Internally consistent thermodynamic data for magnesium sulfate hydrates

Geochimica et Cosmochimica Acta

Volumn 73, Issue 22, 2009, Pages 6805-6815

  Grevel, Klaus Dieter ^a,b,c   Majzlan, Juraj ^a,b  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b UNIVERSITY OF FREIBURG   (Germany)

^c RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ENTHALPY; EXPERIMENTAL MINERALOGY; EXPERIMENTAL STUDY; MAGNESIUM; RELATIVE HUMIDITY; SULFATE GROUP; TEMPERATURE EFFECT; THERMODYNAMIC PROPERTY;

EID: 70349750222     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2009.08.005     Document Type: Article

References (42)

1. 2O). Am. Mineral. 94.
2. Altheide T., Chevrier V., Nicholson C., and Denson J. Experimental investigation of the stability and evaporation of sulfate and chloride brines on Mars. Earth Planet. Sci. Lett. 282 (2009) 69-78
3. 2O system to 440 K. J. Chem. Eng. Data 43 (1998) 791-806
4. 2O. J. Petrol. 27 (1986) 1331-1364
5. 2O (Rozenit). Acta Cryst. 15 (1962) 815-826
6. Baur W.H., and Rolin J.L. Salt hydrates: IX. The comparison of the crystal structure of magnesium sulfate pentahydrate with copper sulfate pentahydrate and magnesium chromate pentahydrate. Acta Cryst. B28 (1972) 1448-1455
7. Chatterjee N. D. (1991) Applied Mineralogical Thermodynamics - Selected Topics. Springer-Verlag, Berlin, Heidelberg, XVI+321 p.
8. Chipera S.J., and Vaniman D.T. Experimental stability of magnesium sulfate hydrates that may be present on Mars. Geochim. Cosmochim. Acta 71 (2007) 241-250
9. 2O. Astrobiology 3 (2003) 619-630
10. Chou I.-M. and Seal R. R. II (2007) Magnesium and calcium sulfate stabilities and the water budget of Mars. J. Geophys. Res. - Planets 112, article No. E11004, 10p. doi:10.1029/2007JE002898.
11. Chou I.-M., Seal II R.R., and Hemingway B.S. Determination of melanterite-rozenite and chalcanthite-bonattite equilibria by humidity measurements at 0.1 MPa. Am. Mineral. 87 (2002) 108-114
12. 2O. J. Am. Chem. Soc. 77 (1955) 3935-3938
13. DeKock C.W. Thermodynamic properties of selected metal sulfates and their hydrates. U.S. Bur. Mines Inf. Circ. 9081 (1986) 59p
14. Ferraris G., Jones D.W., and Yerkess J. Refinement of crystal structure of magnesium sulfate heptahydrate (epsomite) by neutron diffraction. J Chem. Soc.-Dalton Trans. 8 (1973) 816-821
15. Frost G.B., Breck W.G., Clayton R.N., Reddoch A.H., and Miller C.G. The heat capacities of the crystalline and vacuum dehydrated form of magnesium sulphate monohydrate. Can. J. Chem. 35 (1957) 1446-1453
16. Giauque W.F., and Stout J.W. The entropy of water and the third law of thermodynamics. The heat capacity of ice from 15 to 273 K. J. Am. Chem. Soc. 58 (1936) 1144-1150
17. Gopal E. S. R. (1966) Specific heats at low temperatures. Int. Cryog. Monog. Ser. 3, Heywood, London, X + 240 p.
18. Greenspan L. Humidity fixed points of binary saturated aqueous solutions. J. Res. Nat. Bur. Stand. - Phys. Chem. 81A (1977) 89-96
19. 2O. Habilitation thesis (partly in German), Dept. for Geosciences, Ruhr-University Bochum, Germany, VII+113p.
20. 2O fluid mixtures at high pressures and at temperatures above 400 °C. Eur. J. Mineral. 4 (1992) 1303-1310
21. 2O at 0-303 K. Geochem. Int. 45 (2007) 206-209
22. Haar L., Gallagher J.S., and Kell G.S. NBS/NRC Steam Tables. Thermodynamic and Transport Properties and Computer Programs for Vapor and Liquid States of Water in SI Units (1984), Hemisphere Publishing Company, Washington D.C. 320p
23. Haida O., Matsuo T., Suga H., and Seki S. Calorimetric study of the glassy state. X. Enthalpy relaxation at the glass-transition temperature of hexagonal ice. J. Chem. Thermodyn. 6 (1974) 815-825
24. 2O, a titanite-group mineral. N. Jb. Mineral.-Abh. 157 (1987) 121-132
25. Ko H.C., and Daut G.E. Enthalpies of formation of α- and β-magnesium sulfate and magnesium sulfate monohydrate. U.S. Bur. Mines Rpt. Invest. 8409 (1979) 8p
26. Larson A. C. and Von Dreele R. B. (1994) GSAS general structure analysis system. LANSCE, MS-H805, Los Alamos, New Mexico.
27. Linke W. F. (1965) Solubilities - inorganic and metal-organic compounds; a compilation of solubility data from the periodical literature, vol. 2, fourth ed. Am. Chem. Soc., Washington D.C.
28. 2O, by X-ray powder diffraction and the charge flipping method. Am. Mineral. 94, 622-625.
29. 3). Am. Mineral. 88 (2003) 846-854
30. Moore G.E., and Kelley K.K. The specific heats at low temperatures of anhydrous sulfates of iron, magnesium, manganese, and potassium. J. Am. Chem. Soc. 64 (1942) 2949-2951
31. 2O. Geochim. Cosmochim. Acta 51 (1987) 2429-2443
32. Parker V. B. (1965) Thermal properties of uni-univalent electrolytes. Nat. Stand. Ref. Data Ser., U.S. N.B.S. 2, V+66 p.
33. Parker V. B., Wagman D. D. and Evans W. H. (1971) Selected values of chemical thermodynamic properties. Tables for the alkaline Earth elements (elements 92 through 97 in the standard order of arrangement). U.S. Nat. Bur. Stand. Tech. Note 270-6, 119 p.
34. Peterson R.C., and Wang R. Crystal molds on Mars: melting of a possible new mineral species to create Martian chaotic terrain. Geology 34 (2006) 957-960
35. Peterson R.C., Nelson W., Madu B., and Shurvell H.F. Meridianiite: a new mineral species observed on Earth and predicted to exist on Mars. Am. Mineral. 92 (2007) 1756-1759
36. 5 Pascals) and at higher temperatures. U.S. Geol. Surv. Bull. 2131, IV+461 p.
37. Spencer R.J. Sulfate minerals in evaporite deposits. Rev. Mineral. Geochem. 40 (2000) 173-192
38. 2O and generation of stress in porous materials. Cryst. Growth & Design 8 (2008) 336-343
39. Van't Hoff J.H., Meyerhoffer W., d'Ans J., Armstrong E.F., Barschall H., Biach O., Blasdale W.C., Bruni G., Chiaraviglio D., Cottrell F.G., Dawson H.M., Denison R.B., Donnan F.G., Estreicher-Rozbiersky T., von Euler-Chelpin H., o'Farrelly A., Farup F., Grassi N., Hinrichsen W., Just G., Kassatkin N., Kenrick F.B., Lichtenstein L., Sachs H., Saunders A.P., Smith N., Voerman G.L., Weigert F., Williams P. and Wilson H. (1912) Untersuchungen über die Bildungsverhältnisse der ozeanischen Salzablagerungen insbesondere des Stassfurter Salzlagers. Precht H. and Cohen E., eds., Akad. Verlagsges. m.b.H., Leipzig.
40. Visser J.W. A fully automatic program for finding the unit cell from powder data. J. Appl. Cryst. 2 (1969) 89-95
41. 2 organic substances in SI units. J. Phys. Chem. Ref. Data 11 Suppl. 2, 371 p.
42. Zalkin A., Ruben H., and Templeton D.H. The crystal structure and hydrogen bonding of magnesium sulfate hexahydrate. Acta Cryst. 17 (1964) 235-240