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A highly labile compound postulated as [Fe(PF3)4BF] has also been identified spectroscopically: c) P. L. Timms, Acc. Chem. Res. 1973, 6, 118-123.
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A highly labile compound postulated as [Fe(PF3)4BF] has also been identified spectroscopically: c) P. L. Timms, Acc. Chem. Res. 1973, 6, 118-123.
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For recent reviews of transition-metal borylene chemistry see, for example: a
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For recent reviews of transition-metal borylene chemistry see, for example: a) H. Braunschweig, D. Rais, Heteroat. Chem. 2005, 16, 566-571;
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See, for example: a) S. Aldridge, D. L. Coombs, C. Jones, Chem. Commun. 2002, 856-857;
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70350110688
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See the Supporting Information for synthetic and spectroscopic details, and reference [10] for comparative data for a related iron complex
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See the Supporting Information for synthetic and spectroscopic details, and reference [10] for comparative data for a related iron complex.
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33
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70350087821
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As determined by a survey of the Cambridge Structural Database, February 11
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As determined by a survey of the Cambridge Structural Database, February 11, 2009.
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Leigh, G.J.1
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70350095891
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+.
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49
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70350087817
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3) in the dichloromethane reaction solvent.
-
3) in the dichloromethane reaction solvent.
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50
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70350087820
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BF = 265 Hz), see H. Braunschweig, K. Kraft, T Kupfer, K. Radacki, F. Seeler, Angew. Chem. 2008, 120, 5009-5011;
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BF = 265 Hz), see H. Braunschweig, K. Kraft, T Kupfer, K. Radacki, F. Seeler, Angew. Chem. 2008, 120, 5009-5011;
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70350106988
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[25]
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[25]
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53
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41749109209
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DOI: 10.1021/om801215b
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G. A. Pierce, D. Vidovic, D. L. Kays, N. D. Coombs, A. L. Thompson, E. D. Jemmis, S. De, S. Aldridge, Organometallics, DOI: 10.1021/om801215b.
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Organometallics
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Pierce, G.A.1
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De, S.7
Aldridge, S.8
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54
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70350116403
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Although not completely structurally analogous with 1 (which has a type I structure; Scheme 3, CpRu(CO)(μ-CO)}2, type II) was chosen for comparative reactivity studies towards AlCl3, as neither, CpRu(CO)2}2(μ-CO, type I) nor, CpRu(CO, 2(μ-CO)(μ-BF, type II) is known. Attempts to access, CpRu(CO)}2(μ-CO)(μ-BF, from 1 via thermally, pho-tolytically, or chemically initiated CO loss have, to date, met with no success. Thus, while photolysis or reactions with amine oxides do not lead to the isolation of any tractable compounds containing Ru and B, thermolysis of 1 (at 80 8C for ca. 16 days in toluene) rather surprisingly leads to clean generation of difluoroboryl complex 2, as judged by both11B and 19F NMR spectroscopy (see the Supporting Information, Although the nature of accompanying organometallic product(s) could not be definitively established, 2 appears to be the on
-
11B-containing species present in the final reaction solution.
-
-
-
-
55
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0346527903
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For other reports of the coordination of Lewis acids to the oxygen atom of a carbonyl ligand see, for example
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For other reports of the coordination of Lewis acids to the oxygen atom of a carbonyl ligand see, for example: N. E. Kim, N. J. Nelson, D. F. Shriver, Inorg. Chim. Acta 1973, 7, 393-396.
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Inorg. Chim. Acta
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Kim, N.E.1
Nelson, N.J.2
Shriver, D.F.3
|