5-Exo-cyclizations of pentenyliminyl radicals: Inversion of the gem-dimethyl effect

Journal of Physical Chemistry A

Volumn 113, Issue 37, 2009, Pages 10005-10012

  Portela Cubillo, Fernando ^a   Alonso Ruiz, Rafael ^b   Sampedro, Diego ^b   Walton, John C ^a  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

^b UNIVERSITY OF LA RIOJA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; ALKYL SUBSTITUENT; AROMATIC RINGS; ARYL SUBSTITUENTS; C-C DOUBLE BONDS; CONTINUOUS WAVE; CYCLIZATIONS; DFT COMPUTATIONS; DIFFUSION CONTROLLED; DIOXIME; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; EPR SPECTROSCOPY; GEM-DIMETHYL; IMINYL RADICALS; O-CYCLIZATION; OXALATE PRECURSORS; OXIME ESTERS; PENTENYL CHAINS; RADICAL CYCLIZATIONS; RING CLOSURES; STERIC INTERACTIONS; UNSYMMETRICAL;

ALKYLATION; AROMATIC COMPOUNDS; CYCLIZATION; ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; ESTERS; GEMS; ISOMERS; PARAMAGNETIC RESONANCE; PARAMAGNETISM; PROBABILITY DENSITY FUNCTION; QUANTUM THEORY; RATE CONSTANTS; SUBSTITUTION REACTIONS;

PH EFFECTS;

EID: 70349127376     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9047902     Document Type: Article

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