Trapping of trace gases by growing ice surfaces including surface-saturated adsorption

Journal of Geophysical Research Atmospheres

Volumn 114, Issue 13, 2009, Pages

  Karcher B ^a   Abbatt, J P D ^b   Cox, R A ^c   Popp, P J ^d,e   Voigt, C ^a,e  

^a GERMAN AEROSPACE CENTER DLR   (Germany)

^b UNIVERSITY OF TORONTO   (Canada)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^d UNIVERSITY OF COLORADO   (United States)

^e UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; ADSORPTION; ADSORPTION ISOTHERMS; ATMOSPHERIC TEMPERATURE; CLOUDS; CRYSTALS; DIFFUSION IN GASES; FILM GROWTH; MOLECULES; NITRIC ACID; VAPORS;

ADSORPTION EQUILIBRIA; EXACT ANALYTICAL SOLUTIONS; FIELD MEASUREMENT; FIELD OBSERVATIONS; GAS PHASE DIFFUSION; ICE CRYSTALS; ICE FILMS; ICE GROWTH; ICE PARTICLES; ICE PHASE; ICE SURFACES; LABORATORY STUDIES; LANGMUIR-TYPE ADSORPTION; MOLAR RATIO; PHYSICAL CONDITIONS; PHYSICAL NATURE; POTENTIAL MODEL; STEADY STATE; SUPERSATURATED AIR; THERMODYNAMIC SOLUBILITY; TRACE GAS; TRACE-GASES; TRAPPED MOLECULES; TRAPPING EFFICIENCIES; TRAPPING MODEL; TROPICAL TROPOPAUSE; UPDATED MODEL; VAPOR FLUXES; VERY LOW TEMPERATURES;

ICE;

ADSORPTION; AIRBORNE SURVEY; ANALYTICAL METHOD; CIRRUS; CLIMATE MODELING; CLOUD WATER; COMPARATIVE STUDY; ICE CRYSTAL; NITRIC ACID; SUPERSATURATION; THERMODYNAMICS; TRACE GAS; TROPOPAUSE;

EID: 70349311888     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2009JD011857     Document Type: Article

References (20)

1. Abbatt, J. P. D. (1997), Interaction of HNO3 with water-ice surfaces at temperatures of the free troposphere, Geophys. Res. Lett., 24, 1479-1482.
2. Abbatt, J. P. D., T. Bartels-Rausch, M. Ullerstam, and T. J. Ye (2008), Uptake of acetone, ethanol, and benzene to snow and ice: Effects of surface area and temperature, Environ. Res. Lett., 3, 045008.
3. Ammann, M., R. Atkinson, R. A. Cox, J. Crowley, R. Hynes, M. E. Jenkin, M. J. Rossi, J. Troe, and T. Wallington, (2008) Summary of evaluated data for atmospheric heterogeneous processes, IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry, International Union for Pure and Applied Chemistry. (Available at http://www. iupac-kinetic.ch.cam.ac.uk, January)
4. Cox, R. A., M. A. Fernandez, A. Symington, M. Ullerstam, and J. P. D. Abbatt (2005), A kinetic model for uptake of HNO3 and HCl on ice in a coated wall flow system, Phys. Chem. Chem. Phys., 7, 3434-3442.
5. Gierens, K. (1994), The influence of radiation on the diffusional growth of ice crystals, Contr. Atmos. Phys., 67, 181-193.
6. Hanson, D. R. (1992), The uptake of HNO3 onto ice, NAT, and frozen sulfuric acid, Geophys. Res. Lett., 19, 2063-2066.
7. Heard, D. E. (Ed.) (2005), Atmospheric chemistry, Faraday Discuss., 130, 241-264.
8. Huthwelker, T., M. Ammann, and Th. Peter (2006), The uptake of acidic gases on ice, Chem. Rev., 106, 1375-1444.
9. Kärcher, B., and M. M. Basko (2004), Trapping of trace gases in growing ice crystals, J. Geophys. Res., 109, D22204, doi:10.1029/2004JD005254.
10. Kärcher, B., and C. Voigt (2006), Formation of nitric acid/water ice particles in cirrus clouds, Geophys. Res. Lett., 33, L08806, doi:10.1029/ 2006GL025927. (Pubitemid 43950167)
11. von Kuhlmann, R., and M. G. Lawrence (2006), The impact of ice uptake of nitric acid on atmospheric chemistry, Atmos. Chem. Phys., 6, 225235. (Pubitemid 43263657)
12. Popp, P. J., et al. (2004), Nitric acid on subtropical cirrus cloud particles, J. Geophys. Res., 109, D06302, doi:10.1029/2003JD004255.
13. Popp, P. J., et al. (2007), Condensed-phase nitric acid in a tropical subvisible cirrus cloud, Geophys. Res. Lett., 34, L24812, doi:10.1029/ 2007GL031832.
14. Pöschl, U., Y Rudich, and M. Ammann (2007), Kinetic model framework for aerosol and cloud surface chemistry and gas-particle interactions: Part 1. General equations, parameters, and terminology, Atmos. Chem. Phys., 7, 5989-6023. (Pubitemid 350301052)
15. Pruppacher, H. R., and J. D. Klett (1997), Microphysics of Clouds and Precipitation, Kluwer Acad., Norwell, Mass.
16. Thibert, E., and F. Dominé (1998), Thermodynamics and kinetics of the solid solution of HNO3 in ice, J. Phys. Chem. B, 102, 4432-4439.
17. Ullerstam, M., and J. P. D. Abbatt (2005), Burial of gas phase HNO 3 by growing ice surfaces under tropospheric conditions, Phys. Chem. Chem. Phys., 7, 3596-3600.
18. Ullerstam, M., T. Thornberry, and J. P. D. Abbatt (2005), Uptake of gasphase nitric acid to ice at low partial pressures: Evidence for unsaturated surface coverage, Faraday Discuss., 130, 211-226. (Pubitemid 41223686)
19. Voigt, C., et al. (2006), Nitric acid in cirrus clouds, Geophys. Res. Lett., 33, L05803, doi: 10.1029/2005GL025159.
20. Voigt, C., et al. (2007), In situ observations and modeling of small nitric acid-containing ice crystals, Atmos. Chem. Phys., 7, 3373-3383. (Pubitemid 47138921)