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11x = axial nitrogen, tpp = dianion of mesotetraphenylporphyrin, ttp = «i<;j'o-tetra-/Molylporphyrin, oep = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin, 1-MeIm = 1-methylimidazole, kryptofix-222 or 222 = 4,7,13,16,21,24-hexaoxo-1,10-diazabicyclo[8.8.8] hexacosane
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11x = axial nitrogen, tpp = dianion of mesotetraphenylporphyrin, ttp = «i<;j'o-tetra-/Molylporphyrin, oep = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin, 1-MeIm = 1-methylimidazole, kryptofix-222 or 222 = 4,7,13,16,21,24-hexaoxo-1,10-diazabicyclo[8.8.8] hexacosane.
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2[Fe(ttp)(CN),]. and 723547 [K(222)][Fe(tpp)CN(l-Melm)] contain the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallography Data Centre via www. ccdc.cam.ac.uk/data-request/cif.
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Comparisons of the structures of the two spin-crossover polymorphic forms at four temperatures between 100 and 400 K is given in the Supporting Information
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This value is observed at 400K; however, the spin-state transition is likely to be not quite complete. In polymorph 2, this Fe-CN distance is 2.068(4) Â at 400 K (see the Supporting Information)
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