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Unlike diazonium salts, which are prone to graft spontaneously onto materials, arylhydrazines are not amenable to such a process. A cyclic voltammogram recorded for a GC electrode upon 30 min of exposure to an arylhydrazine solution shows that there are no blocking effects at all.
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4644229254
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It is proposed that N atoms in the arylhydrazine are expelled as nitrogen gas during the oxidation, thereby allowing the substate-aryl linkage to become the predominant bonding mode. In contrast for the electrooxidative grafting of primary and secondary alkylamines, covalent attachment at the surface goes through N; see
-
It is proposed that N atoms in the arylhydrazine are expelled as nitrogen gas during the oxidation, thereby allowing the substate-aryl linkage to become the predominant bonding mode. In contrast for the electrooxidative grafting of primary and secondary alkylamines, covalent attachment at the surface goes through N; see: Adenier, A.; Chehimi, M. M.; Gallardo, I.; Pinson, J.; Vilà, N. Langmuir 2004, 20, 8243-8253.
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70349629130
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note
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X-ray photoelectron spectroscopy measurements confirm that the nitrogens in the hydrazine group are lost during the grafting process.
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