2-Norbornyl ion-pair leakage in electrophilic addition of HCl to nortricyclene and norbornene

Organic Letters

Volumn 11, Issue 20, 2009, Pages 4684-4687

  Kong, Jing ^a,b   Roy, Debjanl ^b   Lenoir, Dieter ^c   Zhang, Xiangwen ^a   Zou, Ji Jun ^a   Von Schleyer, Paul Ragué ^a,b  

^a TIANJIN UNIVERSITY   (China)

^b UNIVERSITY OF GEORGIA   (United States)

^c INSTITUTE OF EPIDEMIOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 70349909554     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol901984x     Document Type: Article

References (28)

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19. Numerous exploratory computations at various theoretical levels: B3LYP/6-311+G(3df,2p), M052X/6-311+G(d,p), and MP2/6-31G(d) were generally consistent with the B3LYP/6-311+G(d,p) data reported in this paper. See the Supporting Information for further details.
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28. 1Cl dihedral angle, which was constrained incrementially in 10° steps from the 75° in 5 to the 175° in 7. The resulting, partially optimized intermediate geometries are given in the Supporting Information.