Identification of ionic liquid breakdown products in an advanced oxidation system

Journal of Hazardous Materials

Volumn 171, Issue 1-3, 2009, Pages 478-483

  Czerwicka, M ^a   Stolte, S ^b   Muller A ^c   Siedlecka, E M ^a   Golebiowski M ^a   Kumirska, J ^a   Stepnowski, P ^a  

^a UNIVERSITY OF GDA SK   (Poland)

^b UNIVERSITY OF BREMEN   (Germany)

^c JACOBS UNIVERSITY BREMEN   (Germany)

Author keywords

Advanced oxidation technology; Degradation products; Ionic liquids

Indexed keywords

ADVANCED OXIDATION; ADVANCED OXIDATION PROCESSES; ADVANCED OXIDATION TECHNOLOGY; ALKYL CHAIN; ALKYLIMIDAZOLIUM; BIOLOGICAL TESTS; BREAKDOWN PRODUCTS; DEGRADATION PRODUCTS; ELECTROSPRAY MASS SPECTROMETRY; IMIDAZOLIUM IONIC LIQUIDS; MS/MS ANALYSIS; NATURAL WATERS; POTENTIAL TRANSFORMATIONS; UV IRRADIATION; UV SYSTEMS; WASTEWATER TREATMENT SYSTEM;

BIODEGRADATION; CHEMICAL OXYGEN DEMAND; CHROMATOGRAPHIC ANALYSIS; DEGRADATION; DISSOLUTION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IONIZATION OF LIQUIDS; IONS; MASS SPECTROMETRY; OXIDATION; PHOTODEGRADATION; WASTEWATER; WASTEWATER RECLAMATION; WASTEWATER TREATMENT;

IONIC LIQUIDS;

HYDROGEN PEROXIDE; IONIC LIQUID;

BIODEGRADATION; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; OXIDATION; TOXICITY; WASTEWATER;

ARTICLE; BIODEGRADABILITY; DECOMPOSITION; ELECTROSPRAY MASS SPECTROMETRY; HAZARD ASSESSMENT; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROXYLATION; OXIDATION KINETICS; ULTRAVIOLET IRRADIATION; WASTE WATER;

BIODEGRADATION, ENVIRONMENTAL; HYDROGEN PEROXIDE; IONIC LIQUIDS; IONS; LIGHT; OXYGEN; PHOTOCHEMISTRY; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; TANDEM MASS SPECTROMETRY; ULTRAVIOLET RAYS; WASTE DISPOSAL, FLUID; WATER POLLUTANTS, CHEMICAL; WATER PURIFICATION;

EID: 70349240283     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.06.027     Document Type: Article

References (29)

1. Kralisch D., Stark A., Korsten S., Kreisel G., and Ondruschka B. Energetic, environmental and economic balances: spice up your ionic liquid research efficiency. Green Chem. 7 (2005) 301-309
2. R.D. Rogers, K. Seddon, Ionic Liquids: Industrial Applications for Green Chemistry. American Chemical Society ACS Ser. 818, Oxford University Press, Washington DC, 2002.
3. Stepnowski P. Preliminary assessment of the sorption of some alkyl imidazolium cations as used in ionic liquids to soils and sediments. Aust. J. Chem. 58 (2005) 170-173
4. Stepnowski P., Mrozik W., and Nichthauser J. Adsorption of alkylimidazolium and alkylpyridinium ionic liquids onto natural soils. Environ. Sci. Technol. 41 (2007) 511-516
5. Mrozik W., Nichthauser J., and Stepnowski P. Prediction of the adsorption coefficients for imidazolium ionic liquids in soils using cyanopropyl stationary phase. Pol. J. Environ. Stud. 17 (2008) 383-388
6. Mrozik W., Jungnickel C., Skup M., Urbaszek P., and Stepnowski P. Determination of the adsorption mechanism of imidazolium-type ionic liquids onto kaolinite: implications for their fate and transport in the soil environment. Environ. Chem. 5 (2008) 299-306
7. Gathergood N., Garcia M.T., and Scammells P.J. Biodegradable ionic liquids. Part I. Concept, prelinary targets and evaluation. Green Chem. 6 (2004) 166-175
8. Romero A., Santos A., Tojo J., and Rodríguez A. Toxicity and biodegradability of imidazolium ionic liquids. J. Hazard. Mater. 151 (2008) 268-273
9. Docherty K.M., Dixon J.K., and Kulpa Jr. C.F. Biodegrability of imidazolium and pyridinium ionic liquids by an activated sludge microbial community. Biodegradation 18 (2007) 481-493
10. 2 Fenton-like system in the degradation of MTBE and its by-products. Water Environ. Res. 79 (2007) 2318-2324
11. Siedlecka E.M., and Stepnowski P. Decomposition rates of methyl tert butyl ether and its by-products by the Fenton system in saline wastewaters. Sep. Purif. Technol. 52 (2006) 317-324
12. Gulyas H. Processes for the removal of recalcitrant organics from industrial wastewaters. Water. Sci. Technol. 36 (1997) 9-16
13. Stepnowski P., and Zaleska A. Comparison of different advanced oxidation processes for the degradation of room temperature ionic liquids. J. Photochem. Photobiol. A: Chem. 170 (2005) 45-50
14. 2 oxidation system. Chem. Anal. (Warsaw) 53 6 (2008) 943-945
15. Siedlecka E.M., Mrozik W., Kaczyński Z., and Stepnowski P. Degradation of 1-butyl-3-methylimidazolium chloride ionic liquid in a Fenton-like system. J. Hazard. Mater. 154 (2008) 893-900
16. Li X., Zhao J., Li Q., Wang L., and Tsang S.C. Ultrasonic chemical oxidative degradations of 1,3-dialkylimidazolium ionic liquids and their mechanistic elucidations. Dalton Trans. 19 (2007) 1875-1880
17. Kroon M.C., Buijs W., Peters C.J., and Witkamp G.J. Decomposition of ionic liquids in electrochemical processing. Green Chem. 8 (2006) 241-245
18. Allen D., Baston G., Bradley A.E., Gorman T., Haile A., Hamblett I., Hatter J.E., Healey M.J.F., Hodson B., Lewin R., Lovell K.V., Newton B., Pitner W.R., Rooney D.W., Sanders D., Seddon K.R., Sims H.E., and Thied R.C. An investigation of the radiochemical stability of ionic liquids. Green Chem. 4 (2002) 152-158
19. 2N. Dalton Trans. 21 (2006) 2526-2534
20. Stepnowski P., Müller A., Behrend P., Ranke J., Hoffmann J., and Jastorff B. Reversed-phase liquid chromatography of selected room-temperature ionic cations. J. Chromatogr. A 993 (2003) 173-178
21. Stepnowski P., and Mrozik W. Analysis of selected ionic liquid cations by ion exchange chromatography and reversed-phase high performance liquid chromatography. J. Sep. Sci. 28 (2005) 149-154
22. Stepnowski P. Solid phase extraction of ionic liquids from environmental aqueous samples. Anal. Bioanal. Chem. 381 (2005) 189-193
23. Stolte S., Abdulkarim S., Arning J., Blomeyer-Niestedt A.-K., Bottin-Weber U., Matzke M., Ranke J., Jastorff B., and Thöming J. Primary biodegradation of ionic liquids cations, identification of degradation products of 1-methyl-3-octylimidazolium chloride and electrochemical wastewater treatment of poorly biodegradable compounds. Green Chem. 10 (2008) 214-224
24. Stepnowski P., and Storoniak P. Lipophilicity and metabolic route prediction of imidazolium ionic liquids. Environ. Sci. Pollut. Res. 12 (2005) 199-204
25. Philipp B., Hoff M., Germa F., Schink B., Beimborn D., and Mersch-Sundermann V. Biochemical interpretation of quantitative structure-activity relationships (QSAR) for biodegradation of N-heterocycles: a complementary approach to predict biodegradability. Environ. Sci. Technol. 41 (2007) 1390-1398
26. Jastorff B., Möter K., Berendt P., Bottin-Weber U., Filser J., Heimers A., Ondruschka B., Ranke J., Schaefer M., Schröder H., Stark A., Stepnowski P., Stock F., Störmann R., Stolte S., Welz-Biermann U., Ziegert S., and Thöming J. Progress in evaluation of risk potential of ionic liquids-basis for an eco-design of suitable products. Green Chem. 7 (2005) 362-372
27. Stolte S., Matzke M., Arning J., Böschen A., Pitner W.-R., Welz-Biermann U., Jastorff B., and Ranke J. Effects of different head groups and functionalised side chains on the aquatic toxicity of ionic liquids. Green Chem. 9 (2007) 1170-1179
28. Stolte S., Arning J., Bottin-Weber U., Matzke M., Stock F., Thiele K., Uerdingen M., Welz-Biermann U., Jastorff B., and Ranke J. Anion effects on the cytoxicity of ionic liquids. Green Chem. 8 (2006) 621-629
29. Matzke M., Stolte S., Thiele K., Juffernholtz T., Arning J., Ranke J., Welz-Biermann U., and Jastorff B. The influence of anion species on the toxicity of 1-alkyl-3-methylimidazolium ionic liquids observed in an (eco)toxicological test battery. Green Chem. 9 (2007) 1198-1207