Size control of polystyrene nodules formed on silica particles in soap-free emulsion polymerization with amphoteric initiator

Colloid and Polymer Science

Volumn 287, Issue 9, 2009, Pages 1051-1056

  Nagao, Daisuke ^a   Ueno, Takuya ^a   Oda, Daisuke ^a   Konno, Mikio ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

Amphoteric initiator; Composite particle; Polystyrene; Raspberry shaped; Silica

Indexed keywords

AMPHOTERIC INITIATOR; AVERAGE SIZE; COMPOSITE PARTICLE; COMPOSITE PARTICLES; DISSOCIATION DEGREE; IONIZABLE GROUPS; PH RANGE; POLYMER PARTICLES; RASPBERRY-SHAPED; SHAPED PARTICLES; SILICA PARTICLES; SILICA SURFACE; SIZE CONTROL; SOAP-FREE EMULSION POLYMERIZATION; SURFACE-MODIFIED; WATER PHASE;

COMPOSITE MATERIALS; EMULSIFICATION; EMULSION POLYMERIZATION; POLYMERS; POLYSTYRENES; SILICA; STYRENE;

AGGLOMERATION;

2,2' AZOBIS [N (2 CARBOXYETHYL) 2,2 METHYLPROPIONAMIDINE]; AMPHOLYTE; POLYSTYRENE; PROPIONAMIDE DERIVATIVE; SILANE DERIVATIVE; SILICON DIOXIDE; SOAP; UNCLASSIFIED DRUG; WATER;

ADSORPTION; ARTICLE; CHEMICAL MODIFICATION; COMPOSITE MATERIAL; CONTROLLED STUDY; EMULSION; PARTICLE SIZE; PH; POLYMERIZATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 69249212301     PISSN: 0303402X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00396-009-2063-7     Document Type: Article

References (23)

1. 2/PMMA composite particles via conventional emulsion polymerization. J Polym Sci A 44:3807-3816. doi: 10.1002/pola.21472
2. 2 nanocomposite particles. J Appl Polym Sci 104:415-421. doi: 10.1002/app. 25172
3. Zeng Z, Yu J, Guo Z (2005) Preparation of polymer/silica composite nanoparticles bearing carboxyl groups on the surface via emulsifier-free emulsion copolymerization. J Polym Sci A 43:2826-2835. doi: 10.1002/ pola.20764
4. 2/ polystyrene nanocomposite particles via miniemulsion polymerization. Langmuir 21:2124-2128. doi: 10.1021/la047652b
5. Wu Q, Wang Z, Kong X, Gu X, Xue G (2008) A ficile strategy for controlling the self-assembly of nanocomposite particles based on colloidal steric stabilization theory. Langmuir 24:7778-7784. doi: 10.1021/la800532q
6. Reculusa S, Poncet-Legrand C, Perro A, Duguet E, Bourgeat-Lami E, Mingotaud C, Ravaine S (2005) Hybrid dissymmetrical colloidal particles. Chem Mater 17:3338-3844. doi: 10.1021/cm050406g
7. Nagao D, Hashimoto M, Hayasaka K, Konno M (2008) Synthesis of anisotropic polymer particles with soap-free emulsion polymerization in the presence of a reactive silane coupling agent. Macromol Rapid Commun 29:1484-1488. doi: 10.1002/marc.200800279
8. Perro A, Reculusa S, Bourgeat-Lami E, Duguet E, Ravaine S (2006) Synthesis of hybrid colloidal particles: From snowman-like to raspberry-like morphologies. Colloids Surf A 284-285:78-83. doi: 10.1016/ j.colsurfa.2005.11.073
9. Guo S, Dong S, Wang E (2008) A general method for the rapid synthesis of hollow metallic or bimetallic nanoelectrocatalysts with urchin like morphology. Chem Eur J 14:4689-4695. doi: 10.1002/chem.200800077
10. Xu Z, Xia A, Wang C, Yang W, Fu S (2007) Synthesis of raspberry-like magnetic polystyrene microspheres. Mater Chem Phys 103:494-499. doi: 10.1016/j.matchemphys.2007.02.074
11. Luna-Xavier J, Guyot A, Bourgeat-Lami E (2004) Preparation of nano-sized silica/poly(methylmethacrylate) composite latexes by heterocoagulation: comparison of three synthetic routes. Polym Int 53:609-617. doi: 10.1002/ pi.1440
12. Reculusa S, Poncet-Legrand C, Ravaine S, Mingotaud C, Duguet E, Bourgeat-Lami E (2002) Syntheses of raspberry like silica/polystyrene materials. Chem Mater 14:2354-2359. doi: 10.1021/cm0116525
13. Ming JW, Wu D, van Benthem R, de With G (2005) Superhydrophobic films from raspberry-like particles. Nano Lett 5:2298-2301. doi: 10.1021/ nl0517363
14. Hong J, Bae WK, Lee H, Oh S, Char K, Caruso F, Cho J (2007) Tunable superhydrophobic and optical properties of colloidal films coated with block copolymer micelles/micelle multilayers. Adv Mater 19:4364-4369. doi: 10.1002/adma.200701362
15. Tsai H, Lee Y (2007) Facile method to fabricate raspberry-like particulate films for superhydrophobic surfaces. Langmuir 23:12687-12693. doi: 10.1021/la702521u
16. Bourgeat-Lami E, Herrera NN, Putaux J, Reculusa S, Perro A, Ravaine S, Mingotaud C, Duguet E (2005) Surface assisted nucleation and growth of polymer latexes on organically-modified inorganic particles. Macromol Symp 229:32-46. doi: 10.1002/masy.200551105
17. Bourgeat-Lami E, Herrera NN, Putaux J, Perro A, Reculusa S, Ravaine S, Duguet E (2007) Designing organic/inorganic colloids by heterophase polymerization. Macromol Symp 248:213-226. doi: 10.1002/masy.200750223
18. Reculusa S, Mingotaud C, Bourgeat-Lami E, Duguet E, Ravaine S (2004) Synthesis of daisy-shaped and multipod-like silica/polystyrene nanocomposites. Nano Lett 4:1677-1682. doi: 10.1021/nl049161h
19. Gu S, Inukai S, Konno M (2002) Preparation of monodisperse, micron-sized polystyrene particles with an amphoteric initiator in soap free polymerization. J Chem Eng Jpn 35:977-981
20. Gu S, Akama H, Nagao D, Kobayashi Y, Konno M (2004) Preparation of micrometer-sized poly(methyl methacrylate) particles with amphoteric initiator in aqueous media. Langmuir 20:7948-7951. doi: 10.1021/la049280c
21. Yamada Y, Sakamoto T, Gu S, Konno M (2005) Soap-free synthesis for producing highly monodisperse, micrometer-sized polystyrene particles up to 6 μm. J Colloid Interface Sci 281:249-252. doi: 10.1016/ j.jcis.2004.08.030
22. Nagao D, Sakamoto T, Konno H, Gu S, Konno M (2006) Preparation of micrometer-sized polymer particles with control of initiator dissociation during soap-free emulsion polymerization. Langmuir 22:10958-10962. doi: 10.1021/la061451l
23. Nagao D, Yokoyama M, Yamauchi N, Matsumoto H, Kobayashi Y, Konno M (2008) Synthesis of highly monodisperse particles composed of a magnetic core and fluorescent shell. Langmuir 24:9804-9808. doi: 10.1021/la801364w