Acetylene oligomerization with metallocene catalysts and triethylaluminum: The peculiar course of the aufbau reaction with acetylene

Organometallics

Volumn 28, Issue 19, 2009, Pages 5722-5732

  Karpiniec, Samuel S ^a   McGuinness, David S ^a   Patel, Jim ^b   Davies, Noel W ^c  

^a UNIVERSITY OF TASMANIA   (Australia)

^b CSIRO   (Australia)

^c UNIVERSITY OF TASMANIA   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN GROWTH; CHAIN TERMINATIONS; CHAIN TRANSFER; DIHYDROGEN; EARLY TRANSITION METALS; HIGH CONCENTRATION; LANTHANIDES; METALLOCENE CATALYST; METALLOCENES; TRIETHYLALUMINUM;

ACETYLENE; ALUMINA; ALUMINUM; CATALYSIS; CATALYSTS; LIGHTING; OLIGOMERIZATION; OLIGOMERS; ORGANOMETALLICS; RARE EARTH ELEMENTS; TRANSITION METALS;

OPTICAL SENSORS;

EID: 70349776361     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9005438     Document Type: Article

References (30)

1. Stewart, L. Oilfield Rev. 2003, Autumn, 32.
2. Hall, K. R.; Akgerman, A.; Anthony, R. G.; Eubank, P. T.; Bullin, J. A.; Cantrell, J. G.; Weber, B. R.; Betsill, J. APPEA J. 2002, 59.
3. Hall, K. R. Catal. Today 2005, 106, 243.
4. Chauser, M. G.; Rodionov, Y. M.; Misin, V. M.; Cherkashin, M. I. Russ. Chem. Rev. 1976, 45, 348.
5. Natta, G.; Mazzanti, G.; Corradini, P. Atti Accad, Nazi Lincei Rend. Classe Sci. Fis. Mat. Nat. 1958, 25, 3.
6. Feast, W. J.; Tsibouklis, J.; Pouwer, K. L.; Groenendaal, L.; Meijer, E. W. Polymer 1996, 37, 5017.
7. Ito, T.; Shirakawa, H.; Ikeda, S. J. Polym. Sci., Polym. Chem. Ed. 1974, 12, 11.
8. Reppe, W.; Schlichting, O.; Klager, K.; Toepel, T. Justus Liebigs Ann. Chem. 1948, 560, 1.
9. Winter, M. J. In The Chemistry of the Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; John Wiley and Sons: New York, 1985; Vol. 3, p 259.
10. Trimm, D. L.; Liu, I. O. Y.; Cant, N. W. J. Catol. Catal. A 2008, 288, 63.
11. St. Clair, M.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1991, 10, 525.
12. Heeres, H. J.; Teuben, J. H. Organometallics 1991, 10, 1980.
13. Heeres, H. J.; Heeres, A.; Teuben, J. H. Organometallics 1990, 9, 1508.
14. Straub, T.; Haskel, A,; Eisen, M. S. J. Am. Chem.Soc. 1995, 117, 6364.
15. Haskel, A.; Straub, T.; Dash, A. K.; Eisen, M. S. J. Am. Chem. Soc. 1999, 121, 3014.
16. Haskel, A.; Wang,J. Q.; Straub,T.; Neyroud, T. G.; Eisen, M. S. J. Am. Chem. Soc. 1999, 121, 3025.
17. Karpiniec, S.; McGuinness, D.; Patel, J.; Davies, N. Chem.Eur. J. 2009, 15, 1082.
18. Alt, H. G.; Engelhardt, H. E.; Rausch, M. D.; Kool, L. B. J. Organomet. Chem. 1987, 329, 61.
19. Ohff, A.; Burlakov, V. V.; Rosenthal, U. J. Mol. Catal. A 1996, 108, 119.
20. Wilke, G.; Müller, H. Justus Liebigs Ann. Chem. 1960, 629, 222.
21. Ziegler, K. Angew. Chem. 1952, 64, 323.
22. 3.
23. 2O quench). This again suggests that secondary condensation reactions do become significant at higher aluminum concentrations.
24. Hyla-Kryspin, I.; Gleiter, R. J. Mol. Catal. A 2000, 160, 115.
25. Budzelaar, P. H. M.; Talarico, G. Struct. Bonding (Berlin) 2003, 105, 141.
26. 11 formation, see: Thomas, D.; Peulecke, N.; Burlakov, V. V.; Heller, B.; Baumann, W.; Spannenberg, A.; Kempe, R.; Rosenthal, U.; Beckhaus, R. Z. Anorg. Allg. Chem. 1998, 624, 919.
27. Negishi, E.-i.; Kondakov, D. Y.; Choueiry, D.; Kasai, K.; Takahashi, T. J. Am. Chem. Soc. 1996, 118, 9577.
28. Maginn, R. E.; Manastyrskyj, S.; Dubeck, M. J. Am. Chem. Soc. 1963, 85, 672.
29. Evans, W. J.; Meadows, J. H.; Wayda, A. L.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc 1982, 104, 2008.
30. Herrmann, W. A. Synthetic Methods of Organometallic and Inorganic Chemistry; Georg Thieme Verlag: New York, 1997; Vol. 6.