. Kawaji, and T. Atake, "Distinctive charge density distributions of perovskite-type antiferroelectric oxides PbZrO3 and PbHfO3 in cubic phase," Jpn. J. Appl. Phys., vol.43, 9B, pp. 6799-6802, 2004.
21. G. A. Samara, "A new pressure-induced phase in PbHfO3," Phys. Lett., vol.30A, no.8, pp. 446-447, 1969.
22. Landolt-Bornstein Numerical Data and Functional Relationships in Science and Technology, New York: Springer-Verlag, 1981.vol. 16, Ferroelectrics and Related Substances; subvol. A: Oxides.
23. R. E. Alonso, L. A. Errico, E. L. Peltzer y Blanca, A. Lopez-Garcia, A. Svane, and N. E. Christensen, "Theoretical study of pure and Ta-doped monoclinic hafnia (m-HfO2)," Phys. Rev. B, vol.78, art. no.165206, 2008.