메뉴 건너뛰기




Volumn 48, Issue 34, 2009, Pages 6251-6256

Charge transfer assisted by collective hydrogen-bonding dynamics

Author keywords

Charge transfer; Femtochemistry; Hydrogen bonding dynamics; Solvation dynamics; Time resolved fluorescence

Indexed keywords

APROTIC SOLVENTS; BIOLOGICAL PROCESS; BIPOLAR DISORDER; CONTINUUM DIELECTRIC MODEL; FEMTOCHEMISTRY; FEMTOSECOND SPECTROSCOPY; HYDROGEN BOND NETWORKS; HYDROGEN BONDINGS; HYDROGEN-BONDING DYNAMICS; SOLVATION DYNAMICS; SPECIFIC INTERACTION; TIME-RESOLVED FLUORESCENCE;

EID: 70349944505     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200902340     Document Type: Article
Times cited : (57)

References (46)
  • 12
    • 84891303633 scopus 로고    scopus 로고
    • Eds, J. T. Hynes, J. P. Klinman, H.-H. Limbach, R. L. Schowen, Wiley-VCH, Weinheim
    • Hydrogen-Transfer Reactions (Eds.: J. T. Hynes, J. P. Klinman, H.-H. Limbach, R. L. Schowen), Wiley-VCH, Weinheim, 2007.
    • (2007) Hydrogen-Transfer Reactions
  • 40
    • 21344489300 scopus 로고    scopus 로고
    • The ultrafast solvent inertial relaxation (librational motion) is faster than ca. 100 fs in MeOH and is not fully resolved in our measurements because of the limited instrumental response function of 250 fs; the fractional amplitude of the inertial motion of ACN in this study is appreciably smaller than that reported with a better time resolution.[19] We can estimate the missing component in the solvation dynamics that arises from the inaccessibility of the ultrafast inertial component (≤ 100 fs) by following a method proposed by Fee and Maroncelli (see R. S. Fee, M. Maroncelli, Chem. Phys. 1994, 183, 235, Using an approximation, v̄p(0) ≈ v̄p(abs, v̄p(abs, v̄np(em, where the subscripts p and np denote polar and nonpolarreference spectra, v̄(0) for ACN and MeOH were deduced to be (20600 ±150) cm-1. With this val
    • [19] with the time resolution of ca. 100 fs.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.