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26
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70349770664
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2. The depiction of the lowest unoccupied MO in Scheme 1 omits, for clarity, the small metal-based atomic orbital contribution
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2. The depiction of the lowest unoccupied MO in Scheme 1 omits, for clarity, the small metal-based atomic orbital contribution.
-
-
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29
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70349774337
-
-
- = 2- diphenylphosphinobenzenethiolate), which undergoes ligand-based reactions with alkenes. See ref 4e
-
- = 2- diphenylphosphinobenzenethiolate), which undergoes ligand-based reactions with alkenes. See ref 4e.
-
-
-
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30
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70349770662
-
-
3).
-
3).
-
-
-
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31
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70349775604
-
-
3).
-
3).
-
-
-
-
33
-
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70349770659
-
-
-3, 11 556 reflections collected, of which 3437 were independent, GOF= 1.038, Rl = 0.0429 [data with I > 2a(I)], wR2 = 0.0856 (all data).
-
-3, 11 556 reflections collected, of which 3437 were independent, GOF= 1.038, Rl = 0.0429 [data with I > 2a(I)], wR2 = 0.0856 (all data).
-
-
-
-
34
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0001735673
-
-
2 have some thioketone character, it is relevant that free diarylthioketones undergo hetero-DielsAlder additions with 1,3-dienes (likely concerted for very reactive dienes but apparently stepwise for less reactive dienes)
-
2 have some thioketone character, it is relevant that free diarylthioketones undergo hetero-DielsAlder additions with 1,3-dienes (likely concerted for very reactive dienes but apparently stepwise for less reactive dienes): Wilker, S.; Erker, G. J. Am. Chem. Soc. 1995, 117, 10922.
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(1995)
J. Am. Chem. Soc.
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, pp. 10922
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Wilker, S.1
Erker, G.2
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36
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0041327982
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(a) Masdeu-Bultó, A. M.; Diéguez, M.; Martin, E.; Gómez, M. Coord. Chem. Rev. 2003, 242, 159.
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Masdeu-Bultó, A.M.1
Diéguez, M.2
Martin, E.3
Gómez, M.4
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