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Volumn 12, Issue 9, 2009, Pages 890-894

Unique direct synthesis of cyanide-bridged Fe2Cu2 molecular squares by destruction of sodium nitroprusside

Author keywords

Copper(II); Molecular squares; Nitroprusside anion

Indexed keywords


EID: 69249212128     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.07.006     Document Type: Article
Times cited : (9)

References (39)
  • 23
    • 69249223298 scopus 로고    scopus 로고
    • note
    • -1): 3070(m), 3030(m), 2120(m), 2100(m), 2080(s), 2050(m), 1910(m), 1610(w), 1480(s), 1455(s), 1320(w), 1260 (w), 1170(w), 1030(vw), 860(w), 840(w) 790(vs), 740(m), 680(w). The complex is stable in air and soluble in dmso and dmf, but insoluble in water.
  • 32
    • 69249235661 scopus 로고    scopus 로고
    • note
    • 2- block is statistically disordered on a crystallographic inversion center over two positions with the site occupancies of atoms of the cyanide and NO groups of 0.5. The uncoordinated NCS anions also were found to be disordered and refined to an occupancy factor of 50%. Residual peaks in the difference maps were modelled as disordered free water molecules, each assigned site occupancies of 0.5.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.