A crystalline germanate with mesoporous 30-ring channels

Journal of the American Chemical Society

Volumn 131, Issue 40, 2009, Pages 14128-14129

  Ren, Xiaoyan ^a   Li, Yi ^a   Pan, Qinhe ^a   Yu, Jihong ^a   Xu, Ruren ^a   Xu, Ying ^b  

^a JILIN UNIVERSITY   (China)

^b University of Georgia   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MESOPOROUS; NET STRUCTURES; OPEN-FRAMEWORK MATERIALS; RING CHANNELS; SOLVOTHERMAL CONDITIONS;

CRYSTALLINE MATERIALS;

GERMANIUM;

GERMANATE OXIDE JLG 12; GERMANIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; POROSITY;

CRYSTALLIZATION; GERMANIUM; MODELS, MOLECULAR;

EID: 70349935323     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja902413j     Document Type: Article

References (34)

1. (a) Davis, M. E. Chem. - Eur. J. 1997, 3, 1745-1750.
2. (b) Cheetham, A. K.; Férey, G.; Loiseau, T. Angew. Chem., Int. Ed. 1999, 38, 3268-3292.
3. (c) Davis, M. E. Nature 2002, 417, 813-821.
4. (d) Sun, J.; Bonneau, C.; Cantín, Á.; Corma, A.; Díaz-Cabañas, M. J.; Moliner, M.; Zhang, D.; Li, M.; Zou, X. Nature 2009, 458, 1154-1157.
5. (a) Yang, G.-Y.; Sevov, S. C. J. Am. Chem. Soc. 1999, 121, 8389-8390.
6. (b) Guillou, N.; Gao, Q.; Forster, P. M.; Chang, J.-S.; Noguès, M.; Park, S.-E.; Férey, G.; Cheetham, A. K. Angew. Chem., Int. Ed. 2001, 40, 2831-2834.
7. (c) Lin, C.-H.; Wang, S.-L.; Lii, K.-H. J. Am. Chem. Soc. 2001, 123, 4649-4650.
8. (a) Liang, J.; Li, J.; Yu, J.; Chen, P.; Fang, Q.; Sun, F.; Xu, R. Angew. Chem., Int. Ed. 2006, 45, 2546-2548.
9. (b) Lai, Y.-L.; Lii, K.-H.; Wang, S.-L. J. Am. Chem. Soc. 2007, 129, 5350-5351.
10. (a) Plévert, J.; Gentz, T. M.; Laine, A.; Li, H.; Young, V. G.; Yaghi, O. M.; O'Keeffe, M. J. Am. Chem. Soc. 2001, 123, 12706-12707.
11. (b) Tang, L.; Dadachov, M. S.; Zou, X. Chem. Mater. 2005, 17, 2530-2536.
12. (c) Zhou, Y.; Zhu, H.; Chen, Z.; Chen, M.; Xu, Y.; Zhang, H.; Zhao, D. Angew. Chem., Int. Ed. 2001, 40, 2166-2168.
13. (d) Lin, Z.-E.; Zhang, J.; Zhao, J.-T.; Zheng, S.-T.; Pan, C.-Y.; Wang, G.-M.; Yang, G.-Y. Angew. Chem., Int. Ed. 2005, 44, 6881-6884.
14. (e) Zou, X.; Conradsson, T.; Klingstedt, M.; Dadachov, M. S.; O'Keeffe, M. Nature 2005, 437, 716-719.
15. (f) Christensen, K. E.; Bonneau, C.; Gustafsson, M.; Shi, L.; Sun, J.; Grins, J.; Jansson, K.; Sbille, I.; Su, B.-L.; Zou, X. J. Am. Chem. Soc. 2008, 130, 3758-3759.
16. (a) Gier, T. E.; Bu, X.; Feng, P.; Stucky, G. D. Nature 1998, 395, 154-157.
17. (b) Corma, A.; Díaz-Cabañas, M. J.; Martínez- Triguero, J.; Rey, F.; Rius, J. Nature 2002, 418, 514-517.
18. (a) Li, H.; Eddaoudi, M.; Richardson, D. A.; Yaghi, O. M. J. Am. Chem. Soc. 1998, 120, 8567-8568.
19. (b) Pan, Q.; Li, J.; Ren, X.; Wang, Z.; Li, G.; Yu, J.; Xu, R. Chem. Mater. 2008, 20, 370-372.
20. (c) Pan, Q.; Li, J.; Christensen, K. E.; Bonneau, C.; Ren, X.; Shi, L.; Sun, J.; Zou, X.; Li, G.; Yu, J.; Xu, R. Angew. Chem., Int. Ed. 2008, 47, 7868-7871.
21. (a) Attfield, M. P.; Al-Ebini, Y.; Pritchard, R. G.; Andrews, E. M.; Charlesworth, R. J.; Hung, W.; Masheder, B. J.; Royal, D. S. Chem. Mater. 2007, 19, 316-322.
22. (b) Li, H.; Eddaoudi, M.; Yaghi, O. M. Angew. Chem., Int. Ed. 1999, 38, 653-655.
23. (c) Bu, X.; Feng, P.; Stucky, G. D. Chem. Mater. 2000, 12, 1505-1507.
24. (a) Medina, M. E.; Gutiérrez-Puebla, E.; Monge, M. A.; Snejko, N. Chem. Commun. 2004, 2868-2869.
25. (b) Xu, Y.; Cheng, L.; You, W. Inorg. Chem. 2006, 45, 7705-7708.
26. (a) O'Keeffe, M.; Eddaoudi, M.; Li, H.; Reineke, T.; Yaghi, O. M. J. Solid State Chem. 2000, 152, 3-20.
27. (b) Férey, G. J. Solid State Chem. 2000, 152, 37-48.
28. (c) Férey, G.; Mellot-Draznieks, C.; Loiseau, T. Solid State Sci. 2003, 5, 79-94.
29. Christensen, K. E.; Shi, L.; Conradsson, T.; Ren, T.; Dadachov, M. S.; Zou, X. J. Am. Chem. Soc. 2006, 128, 14238-14239.
30. 1.73 (X = OH, F). Calcd (wt%): C, 11.27; H, 3.15; N, 4.38; TG, 24.10. Found (wt%): C, 12.17; H, 3.20; N, 4.66; TG, 23.98.
31. 2O (1.0 mL) and 2-methylpentamethylenediamine (MPMD, Dytel A, Sigma-Aldrich, 5.0 mL) with constant stirring. Then, 1,2-diaminopropane (1,2-PDA, 1.0 mL) and HF (40 wt %, 0.12 mL) were added to this mixture. A homogeneous gel was formed after stirring for ∼2 h. The gel was finally transferred to a 15-mL Teflon-lined stainless-steel autoclave and heated at 170°C for 12 days under static conditions. Colorless needle-shaped single crystals of JLG-12 were separated by filtration, washed with distilled water, and then dried in air. JLG-12 can also be obtained in the absence of 1,2-PDA. The addition of 1,2-PDA favored the formation of larger single crystals.
32. 1 = 0.0938 for reflections with I > 2σ(I) and 0.1436 for all reflections.
33. Blatov, V. A.; Delgado-Friedrichs, O.; O'Keeffe, M.; Proserpio, D. M. Acta Crystallogr., Sect. A 2007, 63, 418-425.
34. RCSR homepage at http://rcsr.anu.edu.au/.