Single-crystal EPR study of Fe3+ and VO2+ in prehnite from the Jeffrey mine, Asbestos, Quebec

Canadian Mineralogist

Volumn 47, Issue 4, 2009, Pages 933-945

  Pan, Yuanming ^a   Mao, Mao ^a   Lin, Jinru ^a  

^a UNIVERSITY OF SASKATCHEWAN   (Canada)

Author keywords

Ferric iron; High spin terms; Jeffrey mine; Layer silicates; Local distortion; Prehnite; Quebec; Single crystal EPR; Site occupancy; VO2+

Indexed keywords

FERRIC IRON; HIGH-SPIN TERMS; JEFFREY MINE; LAYER SILICATES; LOCAL DISTORTION; PREHNITE; QUEBEC; SINGLE-CRYSTAL EPR; SITE OCCUPANCY; VO2+;

ASBESTOS; ELECTRON RESONANCE; HAMILTONIANS; MANGANESE; MANGANESE COMPOUNDS; MINES; MINING; OPTICAL MICROSCOPY; PARAMAGNETIC MATERIALS; PARAMAGNETIC RESONANCE; PARAMAGNETISM; QUANTUM THEORY; SILICATES; SPIN DYNAMICS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

CRYSTAL STRUCTURE; DATA SET; ELECTRON PROBE ANALYSIS; ELECTRON SPIN RESONANCE; OPTICAL PROPERTY; SOROSILICATE; X-RAY DIFFRACTION;

ASBESTOS; CANADA; NORTH AMERICA; QUEBEC [CANADA];

EID: 70350153143     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.47.4.933     Document Type: Article

References (38)

1. 57Fe Mössbauer and X-ray Rietveld studies of ferrian prehnite from Kouragahana, Shimane Peninsula, Japan. J. Mineral. Petrol. Sci. 98, 31-40.
2. Akizuki, M. (1987) : Al, Si order and the internal texture of prehnite. Can. Mineral. 25, 707-716.
3. Angel, B. R., Jones, J. P. E. & Hall, P. L. (1974) : Electron spin resonance studies of doped synthetic kaolinite. I. Clay Minerals 10, 247-255.
4. Artioli, G., Quartieri, S. & Deriu, A. (1995) : Spectroscopic data on coexisting prehnite-pumpellyite and epidotepumpellyite. Can. Mineral. 33, 67-75.
5. 2O. Mol. Phys. 39, 1471-1485.
6. Aumento, F. (1968) : The space group of prehnite. Can. Mineral. 9, 485-495.
7. 3+ in natural kaolinites: new insights from electron paramagnetic resonance spectra fitting at X-and Q-band frequencies. Clays Clay Minerals 47, 605-616.
8. 3+ in kaolinite. Clays Clay Minerals 48, 439-445.
9. Balič-Žunič, T., Ščavničar, S. & Molin, G. (1990) : Crystal structure of prehnite from KomiŽa. Eur. J. Mineral. 2, 731-734.
10. 2O. J. Am. Chem. Soc. 90, 3305-3309.
11. Baur, W. H., Joswig, W., Kassner, D. & Hofmeister, W. (1990) : Prehnite: structural similarity of the monoclinic and orthorhombic polymorphs and their Si/Al ordering. J. Solid State Chem. 86, 330-333.
12. 2+ in Tutton salt. J. Chem. Phys. 40, 2270-2275.
13. 4 at 10K: evidence for large magnitude high spin Zeeman interactions. J. Phys. Chem. Solids 58, 813-820.
14. Detrie, T. A., Ross, N. L., Angel, R. J. & Welch, M. D. (2008) : Crystal chemistry and location of hydrogen atoms in prehnite. Mineral. Mag. 72, 1163-1179.
15. 3+: a sensitive probe for disorder in kaolinite. Clays Clay Minerals 45, 496-505.
16. 3+ EPR spectra in kaolinite. Phys. Chem. Minerals 20, 242-247.
17. Gangi Reddy, N. C., Fayazyddin, S. M., Rama Subba Reddy, R., Siva Reddy, G., Lakshmi Reddy, S., Sambasiva Rao, P. & Jagannatha Reddy, B. (2005) : Characterisation of prehnite by EMPA, Mössbauer, optical absorption and EPR spectroscopic methods. Spectrochim. Acta A62, 71-75.
18. Grant, C. V., Cope, W., Ball, J. A., Maresch, G. G., Gaffney, B. J., Fink, W. & Britt, R. D. (1999) : Electronic structure of the aqueous vanadyl ion probed by 9 and 94 GHz EPR and pulsed ENDOR spectroscopies and density functional theory calculations. J. Phys. Chem. B103, 10627-10631.
19. Grice, J. D. & Williams, R. (1979) : Famous mineral localities: the Jeffrey mine, Asbestos, Québec. Mineral. Rec. 10, 69-80.
20. Kemp, R. C. (1971) : Orthorhombic iron centres in muscovite and phlogopite micas. J. Phys. C: Solid State Phys. 4, L11-L13.
21. 3+ in phlogopite. J. Phys. C, Solid State Phys. 5, 3566-3572.
22. 3+ in muscovite. Phys. Status Solidi B 57, K79-K81.
23. Mao, Mao, Nilges, M. J. & Pan, Yuanming (2009) : EPR and ESEEM studies of radiation-induced defects in apophyllites. Geol. Assoc. Can. - Mineral. Assoc. Can. - Am. Ceophys. Union, Program Abstr.
24. 2 radical in fluorapophyllite. Eur. J. Mineral. 21, 317-324.
25. McGavin, D. G. (1987) : Symmetry constraints on EPR spin-Hamiltonian parameters. J. Magnetic Reson. 74, 19-55.
26. 4. J. Magnetic Reson. 61, 321-332.
27. 3+ and other transition metal ions. Clay Minerals 10, 313-345.
28. 8. J. Chem. Phys. 56, 5205-5213.
29. 3+ in α-quartz: a reexamination of the socalled I centre. J. Chem. Phys. 85, 68-79.
30. Mombourquette, M. J., Weil, J. A. & McGavin, D. G. (1996) : EPR-NMR User's Manual. Department of Chemistry, University of Saskatchewan, Saskatoon, Saskatchewan.
31. Nazarova, G. S., Ostashchenko, B. A., Mitrofanov, V. Ya., Shilova, O. Yu. & Zaripova, L. D. (1990) : Nature of the color of prehnite. Zh. Priklad. Spektrosk. 53, 305-310.
32. Pan, Yuanming, Fleet, M. E., Chen, Ning, Weil, J. A. & Nilges, M. J. (2002) : Site preference of Gd in fluorapatite by single-crystal W-band EPR and X-ray refinement of the structure: a comparative study. Can. Mineral. 40, 1103-1112.
33. 2. Am. Mineral. 52, 974-984.
34. Peng Sze-Tzung, Chou Kung-Du & Tang You-Chi (1959) : The structure of prehnite. Acta Chim. Sinica 25, 56-63.
35. Preisinger, A. (1965) : Prehnit - ein neuer Schichtsilikattyp. Tschermaks Mineral. Petrogr. Mitt. 10, 491-504.
36. Rae, A. D. (1969) : Relationship between the experimental hamiltonian and the point symmetry of a paramagnetic species in a crystal. J. Chem. Phys. 50, 2672-2685.
37. Wares, R. P. & Martin, R. F. (1980) : Rodingitization of granite and serpentinite in the Jeffrey mine, Aasbestos, Quebec. Can. Mineral. 18, 231-240.
38. 2, from the Tieshan iron mineral deposit, central China. Mineral. Mag. 67, 73-77.