Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels

Inorganic Chemistry Communications

Volumn 12, Issue 10, 2009, Pages 1020-1023

  Li, Huiduan ^a   Zhang, Lirong ^a   Liu, Li ^b   Jiang, Tianchan ^a   Yu, Yang ^a   Li, Guanghua ^a   Huo, Qisheng ^a   Liu, Yunling ^a  

^a JILIN UNIVERSITY   (China)

^b NORTHEAST NORMAL UNIVERSITY   (China)

Author keywords

Helical chain; Hybrid material; Hydrothermal synthesis; Indium phosphite oxalate; Intersecting channels

Indexed keywords

EID: 70349431077     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.08.011     Document Type: Article

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25. 3 with stirring. Finally, 440 mg of dabco was added slowly to the above mixture. After stirring for 30 min, the mixture was transferred into a sealed Teflon-lined steel autoclave and heated at 160 °C for 3 days, then cooled to room temperature. Colorless plate-like crystals of compound 1 were collected and air-dried at room temperature (68% yield based on Indium). The purity of 1 was confirmed by comparison of the experimental powder X-ray diffraction pattern to the calculated spectrum based on the single-crystal structure (as shown in Fig. S1). The diffraction peaks on both spectra correspond well in position, indicating the phase purity of the as-synthesized sample.
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