Reactive extraction of propionic acid using Aliquat 336 in MIBK: Linear solvation energy relationship (LSER) modeling and kinetics study

Journal of Scientific and Industrial Research

Volumn 68, Issue 8, 2009, Pages 708-713

  Keshav, Amit ^a   Wasewar, Kailas L ^b   Chand, Shri ^c  

^a NATIONAL INSTITUTE OF TECHNOLOGY   (India)

^b VISVESVARAYA NATIONAL INSTITUTE OF TECHNOLOGY   (India)

^c INDIAN INSTITUTE OF TECHNOLOGY ROORKEE   (India)

Author keywords

Aliquat 336; Kinetics; Lser model; MIBK; Propionic acid; Reactive extraction

Indexed keywords

ALIQUAT 336; LSER MODEL; MIBK; PROPIONIC ACID; REACTIVE EXTRACTION;

FATTY ACIDS; RATE CONSTANTS; SOLVATION;

ACIDS;

DILUTION; EXTRACTION METHOD; ORGANIC ACID; REACTION KINETICS;

EID: 70349673286     PISSN: 00224456     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (22)

1. Wasewar K L and Pangarkar V G, Intensification of propionic acid production by reactive extraction: Effect of diluents on equilibrium, Chem Biochem Engg Q, 20 (2006) 325-331.
2. (Pubitemid 46497140) Uslu H and Inci I, (Liquid + liquid) equilibria of the (water + propionic acid + Aliquat 336 + organic solvents) at T = 298.15 K, J Chem Thermodyn, 39 (2007) 804-809.
3. Keshav A, Wasewar K L and Chand S, Extraction of propionic acid using different extractants (tri-n-butylphosphate, tri-noctylamine and Aliquat 336), Ind Eng Chem Res, 47 (2008) 6192-6196.
4. Keshav A, Wasewar K L and Chand S, Reactive extraction of propionic acid using tri-n-octylamine, tri-n-butyl phosphate and Aliquat 336 in sunflower oil as diluent, J Chem Tech Biotechnol, Published Online: 14.10.2008.
5. (Pubitemid 39202406) Wasewar K L, Pangarkar V G, Yawalkar A A and Moulijn J A, Fermentation of glucose to lactic acid coupled with reactive extraction: A review, Ind Chem Eng Res, 43 (2004) 5969-5982.
6. (Pubitemid 28051554) Gu Z, Glatz B A and Glatz C E, Propionic acid production by extractive fermentation. I. Solvent considerations, Biotechnol Bioeng, 57 (1998) 454-461.
7. (Pubitemid 37196183) Inci I and Aydin A, Extraction of hydroxy-carboxylic acids with MIBK/toluene solutions of amines, J Sci Ind Res, 62 (2003) 926-929.
8. Lewis, V and Yang S T, A novel extractive fermentation process for propionic acid production from whey lactose, Biotechnol Prog, 8 (1992) 104-110.
9. Keshav A, Wasewar K L and Chand S, Equilibrium studies for extraction of propionic acid using tri-n-butyl phosphate in different solvents, J Chem Eng Data, 53 (2008) 1424-1430.
10. Keshav A, Wasewar K L and Chand S, Equilibrium and kinetics of extraction of propionic acid using tri-n-octylphosphineoxide, Chem Eng Technol, 31 (2008) 1290-1295.
11. Keshav A, Wasewar K L and Chand S, Reactive extraction of propionic acid with tri-n-octylamine in different diluents, Sep. Purif Technol, 63 (2008) 179-183.
12. Keshav A, Wasewar K L and Chand S, Recovery of propionic acid from aqueous stream by reactive extraction: Effect of diluents, Desalination, 244 (2009) 12-23.
13. Ricker N L, Pittman E F & King C J, Solvent extraction with amines for recovery of acetic acid from dilute aqueous industrial streams, J Sep. Pro Technol, 1 (1980) 23-30.
14. Yang S T, White S A and Hsu S T, Extraction of carboxylic acids with tertiary and quaternary amines: Effect of pH, Ind Eng. Chem Res, 30 (1991) 1335-1342.
15. (Pubitemid 34607508) Wasewar K L, Pangarkar V G, Heesink A B M and Versteeg G F, Reactive extraction of lactic acid using Alamine 336 in MIBK: Equilibria and kinetics, J Biotechnol, 97 (2002) 59-68.
16. (Pubitemid 34987655) Wasewar K L, Pangarkar V G, Heesink A B M and Versteeg G F, Equilibria and kinetics for reactive extraction of lactic acid using Alamine 336 in decanol, J Chem Technol Biotechnol, 77 (2002) 1068-1075.
17. Wasewar K L, Pangarkar V G, Heesink A B M and Versteeg G F, Intensification of enzymatic conversion of glucose to lactic acid by reactive extraction, Chem Eng Sci, 58 (2003) 3385-3393.
18. Gaidhani H K, Wasewar K L and Pangarkar V G, Intensification of enzymatic hydrolysis of penicillin-G: Part I Equilibria and kinetics of extraction of phenyl acetic acid by Alamine 336, Chem Eng Sci, 57 (2002) 1979-1984.
19. Doraiswamy L K and Sharma M M, Heterogeneous reaction: Analysis, Examples, and Reactor Design, vol 2: Fluid-Fluid - Solid-Reactions. 1st edn (John Wiley and Sons, New York) 1984, 17-41.
20. *, R, and â, and some methods for simplifying the generalized solvatochromic equation, J Org Chem, 48 (1983) 2877-2887.
21. (Pubitemid 23655889) Bizek V, Horacek J and Kousova M, Amine extraction of citric acid: Effect of diluent, Chem Eng Sci, 48 (1993) 1447-1457.
22. (Pubitemid 44329257) Uslu H, Linear solvation energy relationship (LSER) modeling and kinetic studies on propionic acid reactive extraction using Alamine 336 in a toluene solution, Ind Eng Chem Res, 45 (2006) 5788-5795.