A study on the equilibrium reaction of benzaldehyde and sodium bisulphite by in situ Fourier transform IR spectroscopy

Periodica Polytechnica Chemical Engineering

Volumn 53, Issue 1, 2009, Pages 9-12

  Sallay, Péter ^a   Szilágyi, Nikolett ^a   Csontos, István ^a   Keglevich, György ^a  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

Benzaldehyde sodium bisulphite adduct; Equilibrium; In situ Fourier transform IR spectroscopy; Monitoring

Indexed keywords

FOURIER TRANSFORM INFRARED SPECTROSCOPY; SODIUM; ALDEHYDES; EQUILIBRIUM CONSTANTS;

BENZALDEHYDE - SODIUM BISULPHITE ADDUCT; CONDITION; EQUILIBRIA CONSTANTS; EQUILIBRIUM; EQUILIBRIUM REACTIONS; FOURIER TRANSFORM IR SPECTROSCOPY; IN SITU FOURIER TRANSFORM IR SPECTROSCOPY; SODIUM BISULFITE; IN-SITU; SODIUM BISULPHITE;

EQUILIBRIUM CONSTANTS; FOURIER TRANSFORMS;

EID: 70349835941     PISSN: 03245853     EISSN: 15873765     Source Type: Journal    
DOI: 10.3311/pp.ch.2009-1.02     Document Type: Article

References (10)

1. Ende D J, Preigh M J, Process optimization with in situ technologies, Current Opinion in Drug Discovery & Development 3 (2000), 699-706.
2. Keglevich G, Csontos I, Novák T, Mucsi Z, Marosi G, Greiner I;, Monitoring of esterifications by in situ Fourier transformation spectroscopy, Magyar Kémiai Folyóirat 112 (2006), 114-116.
3. Pintar A, Batista J, Levec J, In situ Fourier transform infrared spectroscopy as an efficient tool for determination of reaction kinetics, Analyst 127 (2002), 1535-1540, DOI 10.1039/b207204a.
4. Rein A J, SPIE - Optically Based Methods for Process Analysis, Vol. 1681, 1992.
5. Sheridan R E, Rein A J, FTIR system reveals secrets of chemical processes, R&D Magazine 33 (1991), 100-102.
6. Yamagiwa N, Abiko Y, Sugita M, Tian J, Matsunaga S, Shibasaki M, Catalytic asymmetric cyano-phosphorylation of aldehydes using a YLi(3)tris(binaphthoxide) complex (YLB), Tetrahedron: Asymmetry 17 (2006), 566-573.
7. Keglevich G, Csontos I, Szilágyi N, Greiner I, A study of the pH dependence of the two-step oximation of acetone by in situ Fourier transform infrared spectroscopy, Chemical Engineering Technology 31 (2008), 421-425, DOI 10.1002/ceat.200700448.
8. Keglevich G, Csontos I, Szilágyi N, Monitoring the pH-dependent oximation of methyl ethyl ketone and benzaldehyde by in situ Fourier transform IR spectroscopy in a heterogeneous liquid - liquid two-phase system, Spectroscopy Letters 42 (2009), 67-72, DOI 10.1080/00387010802428476.
9. 3 - Na2S2O5 + H2O: a spectroscopic and calorimetric investigation, Journal of Chemical Thermodynamics 37 (2005), 187-199, DOI 10.1016/j.jct.2004.08.011.
10. Olson T M, Boyce S D, Hoffmann M R, Kinetics, thermodynamics, and mechanism of the formation of benzaldehyde-S(IV) adducts, Journal of Physical Chemistry 90 (1986), 2482-2488, DOI 10.1021/j100402a043.