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Volumn 48, Issue 17, 2009, Pages 3137-3140

A different approach to enantioselective organic synthesis: Absolute asymmetric synthesis of organometallic reagents

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; ENANTIOSELECTIVE; HIGH SELECTIVITY; N-CHLOROSUCCINIMIDE; NEW APPROACHES; OPTICAL ACTIVITY; OPTICALLY ACTIVE; ORGANIC SYNTHESIS; ORGANOMETALLIC REAGENT; PROOF OF CONCEPT; STARTING MATERIALS; SYMMETRY-BREAKING;

EID: 70349786463     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200806222     Document Type: Article
Times cited : (46)

References (32)
  • 1
    • 70349948691 scopus 로고    scopus 로고
    • B. L. Feringa, R. A. Van Delden, Angew. Chem. 1999, 111, 3624; Angew. Chem. Int. Ed. 1999, 38, 3418;
    • (a) B. L. Feringa, R. A. Van Delden, Angew. Chem. 1999, 111, 3624; Angew. Chem. Int. Ed. 1999, 38, 3418;
  • 5
    • 70349971523 scopus 로고    scopus 로고
    • K. Penzien, G. M. J. Schmidt, Angew. Chem. 1969, 81, 628; Angew. Chem. Int. Ed. Engl. 1969, 8, 608;
    • (a) K. Penzien, G. M. J. Schmidt, Angew. Chem. 1969, 81, 628; Angew. Chem. Int. Ed. Engl. 1969, 8, 608;
  • 14
    • 70349954800 scopus 로고    scopus 로고
    • M. Vestergren, B. Gustafsson, O. Davidsson, M. Håkansson, Angew. Chem. 2000, 112, 3577; Angew. Chem. Int. Ed. 2000, 39, 3435;
    • (a) M. Vestergren, B. Gustafsson, O. Davidsson, M. Håkansson, Angew. Chem. 2000, 112, 3577; Angew. Chem. Int. Ed. 2000, 39, 3435;
  • 16
    • 70349956510 scopus 로고    scopus 로고
    • A conglomerate forms when the two enantiomers in a racemic solution crystallize separately. A conglomerate is thus a mechanical (often, but not necessarily, racemic) mixture of enantiopure crystals
    • A conglomerate forms when the two enantiomers in a racemic solution crystallize separately. A conglomerate is thus a mechanical (often, but not necessarily, racemic) mixture of enantiopure crystals.
  • 21
    • 70349956511 scopus 로고    scopus 로고
    • M. Marigo, S. Bachmann, N. Halland, A. Braunton, K. A. Jørgen-sen, Angew. Chem. 2004, 116, 5623; Angew. Chem. Int. Ed. 2004, 43, 5507.
    • c) M. Marigo, S. Bachmann, N. Halland, A. Braunton, K. A. Jørgen-sen, Angew. Chem. 2004, 116, 5623; Angew. Chem. Int. Ed. 2004, 43, 5507.
  • 23
    • 70349950504 scopus 로고    scopus 로고
    • Crystal data for (5)-l (similar for (R)-1, 0.3 × 0.2 × 0.2 mm, C30H28N2Zn, Mr, 481.9, orthorhombic, space group P21212 1(No.19, a, 10.647(2, b, 12.387(2, c, 18.395(2) Å, V= 2426.1(5)Å3, Z, 4, pcaled, 1.319 gcm-1, μ, 1.032 mm-1. Refinement on F 2 for 308 parameters gave R1, 0.019 and wR2, 0.047 for all 4341 reflections. Crystal data for rac-1: 0.3 × 0.2x0.2 mm, C30H28N2Zn, Mr, 481.9, monoclinic, space group P3/4 /c (No. 14, a, 11.992(2, b, 11.196(2, c, 17.859(2) Å, ß, 91.953(6)°, V, 2396.5(5) Å3, Z, 4, ρcaled, 1.336 gcm-1, μ, 1.045 mm-1. Refinement on F 2 fo
    • 2 for 308 parameters gave R1 = 0.032 and wR2 = 0.075 for all 4122 reflections.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.