Local and collective motions in precise polyolefins with alkyl branches: A combination of 2H and 13C solid-state NMR spectroscopy

Angewandte Chemie - International Edition

Volumn 48, Issue 25, 2009, Pages 4617-4620

  Wei, Yuying ^a   Graf, Robert ^b   Sworen, John C ^a   Cheng, Chi Yuan ^a   Bowers, Clifford R ^a   Wagener, Kenneth B ^a   Spiess, Hans Wolfgang ^b  

^a UNIVERSITY OF FLORIDA   (United States)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

Defects; Molecular dynamics; NMR spectroscopy; Polymer branching; Polyolefins

Indexed keywords

BRANCH CONTENTS; COLLECTIVE MOTIONS; CRYSTALLINE REGIONS; DRAWABILITY; LINEAR POLYMERS; NMR SPECTROSCOPY; PROCESSABILITY; SOLID-STATE NMR SPECTROSCOPY; TWIST DEFECTS; TWISTING MOTION;

DEFECTS; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE; POLYMERS; POLYOLEFINS; SOLID STATE PHYSICS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 70349992329     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200900377     Document Type: Article

References (30)

1. a) G. Strobl, The Physics of Polymers. 2nd ed., Springer. Berlin, 1997;
2. b) B. G. Sumpter, D. W Noid, G. L. Liang, B. Wunderlich, Adv. Polym. Sci. 1994, 116, 27-72.
3. a) C Piel, P. Starek, J. V. Seppälä, W. Kaminsky, J. Polym. Sci. Part A 2006, 44,1600-1612;
4. b) A. Islam, I. A. Hussein,J. Appl. Polym. Sci. 2006, 700, 5019-5033.
5. a) R. G. Alamo. J. A. Blanco, P. K. Agarwal, J. C Randall, Macromolecules 2003, 36, 1559-1571;
6. b) R. G. Alamo, D.L. VanderHart, M. R. Nyden, L. Mandelkern, Macromolecules 2000, 33, 6094-6105;
7. c) I. A. Hussein, T. Hameed, M. C Williams,J. Appl. Polym. Sci. 2006, 102,1717-1728.
8. K. Schmidt-Rohr. H. W. Spiess, Multidimensional Solid-State NMR and Polymers, Academic Press, London, 1994.
9. a) A. E. Tonelli. NMR Spectroscopy and Polymer Microstructure, Wiley-VCH, Weinheim, 1989;
10. b) R. Born, H. W. Spiess, Macromolecules 1995, 28, 7785-7795.
11. a) E. Boz, A.J. Nemeth, K. B. Wagener, K. Jeon, R. Smith, F. Nazirov. M. R. Bockstaller, R. G. Alamo, Macromolecules 2008, 41, 1647-1653;
12. b) J. A. Smith, K. R. Brzezinska, D.J. Valenti, K. B. Wagener, Macromolecules 2000, 33, 3781-3794;
13. c) J. C. Sworen, J. A. Smith, J. M. Berg, K. B. Wagener, J. Am. Chem. Soc. 2004, 126, 11238-11246.
14. a) H. W Spiess, Colloid Polym. Sci. 1983, 261, 193-209;
15. b) D. Hentschel, H. Sillescu, H. W. Spiess, Macromolecules 1981,14, 1605-1607;
16. c) M. S. Greenfield, A.D. Ronemus. R. L. Void, R. R. Void, P. D. Ellis, T. E. Raidy, J. Magn. Reson. 1987, 72, 89107;
17. d) V. Macho, L. Brombacher, H. W. Spiess, Appl. Magn. Reson. 2001, 20, 405-432.
18. G. Lieser, G. Wegner, J. A. Smith, K. B. Wagener, Colloid Polym. Sci. 2004 , 282, 773-781.
19. S. F. Liu, J. D. Mao, K. Schmidt-Rohr, J. Magn. Reson. 2002,755, 15-28.
20. D. L. Vanderhart, J. Magn. Reson. 1981, 44,117-125.
21. a) K. Schmidt-Rohr, H. W. Spiess, Macromolecules 1991, 24, 5288-5293;
22. b) Y-F. Yao, R. Graf, H. W. Spiess, D. R. Lippits, S. Rastogi, Phys. Rev. E 2007, 76,060801(R);
23. c) Y-F. Yao, R. Graf, H. W. Spiess, S. Rastogi, Macromolecules 2008, 41, 2514-2519;
24. d) Y-F. Yao, R. Graf. H. W. Spiess, S. Rastogi, Macromol. Rapid Commun. 2009, 30, DOI: 10.1002J.marc.200900114.
25. a) M. Mansfield, R. H. Boyd, J. Polym. Sci. Part B 1978, 16, 1227-1252;
26. b) E. B. Sirota, A. B. Herhold, Polymer 2000, 41, 8781-8789:
27. c) H. Kaji. F. Horii, Macromolecules 2007, 40,54205423.
28. a) H. W. Spiess. J. Polym. Sci Part A 2004, 42. 5031-5044:
29. b) E. Helfand, Z. R. Wasserman, T. A. Weber, J. Skolnick, J. H. Runnels, J. Chem. Phys 1981, 75, 4441-4445;
30. c) Y. Y. He, T. R. Lutz, M. D. Ediger, C Ayyagari, D. Bedrov, G. D. Smith, Macromolecules 2004, 37, 5032-5039.