Development of a complex method for the determination of actinoides

Journal of Radioanalytical and Nuclear Chemistry

Volumn 281, Issue 3, 2009, Pages 461-465

  Osváth, Sz ^a   Vajda, N ^b   Molnár, Zs ^b  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

^b RadAnal Ltd   (Hungary)

Author keywords

Actinoides; Ammonium peroxodisulfate; Extraction chromatography; UTEVA

Indexed keywords

ACTINIDE; AMERICIUM 241; CALCIUM OXALATE; CURIUM; FERRIC HYDROXIDE; NEPTUNIUM 237; PHOSPHINE OXIDE DERIVATIVE; PLUTONIUM 238; PLUTONIUM 239; PLUTONIUM 240; POTASSIUM BROMATE; RADIOISOTOPE; SODIUM NITRITE; TRIBUTYL PHOSPHATE; URANIUM 234; URANIUM 235; URANIUM 238;

ARTICLE; CHROMATOGRAPHY; CONTROLLED STUDY; OXIDATION; PRECIPITATION; RADIOACTIVE WASTE; RADIOCHEMISTRY;

EID: 70349938008     PISSN: 02365731     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10967-009-0028-4     Document Type: Article

References (15)

1. Wolf, S.F.: Trace analysis of actinides in geological, environmental, and biological matrices. In: Morss, L.R., Edelstein, N.M., Fuger, J. (eds.) The Chemistry of the Actinide and Transactinide Elements, vol. 5, 3rd edn, p. 3273. Springer, Dordrecht (2006)
2. C-S Kim C-K Kim P Martin U Sansone 2007 Determination of Pu isotope concentrations and isotope ratio by inductively coupled plasma mass spectrometry: a review of analytical methodology J. Anal. At. Spectrom. 22 827 841 10.1039/b617568f 1:CAS:528:DC%2BD2sXntFOhur0%3D (Pubitemid 47324832)
3. Vajda N., Molnár Zs., Osváth Sz.: Use of UTEVA for the separation of Th, U, Np and Pu, EiChrom Users' Group Meeting, Vienna, Austria. www.eichrom.com (2002)
4. Vajda, N., Molnár, Zs., Kabai, É., Osváth, Sz.: Simultaneous determination of long-lived radionuclides in environmental samples. In: Warwick, P. (ed.) Environmental Radiochemical Analysis II, p. 185. The Royal Society of Chemistry, Cambridge (2003)
5. Z Varga G Surányi N Vajda Z Stefánka 2007 Rapid sequential determination of americium and plutonium sediment and soil samples by ICP-SFMS and alpha spectrometry Radiochim. Acta. 95 81 87 10.1524/ract.2007.95.2.81 1:CAS:528:DC%2BD2sXjtlWjtrY%3D
6. EP Horwitz ML Dietz H Diamond AM Essling D Graczyk 1992 Separation and preconcentration of uranium from acidic media by extraction chromatography Anal. Chim. Acta. 266 25 37 10.1016/0003-2670(92)85276-C 1:CAS:528:DyaK38Xmt1GgsLo%3D
7. N Vajda A Törvényi G Kis-Benedek CK Kim 2009 Development of extraction chromatographic separation procedures for the simultaneous determination of actinides Radiochim. Acta. 97 9 16 10.1524/ract.2009.1574 1:CAS:528:DC%2BD1MXitlCrsrw%3D
8. CW Sill 1987 Precipitation of actinides as fluorides or hydroxides for high resolution α-spectrometry Nucl. Chem. Waste Manag. 7 201 215 10.1016/0191-815X(87)90066-0 1:CAS:528:DyaL1cXmsVektw%3D%3D (Pubitemid 18010457)
9. Ward M., Welch G. A.: The oxidation of americium to the hexavalent state. J. Chem. Soc. 4038-4039 (1954)
10. Vajda N., Molnár Zs., Kabai É., Zagyvai P.: Radiochemical determination of long-lived radionuclides in environmental samples. In: II Eurasian Conference on Nuclear Science and its Applications, Presentations, vol. 3, p. 312. Almaty, Kazakhstan, (2002)
11. S Röllin UB Eklund K Spahiu 2001 Separation of actinide redox species with cation exchange chromatography and its application to the analysis of spent fuel leaching solutions Radiochim. Acta. 89 757 763 10.1524/ract.2001.89.11-12.757
12. LA Currie 1968 Limits for quantitative detection and quantitative determination Anal. Chem. 40 586 593 10.1021/ac60259a007 1:CAS:528: DyaF1cXnsVyitQ%3D%3D
13. Vajda, N., Molnár, Zs., Osváth, Sz.: Extraction chromatography and liquid scintillation counting for the analyses of long-lived radionuclides. In: Chalupnik, S., Schönhofer, F., Noakes, J. (eds.) LSC 2005, Advances in Liquid Scintillation Spectrometry, Radiocarbon, p. 251. University of Arizona, Tucson, Arizona (2006)
14. Osvath Sz., Vajda N., Molnar Zs.: Determination of long-lived radionuclides in medium and low level radioactive wastes, The 15th International Conference on Nuclear Engineering (ICONE-15), Nagoya, Japan (2007)
15. Sz Osváth N Vajda Zs Molnár 2008 Determination of long-lived Nb isotopes in nuclear power plant wastes Appl. Radiat. Isot. 66 24 27 10.1016/j.apradiso.2007.07.007 1:CAS:528:DC%2BD2sXhtlahtLjL (Pubitemid 350087669)