Cation exchange reactions of vermiculite with Cu-triethylenetetramine as affected by mechanical and chemical pretreatment

Clays and Clay Minerals

Volumn 57, Issue 4, 2009, Pages 486-493

  Steudel, Annett ^a,b   Weidler, Peter G ^b   Schuhmann, Rainer ^a,b   Emmerich, Katja ^a,b  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Ammonium Acetate; Cation Exchange Capacity; Cu triethylenetetramine; Grinding; Vermiculite

Indexed keywords

AMMONIUM ACETATE; CATION EXCHANGE CAPACITY; CU-TRIETHYLENETETRAMINE; GRINDING; VERMICULITE;

AMMONIUM COMPOUNDS; CALCIUM; CHEMICAL REACTIONS; GRINDING (COMMINUTION); GRINDING (MACHINING); ION EXCHANGERS; METALLIC COMPOUNDS; ORGANIC COMPOUNDS; PARTICLE SIZE; POSITIVE IONS; SILICATE MINERALS; SULFUR COMPOUNDS;

CLAY MINERALS;

ACETATE; CARBONATE; CATION EXCHANGE CAPACITY; COPPER; GRINDING; ION EXCHANGE; IRON OXIDE; PARTICLE SIZE; REACTION KINETICS; SMECTITE; VERMICULITE;

EID: 70350131123     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2009.0570409     Document Type: Article

References (32)

1. Abate, G. and Masini, J.C. (2005) Influence of pH, ionic strength, and humic acid on adsorption of Cd(II) and Pb(II) onto vermiculite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 262, 33-39.
2. Abollino, O., Giacomino, A., Malandrino, M., and Mentasti, E. (2008) Interaction of metal ions with montmorillonite and vermiculite. Applied Clay Science, 38, 227-236.
3. Amman, L., Bergaya, F., and Lagaly, G. (2005) Determination of the cation exchange capacity of clays with copper complexes revisited. Clay Minerals, 40, 441-453.
4. Ballard, D.G.H. and Rideal G.R. (1983) Flexible inorganic films and coating. Journal of Materials Science, 18, 545-561.
5. D'Espinose de la Caillerie, J.-B. and Fripiat, J.J. (1991) Dealumination and aluminum intercalation of vermiculite. Clays and Clay Minerals, 39, 270-280.
6. Emmerich, K. (2000) Die geotechnische Bedeutung des Dehydroxylierungsverhalten quellfahiger Tonminerale. PhD thesis, ETH Zurich, Switzerland, 143 pp.
7. Garrett, W.G. and Walker, G.F. (1960) Swelling of some vermiculite-organic complexes in water. Clays and Clay Minerals, 9, 557-567.
8. Ghabru, S.K., Mermut, A.R., and Arnaud, R.J. St. (1989) Layer-charge and cation-exchange characteristics of vermiculite (weathered biotite) isolated froma Gray Luvisol in northeastern Saskatchewan. Clays and Clay Minerals, 37, 164-172.
9. Graf v. Reichenbach, H. (1966) Anomalien des Kationenaustausches bei Vermiculiten. Zeitschrift für Pflanzenernährung, Dungung und Bodenkunde, 113, 203-213.
10. Jímenez de Haro, M.C., Martínez Blanes, J.M., Poyato, J., Pérez-Rodríquez, J.L. (2004) Effects of mechanical treatment and exchanged cation on the microporosity of vermiculite. Journal of Physics and Chemistry of Solids, 65, 435-439.
11. Konta, J. (1995) Clay and man: clay new material in the service of man. Applied Clay Science, 10, 275-335.
12. Koster, H.M. (1977) Die Berechnung kristallchemischer Strukturformeln von 2:1-Schichtsilikaten unter Berucksichtigung der gemessenen Zwischenschichtladungen und Kationenumtauschkapazitäten, sowie die Darstellung der Ladungsverteilung in der Struktur mittels Dreieckskoordinaten. Clay Minerals, 12, 45-54.
13. Lagaly, G. (1994) Layer charge determination by alkylammoniumions. Pp. 1-46 in: Layer Charge Characteristics of 2:1 Silicate Clay Minerals (A. R. Mermut, editor). Workshop Lectures Series 6, The Clay Minerals Society, Boulder, Colorado, USA.
14. Lagaly, G. (1982) Layer charge heterogeneity in vermiculites. Clays and Clay Minerals, 30, 215-222.
15. Lagaly, G. and Weiss, A. (1969) Determination of the layer charge in mica-type layer silicates. 3rd International Clay Conference, Tokyo, Japan, pp. 62-80.
16. Mackenzie, R.C. (1951) A micromethod for determination of cation-exchange capacity of clay. Journal of Colloid Science, 6, 219-222
17. Maqueda, C., Romero, A.S., Morillo, E., and Pérez-Rodríquez, J.L. (2007) Effect of grinding on the preparation of porous materials by acid-leached vermiculite. Journal of Physics and Chemistry of Solids, 68, 1220-1224.
18. Maqueda, C., Romero, A.S., Morillo, E., Pérez-Rodríquez, J.L., Lerf, A., and Wagner, F.E. (2008) The behaviour of Fe in ground and acid-treated vermiculite from Santa Olalla, Spain. Clays and Clay Minerals, 56, 380-388.
19. Mehra, O.P. and Jackson, M.L. (1960) Iron oxide removal from soils and clays by a dithionite-citrate-systembuffered with sodiumbicarbonate. 7th National Conference on Clays and Clay Minerals, Washington, D.C., USA, pp. 317-327.
20. Meier, L.P. and Kahr, G. (1999) Determination of the cation exchange capacity (CEC) of clay minerals using the complexes of copper(II) ion with triethylenetetramine and tetraethylenepentamine. Clays and Clay Minerals, 47, 386-388.
21. Olis, A.C., Malla, P.B., and Douglas, L.A. (1990) The rapid estimation of the layer charges of 2:1 expanding clays from a single alkylammonium ion expansion. Clay Minerals, 25, 39-50.
22. Osman, M.A. (2006) Organo-vermiculites: synthesis, structure and properties. Platelike nanoparticles with high aspect ratio. Journal of Materials Chemistry, 16, 3007-3013.
23. Pérez-Maqueda, L.A., Caneo, O.B., Poyato, J., and Pérez-Rodríquez, J.L. (2001) Preparation and characterization of micron and submicron-sized vermiculite. Physics and Chemistry of Minerals, 28, 61-66.
24. Pérez-Maqueda, L.A., Jiménez de Haro, M.C., Poyato, J., and Pérez-Rodríquez, J.L. (2004) Comparative study of ground and sonicated vermiculite. Journal of Materials Science, 39 5347-5351.
25. Pérez-Rodríquez, J.L., Carrera, F., Poyato, F., and Pérez-Maqueda, L.A. (2002) Sonication as a tool for preparing nanometric vermiculite particles. Nanotechnology, 13, 382-387.
26. Ramírez-Valle, V., Lerf, A., Wagner, F.E., Poyato, J., and Pérez-Rodríquez, J.L. (2008) Thermal study of polypyrrole complexes with vermiculites of different layer charge. Journal of Thermal Analysis and Calorimetry, 92, 43-51.
27. Rich, C.I. (1961) Calciumdetermination for cation-exchange capacity measurements. Soil Science Society of America Journal, 92, 226-231.
28. Suquet, H., Chevalier, S., Marcilly, C., and Barthomeuf, D. (1991) Preparation of porous materials by chemical activation of the Llano vermiculite. Clay Minerals, 26, 49-60.
29. Temuujin, J., Okada, K., and McKenzie, K.J.D. (2003) Preparation of porous silica fromvermiculite by selective leaching. Applied Clay Science, 22, 187-195.
30. Tributh, H. and Lagaly, G. (1986) Aufbereitung und Identifizierung von Bodenund Lagerstattentonen Teil I - Aufbereitung der Proben imLabor. GIT Fachzeitschrift fur das Laboratorium, 30, 524-529.
31. Wiewióra, A., Pérez-Rodríguez, J.L., Pérez-Rodríguez, J.L., Pérez-Maqueda, L.A., and Drapała, J. (2003) Particle size distribution in sonicated high- and low-charged vermiculites. Applied Clay Science, 24,51-58.
32. Wolters F., Lagaly, G., Kahr, G., Nueesch, R., and Emmerich, K. (2009) A comprehensive characterisation of dioctahedral smectites. Clays and Clay Minerals, 57, 104-114.