Soil metals analysis using laser-induced breakdown spectroscopy (LIBS)

Soil Science Society of America Journal

Volumn 73, Issue 5, 2009, Pages 1469-1478

  Essington, Michael E ^a   Melnichenko, Galina V ^a   Stewart, Melanie A ^a   Hull, Robert A ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

Author keywords

AAS, Atomic absorbance spectroscopy; ICP MS, Inductively coupled aigon plasma optical mass spectroscopy; ICP OES, Inductively couple argon plasma optical emission spectroscopy; LIBS, Laser induced breakdown spectroscopy; REP, Relative error of prediction; RSE, Relative standard error; VIP; Variable importance for projection

Indexed keywords

AAS, ATOMIC ABSORBANCE SPECTROSCOPY; ICP-MS, INDUCTIVELY COUPLED AIGON PLASMA-OPTICAL MASS SPECTROSCOPY; ICP-OES, INDUCTIVELY COUPLE ARGON PLASMA-OPTICAL EMISSION SPECTROSCOPY; LIBS, LASER-INDUCED BREAKDOWN SPECTROSCOPY; REP, RELATIVE ERROR OF PREDICTION; RSE, RELATIVE STANDARD ERROR; VIP VARIABLE IMPORTANCE FOR PROJECTION;

ARGON; ATOMIC SPECTROSCOPY; BARIUM; CALCIUM; CHROMIUM; DISSOLUTION; INDUCTIVELY COUPLED PLASMA; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; LASER DAMAGE; LASER SPECTROSCOPY; LASERS; LIGHT EMISSION; MANGANESE; MANGANESE COMPOUNDS; MASS SPECTROMETERS; METAL ANALYSIS; METAL RECOVERY; NEODYMIUM LASERS; OPTICAL EMISSION SPECTROSCOPY; PARTICLE SIZE; PHOTORESISTS; PULSED LASER APPLICATIONS; REGRESSION ANALYSIS; SODIUM; SOIL SURVEYS; SOILS; SPECTRUM ANALYSIS; STANDARDS; ZINC;

EMISSION SPECTROSCOPY;

ANALYTICAL METHOD; ATOMIC EMISSION SPECTROSCOPY; CONCENTRATION (COMPOSITION); DISSOLUTION; ERROR ANALYSIS; INDUCTIVELY COUPLED PLASMA METHOD; LASER METHOD; METAL; SOIL ANALYSIS; SOIL CHEMISTRY;

EID: 69949141595     PISSN: 03615995     EISSN: None     Source Type: Journal    
DOI: 10.2136/sssaj2008.0267     Document Type: Article

References (29)

1. Ammons, J.T., M.E. Essingcon, R.J. Lewis, A.O. Gallagher, and G.M. Lessman. 1995. An application of a modified microwave total dissolution technique for soils. Commun. Soil Sci. Plant Anal. 26:831-842.
2. Body, D., and B.L. Chadwick. 2001. Optimization of the spectral data processing in a LIBS simultaneous elemental analysis system. Spectrochim. Acta B 56:725-736.
3. Bolger, J.A. 2000. Semi-quantitative laser-induced breakdown spectroscopy for analysis of mineral drill core. Appl. Spectrosc. 54:181-189.
4. Bousquet, B., J.-B. Sirven, and L. Canioni. 2007. Towards quantitative laser-induced breakdown spectroscopy analysis of soil samples. Spectrochim. Acta B 62:1582-1589. (Pubitemid 350213354)
5. Bustamante, M.E, C.A. Rinaldi, and J.C. Ferrero. 2002. Laser induced breakdown spectroscopy characterization of Ca in a soil depth profile. Spectrochim. Acta B 57:303-309. (Pubitemid 34187549)
6. Capitelli, E, F. Colao, M.R. Provenzano, R. Fanconi, G. Brunecci, and N. Senesi. 2002. Determination of heavy metals in soils by laser induced breakdown spectroscopy. Geoderma 106:45-62. (Pubitemid 34147330)
7. Castle, B.C., K. Talabardon, B.W. Smith, and J.D. Winefordner. 1998. Variables influencing the precision of laser-induced breakdown spectroscopy measurements. Appl. Spectrosc. 52:649-657.
8. Cremers, D.A., M.H. Ebinger, D.D. Breshears, P.J. Unkefer, S.A. Kammerdiener, M.J. Ferris, K.M. Catlett, and J.R. Brown. 2001. Measuring total soil carbon with laser-induced breakdown spectroscopy (LIBS). J. Environ. Qual. 30:2202-2206. (Pubitemid 33134408)
9. Cremers, D.A., and L.J. Radziemski. 2006. Handbook of laser-induced breakdown spectroscopy. John Wiley & Sons, London.
10. Eppler, A.S., D.A. Cremers, D.D. Hickmott, M.J. Ferris, and A.C. Koskelo. 1996. Matrix effects in the detection of Pb and Ba in soils using laser-induced breakdown spectroscopy Appl. Spectrosc. 50:1175-1181. (Pubitemid 126619399)
11. Eriksson, L., E. Johansson, N. Kettaneh-Wold, and S. Wold. 2001. Multi- and megavariate data analysis. Principles and applications. Umetrics Academy, Umeå, Sweden.
12. Essington, M.E. 2003. Soil and water chemistry: An integrative approach. CRC Press, Boca Raton, FL.
13. Essington, M.E., and S.V. Martigod. 1990. Element partitioning in size- and density-fractionated sewage sludge and sludge-amended soil. Soil Sci. Soc. Am. J. 54:385-394.
14. Hilbk-Kortenbruck, E, R. Noll, P. Wintjens, H. Falk, and C. Becker. 2001. Analysis of heavy metals in soils using laser-induced breakdown spectroscopy combined with laser-induced fluorescence. Spectrochim. Acta B 56:933-945.
15. Hossner, L.R. 1996. Dissolution for total elemental analysis. In D.L. Sparks (ed.) Methods of soil analysis. Part 3. SSSA Book Ser. 5. SSSA, ASA, Madison, WI.
16. Hussain, T., M.A. Gondal, Z.H. Yamani, and M.A. Baig. 2007. Measurement of nutrients in green house soil with laser induced breakdown spectroscopy. Environ. Monit. Assess. 124:131-139.
17. Lazic, V., R. Barbini, E Colao, R. Fantoni, and A. Palucci. 2001. Self-absorption model in quantitative laser induced breakdown spectroscopy measurements on soils and sediments. Spectrochim. Acta B 56:807-820.
18. Lee, W.B., J. Wu, Y.I. Lee, and J. Sneddon. 2004. Recent application of laser-induced breakdown spectroscopy: A review of material approaches. Appl. Spectrosc. Rev. 39:27-97.
19. Martin, M.Z., N. Labbé, N. André, R. Harris, M. Ebinger, S.D. Wullschleger, and A. Vass. 2007. High resolution applications of laser-induced breakdown spectroscopy for environmental and forensic applications. Spectrochim. Acta B 62:1426-1432. (Pubitemid 350218210)
20. Martin, M.Z., N. Labbé, N. André, R. Harris, M. Ebinger, S.D. Wullschleger, and A. Vass. 2007. High resolution applications of laser-induced breakdown spectroscopy for environmental and forensic applications. Spectrochim. Acta B 62:1426-1432.
21. Mohamed, W.T.Y., and A. Askar. 2007. Study of the matrix effect on the plasma characterization of heavy elements in soil sediments using LIBS with a portable Echelle spectrometer. Progr. Phys. 1:46-52.
22. Mulla, D.J., and A.B. McBratney. 2000. Soil Spatial Variability. In M.E. Sumner (ed.) Handbook of soil science. CRC Press, Boca Raton, FL.
23. Multari, R.A., L.E. Foster, D.A. Cremers, and M.J. Ferris. 1996. Effect of sample geometry on elemental emissions in laser-induced breakdown spectroscopy. Appl. Spectrosc. 50:1483-1499.
24. SAS Institute. 2005. SAS for Windows. Release 9.1. SAS Institute, Cary, NC.
25. Sirven, J.-B., B. Bousquet, L. Canioni, L. Sarger, S. Tellier, M. Potin-Gautier, and I.L. Hecho. 2006. Qualitative and quantitative investigation of chromium-polluted soils by laser-induced breakdown spectroscopy combined with neural network analysis. Anal. Bioanal. Chem. 385:256-262.
26. Sallé, B., D.A. Cremers, S. Maurice, R.C. Wiens, and P. Fichet. 2005. Evaluation of a compact spectrograph for in-situ and stand-off laser-induced breakdown spectroscopy analyses of geological samples on Mars missions. Spectrochim. Acta B 60:805-815. (Pubitemid 41000033)
27. USEPA. 2007a. SW-846 Methods for the analysis of hazardous waste. ICP-AES Method 60 10C. USEPA, Washington, DC.
28. USEPA. 2007b. SW-846 Methods for the analysis of hazardous waste. XRF Method 6200. USEPA, Washington, DC.
29. Wold, S., M. Sjöström, and L. Eriksson. 2001. PLS-regression: A basic tool of chemometrics. Chemom. Intell. Lab. Syst. 58:109-130.