C-Cl bond cleavage of CH2Cl2 by the zinc(II) complex [Zn(phen)L2] (L = PhC (S) NP (O) (O i Pr)2-) with the formation of [Zn(phen)LCl] and CH2[PhC(S)NP(O)(OiPr)2]2

Inorganic Chemistry Communications

Volumn 12, Issue 9, 2009, Pages 913-915

  Safin, Damir A ^a   Babashkina, Maria G ^a   Klein, Axel ^a   Bolte, Michael ^b   Krivolapov, Dmitriy B ^c   Litvinov, Igor A ^c  

^a UNIVERSITY OF COLOGNE   (Germany)

^b GOETHE UNIVERSITY   (Germany)

^c A E ARBUZOV INSTITUTE OF ORGANIC AND PHYSICAL CHEMISTRY   (Russian Federation)

Author keywords

1,10 Phenanthroline; Bond cleavage; Crystal structure; Phosphorylthiobenzamide; Zn(II) complexes

Indexed keywords

EID: 69249223424     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.07.019     Document Type: Article

References (13)

1. Sokolov F.D., Safin D.A., Zabirov N.G., Zotov P.V., and Cherkasov R.A. Russ. J. Gen. Chem. 75 (2005) 1919
2. Safin D.A., Sokolov F.D., Nöth H., Babashkina M.G., Gimadiev T.R., Galezowska J., and Kozlowski H. Polyhedron 27 (2008) 2022
3. Zhou X.-X., Liu M.-S., Lin X.-M., Fang H.-C., Chen J.-Q., Yang D.-Q., and Cai Y.-P. Inorg. Chim. Acta 362 (2009) 1441
4. Zhang S., Tang Y., Su Y., Lan J., Xie R., and You J. Inorg. Chim. Acta 362 (2009) 1511
5. Balamurugan V., Hundal M.S., and Mukherjee R. Chem. Eur. J. 10 (2004) 1683
6. Zimin M.G., Zabirov N.G., Kamalov R.M., and Pudovik A.N. Zh. Obshch. Khim. 56 (1986) 2352
7. Sokolov F.D., Safin D.A., Zabirov N.G., Brusko V.V., Khairutdinov B.I., Krivolapov D.B., and litvinov I.A. Eur. J. Inorg. Chem. (2006) 2027
8. 2 (614.69): C, 52.76; H, 6.56; N, 4.56. Found: S{cyrillic}, 52.89; N{cyrillic}, 6.47; N, 4.45%.
9. Zabirov N.G., Sokolov F.D., and Cherkasov R.A. Zh. Obshch. Khim. 68 (1998) 1100
10. Sokolov F.D., Brusko V.V., Zabirov N.G., and Cherkasov R.A. Curr. Org. Chem. 10 (2006) 27
11. The X-ray data for [Zn(phen)LCl] were collected on a Bruker Smart Apex II diffractometer. Data were corrected for absorption using SADABS [12] program. The structure was solved by direct method using the SHELXS97 [13] program and refined by the full matrix least-squares using SHELXL97 [13]. All non-hydrogen atoms were refined anisotropically. The hydrogen atoms were located on difference map and refined isotropically.
12. G.M. Sheldrick, SADABS, Program for Empirical X-ray Absorption Correction, Bruker-Nonius, 1990-2004.
13. Sheldrick G.M. Acta Crystallogr. A64 (2008) 112