Structure and magnetic properties of a novel heterospin 1-D chain complex containing both Cu(II) and nitroxide radicals as spin branches

Science in China, Series B: Chemistry

Volumn 52, Issue 9, 2009, Pages 1438-1443

  Ma, Yue ^a   Chen, Xiaoping ^a   Cao, Dong ^a   Yan, Shiping ^a   Liao, Daizheng ^a  

^a NANKAI UNIVERSITY   (China)

Author keywords

Crystal structure; Cu(II) complex; Magnetic properties; Nitronyl nitroxide radical; Tetrachloro phthalic acid

Indexed keywords

ANTIFERRO-MAGNETIC INTERACTIONS; CHAIN COMPLEXES; COPPER IONS; COUPLING PARAMETERS; CU(II) COMPLEX; FERRO-MAGNETIC INTERACTIONS; IMIDAZOLINES; MAGNETIC DATA; NEUTRAL CHAINS; NITRONYL NITROXIDE RADICAL; NITROXIDE RADICALS; PHTHALIC ACID; POPULATION ANALYSIS; PYRIDYL; TETRACHLORO-PHTHALIC ACID; TETRAMETHYL; THEORETICAL MODELS;

ACIDS; ANTIFERROMAGNETISM; CARBOXYLIC ACIDS; LIGANDS; MAGNETIC MATERIALS; MAGNETIC PROPERTIES; POPULATION STATISTICS; SPIN DYNAMICS;

CRYSTAL STRUCTURE;

EID: 70349507943     PISSN: 10069291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-009-0202-0     Document Type: Article

References (29)

1. +[TCNE]-. J Chem Soc, Chem Commun, 1986, 1026-1028
2. R. Sessoli D. Gatteschi A. Caneschi M. A. Novak 1993 Magnetic bistability in a metal-ion cluster Nature 365 141 143 10.1038/365141a0 1:CAS:528: DyaK3sXms1WisrY%3D
3. A. Caneschi D. Gatteschi N. Lalioti C. Sangregorio R. Sessoli G. Venturi A. Vindigni A. Rettori M. G. Pini M.A. Novak 2001 Cobalt(II)-nitronyl nitroxide chains as molecular magnetic nanowires Angew Chem Int Ed 40 1760 1763 10.1002/1521-3773(20010504)40:9<1760::AID-ANIE17600>3.0.CO;2-U 1:CAS:528:DC%2BD3MXjslCgsLw%3D (Pubitemid 32441103)
4. A. Caneschi D. Gatteschi J. P. Renard P. Rey R. Sessoli 1989 Magnetic coupling in zero- and one-dimensional magnetic systems formed by nickel(II) and nitronyl nitroxides. Magnetic phase transition of a ferrimagnetic chain Inorg Chem 28 2940 2944 10.1021/ic00314a013 1:CAS:528:DyaL1MXlsVGlu7o%3D
5. 2(tp)]. Eur J Inorg Chem, 2003, 62-65
6. 2](n): A new 2-D interdigitating complex containing dicyanoaurate(I) anion, a radical, and cobalt(II) ion incorporating gold center dot center dot center dot gold and hydrogen bonding interactions Inorg Chem 43 4552 4554 10.1021/ic049751i 1:CAS:528:DC%2BD2cXlt1Sjtbw%3D
7. II complexes containing imino nitroxide radicals and a dicyanamide anion New J Chem 25 1572 1576 10.1039/b104773f 1:CAS:528:DC%2BD3MXovFKgt7g%3D (Pubitemid 34048739)
8. 2 (NITpPy = nitronyl nitroxide radical). J Chem Soc, Dalton Trans, 2000, 129-132
9. 2 Polyhedron 20 1371 1374 10.1016/S0277-5387(01)00621-0 1:CAS:528:DC%2BD3MXksV2mtb0%3D (Pubitemid 32619449)
10. 2 (M = Zn, Cd) Z Anorg Allg Chem 631 1702 1705 10.1002/zaac.200500096 1:CAS:528:DC%2BD2MXlsFymtbk%3D (Pubitemid 40828676)
11. L. C. Li D. Z. Liao Z. H. Jiang S. P. Yan 2004 Ferromagnetic interactions in copper(II) and nickel(II) coordination polymers containing nitronyl nitroxide radical and terephthalate Inorg Chim Acta 357 405 410 10.1016/j.ica.2003.05.006 1:CAS:528:DC%2BD2cXmsFynsw%3D%3D
12. 2]n exhibiting strong ferromagnetic coupling Inorg Chem Commun 6 225 228 10.1016/S1387-7003(02)00723-2 1:CAS:528:DC%2BD3sXpsF2gug%3D%3D
13. S. P. Wang D. Z. Gao Y. Song Z. Q. Liu D. Z. Liao Z. H. Jiang S. P. Yan 2006 One-dimensional coordination polymers made of transition metalnitronyl nitroxide radical with dicyanoaurate(I) bridges Inorg Chim Acta 359 505 510 10.1016/j.ica.2005.09.004 1:CAS:528:DC%2BD28XhsFCisg%3D%3D
14. L. C. Li Z. L. Liu S. S. Turner D. Z. Liao Z. H. Jiang S. P. Yan 2003 The first one-dimensional copper(II)-radical system with alternating double end-on and end-to-end azido bridges New J Chem 27 752 755 10.1039/b209397a 1:CAS:528:DC%2BD3sXitlyksr8%3D (Pubitemid 36469893)
15. M. S. Davis K. Morokuma R. W. Kreilick 1972 Free radicals with large negative spin densities J Am Chem Soc 94 5588 5592 10.1021/ja00771a010 1:CAS:528:DyaE38XltVShtbc%3D
16. Sheldrick GM. SHELXS-97: Program for the Solution of Crystal Structures. University of Gottingen, Germany, 1997
17. Sheldick GM. SHELXS-97:Program for the Refinement of Crystal Strutures. University of Gottingen, Germany, 1997
18. R. E. D. Sesto A. M. Arif J. S. Miller 2000 Copper(II) benzoate nitroxide dimers and chains: Structure and magnetic studies Inorg Chem 39 4894 4902 10.1021/ic0007106 1:CAS:528:DC%2BD3cXmsl2jtr8%3D
19. 4 center dot MeOH New J Chem 27 583 587 10.1039/b206475h 1:CAS:528:DC%2BD3sXhsV2ks7Y%3D (Pubitemid 36379500)
20. H. Z. Kou B. C. Zhou D. Z. Liao R. J. Wang Y. D. Li 2002 From one-dimensional chain to pentanuclear molecule. Magnetism of cyanobridged Fe(III)-Ni(II) complexes Inorg Chem 41 6887 6891 10.1021/ic025927+ 1:CAS:528:DC%2BD38Xos1aqur0%3D
21. J. Dean K. J. Maxwell 1982 Study of exchange-coupled pairs of Cr3 ions in Rb3Cr2Cl9 Mol Phys 47 551 563 10.1080/00268978200100402 1:CAS:528: DyaL3sXotVygsA%3D%3D
22. 6 (X = Cl, Br) Inorg Chem 34 778 786 10.1021/ic00108a006 1:CAS:528:DyaK2MXjsFSlurk%3D
23. Georges R, Almenar J J B, Coronado E, Curély J, Drillon M, Miller J S, Drillon M (Eds.): Magnetism: From Molecules to Materials, Vol. 2, Weinheim, Wiley-VCH, 2001. 1-47
24. H. M. McConnell 1963 Ferromagnetism in solid free radicals J Chem Phys 39 1910 1910 10.1063/1.1734562 1:CAS:528:DyaF3sXkslals78%3D
25. Cirujeda J, Mas M, Molins E, Panthou F L, Laugier J, Park J G, Pauson C, Rey P, Rovira C, Veciana J. Control of the structural dimensionality in hydrogen-bonded self-assemblies of open-shell molecules. Extension of intermolecular ferromagnetic interactions in α-phenyl nitronyl nitroxide radicals into three dimensions. J Chem Soc, Chem Commun. 1995, 709-710
26. III) heterobinuclear complex: interaction between orthogonal magnetic orbitals J Am Chem Soc 104 2165 2176 10.1021/ja00372a012 1:CAS:528:DyaL38XhsFCgt7g%3D
27. H. H. Lin H. H. Wei G. H. Lee Y. Wang 2001 Structure and magnetic properties of copper(II) carboxylate with pyridyl-substituted nitronyl nitroxides Polyhedron 20 3057 3063 10.1016/S0277-5387(01)00917-2 1:CAS:528:DC%2BD3MXoslSgt7Y%3D (Pubitemid 33143739)
28. 2} Inorg Chim Acta 357 376 380 10.1016/j.ica.2003.06.002 1:CAS:528:DC%2BD2cXmsFygug%3D%3D
29. 2]n: structure and magnetic properties. J Chem Soc, Dalton Trans, 2002, 1350-1353