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Volumn 48, Issue 27, 2009, Pages 5010-5013

Comparison of cyanide and carbon monoxide as ligands in iron(II) porphyrinates

Author keywords

Cyanides; Iron; M ssbauer spectroscopy; Porphyrinoids; Structure elucidation

Indexed keywords

AS-LIGANDS; CO COMPLEXES; PORPHYRINOIDS; SIX-COORDINATE COMPLEX; SPIN-CROSSOVER COMPOUNDS; STRUCTURE ELUCIDATION;

EID: 70349929351     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901434     Document Type: Article
Times cited : (34)

References (41)
  • 3
    • 0002099182 scopus 로고
    • Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty, Pergamon, Oxford, UK
    • A. G. Sharpe, Comprehensive Coordination Chemistry, Vol.2 (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon, Oxford, UK, 1987, pp. 7-14.
    • (1987) Comprehensive Coordination Chemistry , vol.2 , pp. 7-14
    • Sharpe, A.G.1
  • 10
    • 70349958671 scopus 로고    scopus 로고
    • 11x = axial nitrogen, tpp = dianion of mesotetraphenylporphyrin, ttp = «i<;j'o-tetra-/Molylporphyrin, oep = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin, 1-MeIm = 1-methylimidazole, kryptofix-222 or 222 = 4,7,13,16,21,24-hexaoxo-1,10-diazabicyclo[8.8.8] hexacosane
    • 11x = axial nitrogen, tpp = dianion of mesotetraphenylporphyrin, ttp = «i<;j'o-tetra-/Molylporphyrin, oep = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin, 1-MeIm = 1-methylimidazole, kryptofix-222 or 222 = 4,7,13,16,21,24-hexaoxo-1,10-diazabicyclo[8.8.8] hexacosane.
  • 11
    • 70349960516 scopus 로고    scopus 로고
    • The unexpectedly lower ligand field strength of cyanide in this complex has been highlighted: M. Nakamura, Angew. Chem. 2009,121, 2676;
    • (2009) Angew. Chem. , vol.121 , pp. 2676
    • Nakamura, M.1
  • 13
    • 70349962217 scopus 로고    scopus 로고
    • 2[Fe(ttp)(CN),]. and 723547 [K(222)][Fe(tpp)CN(l-Melm)] contain the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallography Data Centre via www. ccdc.cam.ac.uk/data-request/cif.
  • 14
    • 70349938537 scopus 로고    scopus 로고
    • Comparisons of the structures of the two spin-crossover polymorphic forms at four temperatures between 100 and 400 K is given in the Supporting Information
    • Comparisons of the structures of the two spin-crossover polymorphic forms at four temperatures between 100 and 400 K is given in the Supporting Information.
  • 28
    • 70349946119 scopus 로고    scopus 로고
    • This value is observed at 400K; however, the spin-state transition is likely to be not quite complete. In polymorph 2, this Fe-CN distance is 2.068(4) Â at 400 K (see the Supporting Information)
    • This value is observed at 400K; however, the spin-state transition is likely to be not quite complete. In polymorph 2, this Fe-CN distance is 2.068(4) Â at 400 K (see the Supporting Information)
  • 41
    • 70349927632 scopus 로고
    • Eds.: A. B. P. Lever, H. B. Gray, VCH Publishers, New York, chap. 2
    • P. Debrunner in Iron Porphyrins Part 3 (Eds.: A. B. P. Lever, H. B. Gray), VCH Publishers, New York, 1983, chap. 2.
    • (1983) Iron Porphyrins Part 3
    • Debrunner, P.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.