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Crystal data for TCA: triclinic, P1, a, 17.1909(3, b, 17.5114(3, c, 17.5337(3) Å, α, 60.1413(4, ß, 77.3032(6, y, 84.4332(3)o, V= 4465.21(13) Å3, Z, 6, T.=173K, F, 000, 1572, pcalcd, 1.108 gcm-3. μ(MOKA, 0.076 mm-1 (λ, 0.71069 Ǻ, 30154 measured reflections, 16882 independent reflections (Rint, 0.0341, 1000 refined parameters, R1, 0.0691, wR2, 0.1868 for 8941 reflections with I>2σ(I, GOF= 1.030. The diffuse electron density due to the disordered and unidentified moieties was treated with SQUEEZE routine within the PLATON software package A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, C34, The void is listed at the end of each of the crystal information files, TCA·methanol, trigonal, P3
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2 = 0.1909 for 4391 reflections with I>2σ(Γ), GOF = 1.011. CCDC 713783,713784,713785,713786 and 713787 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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