Structure, magnetism, and ionic conductivity of the gigantic {Mo 176}-wheel assembly: Na15Fe3Co 16[Mo176O528H3(H2O) 80]Cl27·450H2O

Journal of the American Chemical Society

Volumn 131, Issue 38, 2009, Pages 13578-13579

  Imai, Hiroyuki ^a   Akutagawa, Tomoyuki ^a   Kudo, Fumito ^a   Ito, Mitsuhiro ^b   Toyoda, Kazuhiro ^a   Noro, Shin Ichiro ^a   Cronin, Leroy ^c   Nakamura, Takayoshi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

^b NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

^c UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

IRON-BASED; NANO SCALE; POLYOXOMOLYBDATES; WHEEL ASSEMBLY; X-RAY SINGLE-CRYSTAL ANALYSIS;

CONDENSATION REACTIONS; IONIC CONDUCTIVITY; IRON ANALYSIS; MAGNETIC SUSCEPTIBILITY; MOLYBDENUM; SODIUM; WHEELS;

SINGLE CRYSTALS;

IRON; NANOMATERIAL; POLYOXOMOLYBDATE; UNCLASSIFIED DRUG;

ARTICLE; CONDUCTANCE; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; MAGNETISM; OXIDATION REDUCTION REACTION; PH; POLYMERIZATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 70349736102     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9048042     Document Type: Article

References (13)

1. (a) Müller, A.; Krickemeyer, E.; Meyer, J.; Bögge, H.; Peters, F.; Plass, W.; Diemann, E.; Dillinger, S.; Nonnenbruch, F.; Randerath, M.; Menke, C. Angew. Chem., Int. Ed. Engl. 1995, 34, 2122.
2. (b) Müller, A.; Das, S. K.; Fedin, V. P.; Krickemeyer, E.; Beugholt, C.; Bögge, H.; Schmidtmann, M.; Hauptfleisch, B. Z. Anorg. Chem. 1999, 625, 1187.
3. (a) Müller, A.; Krickemeyer, E.; Bögge, H.; Schmidtmann, M.; Beugholt, C.; Kögerler, P.; Lu, C. Angew. Chem., Int. Ed. 1998, 37, 1220.
4. (b) Müller, A.; Koop, M.; Bögge, H.; Schmidtmann, M.; Beugholt, C. Chem. Commun. 1998, 1501.
5. Müller, A.; Krickemeyer, E.; Bögge, H.; Schmidtmann, M.; Beugholt, C.; Kögerler, P.; Lu, C. Angew. Chem., Int. Ed. 1998, 37, 1220.
6. Müller, A.; Koop, M.; Bögge, H.; Schmidtmann, M.; Beugholt, C. Chem. Commun. 1998, 1501.
7. 3, T = 123 ± 2 K, Z = 2. The structure was solved with the program SHELXS-97 and refined using SHELXH-97 to R = 0.0858 for 108 942 reflections with I > 2σ(I), R = 0.120 for all reflections.
8. Van Uitert, L. G.; Sherwood, R. C.; Williams, H. J.; Rubin, J. J.; Bonner, W. A. J. Phys. Chem. Solids 1964, 25, 1447.
9. Figgis, B. N.; Gerloch, M.; Mason, R. Proc. R. Soc. London, Ser. A 1964, 279, 210.
10. (a) Drulis, H.; Dyrek, K.; Hoffmann, K. P.; Stanislaw, S.; Weselucha-Birczynska, A. Inorg. Chem. 1985, 24, 4009.
11. (b) Makinen, M. W.; Kuo, L. C.; Yim, M. B.; Wells, G. W.; Fukuyama, J. M.; Kim, J. E. J. Am. Chem. Soc. 1985, 107, 5245.
12. Proton Conductors, solids, membranes and gels materials and devices; Ed. Colomban, P.; Cambridge University Press: Cambridge, 1992.
13. Akutagawa, T.; Hasegawa, T.; Nakamura, T.; Inabe, T.; Saito, G. Chem. - Eur. J. 2002, 8, 4402.