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+ requires 435.9502:437.9482:439.9464, Δ 1.5 ppm.
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3OD): 7.03 (s, H-6), 4.59 (s, H-12), 4.41 (dd, J = 5.6, 3.4 Hz, H-11), 4.24 (dd, J = 9.8, 5.9 Hz, H-10b), 4.09 (dd, J = 9.7, 3.1 Hz, H-10a), 3.37 (d, J = 14.9 Hz, H-7a), 3.11 (d, J = 14.7 Hz, H-7b).
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15N shifts were referenced to the unified TMS scale with a Ξ ratio of 10.136767.
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2 in diethyl ether (50 μL, 100 μmol) was added. The reaction was left to stir under argon at rt for 45 min and then quenched with 2% AcOH (2 mL) and left overnight.
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