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70349611119
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note
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The discreteness of the electronic charge leads to additional shot noise. This contribution to the fluctuations is however negligible compared to diffusion noise at the low frequencies investigated here.
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10
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70349616148
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note
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We use the term "escape rate" for consistency with Bezrukov. In electrochemical parlance, κ is a mass-transfer coefficient.
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12
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70349620426
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note
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The real part of Č(s) was evaluated using MapleSoft Maple 12.
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13
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70349623950
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note
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a, which is simply the linear concentration of molecules at this interface between the active region and the entrance channel.
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70349629592
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During extended measurements, we also observed a slight increase of the current due to evaporation of the solvent. This cannot account for the nonideal shape of the voltammograms, however, since this shape was essentially identical during subsequent forward and backward sweeps. Furthermore, the time scale for evaporation (0.5% current increase per 100 s, the time to record one voltammogram) was much slower compared to the observed current increase of 4% between 0.3 and 0.4 V (10 s).
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22
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70349617301
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note
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b = -0.1V) was indistinguishable from the background PSD in Figure 6.
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23
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70349615450
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note
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These spikes are also observed with no electrode connected, indicating that the interference occurs internally in the potentiostat.
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70349632442
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56 a modified diffusion equation that takes adsorption explicitly into account via trapping and release rates. However the resulting equations can be solved analytically only for a limited set of boundary conditions. For simplicity we therefore employ the model of eq 22.
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41
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70349616138
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note
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We make this assumption for simplicity; a more detailed model of potentialdependent adsorption could easily be introduced at this stage.
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42
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67649986187
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70349625644
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note
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36
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44
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70349629585
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note
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17 is therefore also unaffected.
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48
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70349631204
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note
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2 is slightly bigger because of the two methanol groups.
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49
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0037162486
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