Synthesis and optical spectroscopy of oligo(1,6-heptadiynes) with a single basic structure prepared through adamantylimido-based molybdenum Wittig and metathesis chemistry

Journal of the American Chemical Society

Volumn 131, Issue 37, 2009, Pages 13441-13452

  Scriban, Corina ^a   Amagai, Bryan S ^b   Stemmler, Elizabeth A ^b   Christensen, Ronald L ^b   Schrock, Richard R ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b BOWDOIN COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLIDENES; ASYMPTOTIC CONVERGENCE; BASIC STRUCTURE; CIS-DOUBLE BONDS; CONJUGATED DOUBLE BONDS; CONJUGATION LENGTH; CYCLOPENTENE RINGS; DOUBLE BONDS; ELECTRONIC ORIGIN; ELECTRONIC TRANSITION; ELECTRONIC TRANSITION ENERGIES; EXCITED-STATE ENERGY; MALDI-MS; METATHESIS CHEMISTRY; OLIGOENES; OPTICAL SPECTRA; OPTICAL SPECTROSCOPY; ROOM TEMPERATURE SAMPLES; SYSTEMATIC INVESTIGATIONS; THEORETICAL TREATMENTS;

ALDEHYDES; MOLYBDENUM; PURIFICATION; SYNTHESIS (CHEMICAL);

CHEMICAL BONDS;

ADAMANTANE; ALDEHYDE; ALKADIENE; CAROTENOID; CYCLOPENTANE; DIETHYL DIPROPARGYLMALONATE POLYMER; MALONIC ACID DERIVATIVE; MOLYBDENUM; OLIGO( 1,6 HEPTADIYNE); POLYENE; UNCLASSIFIED DRUG;

ABSORPTION; ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONJUGATION; ELECTRON TRANSPORT; ENERGY TRANSFER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ISOMERIZATION; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; MOLECULAR WEIGHT; MOLECULE; OPTICAL SPECTROSCOPY; PHASE TRANSITION; POLYMERIZATION; PURIFICATION; RING CLOSING METATHESIS; ROOM TEMPERATURE; SPECTROSCOPY; STOICHIOMETRY; SYNTHESIS; WITTIG REACTION;

EID: 70349381790     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja904541b     Document Type: Article

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