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Volumn 54, Issue 8, 2009, Pages 2158-2169

Review of the apparent molar heat capacities of NaCl(aq), HCl(aq), and NaOH(aq) and their representation using the pitzer model at temperatures from (298.15 to 493.15) K

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROLYTES; FREE ENERGY; GIBBS FREE ENERGY; POLYNOMIALS; SODIUM CHLORIDE; SODIUM HYDROXIDE; SPECIFIC HEAT OF SOLIDS; SYSTEMATIC ERRORS;

EID: 69049104626     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je8009946     Document Type: Review
Times cited : (4)

References (43)
  • 1
    • 0002437410 scopus 로고    scopus 로고
    • Temperature corrections to thermodynamic data and enthalpy calculations
    • Grenthe I., Puigdomenech, I., Eds.; OECD Nuclear Energy Agency
    • Puigdomenech, I.; Rard, J. A.; Plyasunov, A. V.; Grenthe, I. Temperature Corrections to Thermodynamic data and Enthalpy Calculations. In Modelling in Aquatic Chemistry; Grenthe, I., Puigdomenech, I., Eds.; OECD Nuclear Energy Agency: 1997; pp 427.
    • (1997) Modelling in Aquatic Chemistry , pp. 427
    • Puigdomenech, I.1    Rard, J.A.2    Plyasunov, A.V.3    Grenthe, I.4
  • 3
    • 0000712590 scopus 로고
    • Thermodynamics of aqueous aluminate ion: standard partial molar heat capacities and volumes of tetrahydroxyaluminate(1-)(aq) from 10 to 55 degree.C
    • Hovey, J. K.; Hepler, L. G.; Tremaine, P. R. Thermodynamics of aqueous aluminate ion: standard partial molar heat capacities and volumes of tetrahydroxyaluminate(1-)(aq) from 10 to 55 degree.C. J. Phys. Chem. 1988, 92, 1323-1332.
    • (1988) J. Phys. Chem. , vol.92 , pp. 1323-1332
    • Hovey, J.K.1    Hepler, L.G.2    Tremaine, P.R.3
  • 5
    • 0001296065 scopus 로고    scopus 로고
    • Thermodynamics of hydration of a 4+ aqueous ion: Partial molar heat capacities and volumes of aqueous thorium(iv) from 10 to 55°C
    • Hovey, J. K. Thermodynamics of Hydration of a 4+ Aqueous Ion: Partial Molar Heat Capacities and Volumes of Aqueous Thorium(IV) from 10 to 55 °C. J. Phys. Chem. B 1997, 101, 4321-4334.
    • (1997) J. Phys. Chem. B , vol.101 , pp. 4321-4334
    • Hovey, J.K.1
  • 6
    • 0001599498 scopus 로고    scopus 로고
    • Apparent molar volumes and heat capacities of aqueous acetic acid and sodium acetate at temperatures from T = 278.15 K to T = 393.15 K at the pressure 0.35 MPa
    • Ballerat-Busserolles, K.; Ford, T. D.; Call, T. G.; Woolley, E. M. Apparent molar volumes and heat capacities of aqueous acetic acid and sodium acetate at temperatures from T ) 278.15 K to T ) 393.15 K at the pressure 0.35 MPa. J. Chem. Thermodyn. 1999, 31, 741-762.
    • (1999) J. Chem. Thermodyn , vol.31 , pp. 741-762
    • Ballerat-Busserolles, K.1    Ford, T.D.2    Call, T.G.3    Woolley, E.M.4
  • 7
    • 33847167601 scopus 로고    scopus 로고
    • Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate, strontium nitrate, and manganese nitrate at temperatures from 278.15 to 393.15 K and at the pressure 0.35 MPa
    • Jones, J. S.; Ziemer, S. P.; Brown, B. R.; Woolley, E. M. Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate, strontium nitrate, and manganese nitrate at temperatures from 278.15 to 393.15 K and at the pressure 0.35 MPa. J. Chem. Thermodyn. 2007, 39, 550-560.
    • (2007) J. Chem. Thermodyn , vol.39 , pp. 550-560
    • Jones, J.S.1    Ziemer, S.P.2    Brown, B.R.3    Woolley, E.M.4
  • 8
    • 33646903363 scopus 로고
    • Thermodynamics of electrolytes. I. Theoretical basis and general equations
    • Pitzer, K. S. Thermodynamics of electrolytes. I. Theoretical basis and general equations. J. Phys. Chem. 1973, 77, 268-277.
    • (1973) J. Phys. Chem. , vol.77 , pp. 268-277
    • Pitzer, K.S.1
  • 9
    • 33646923521 scopus 로고
    • Thermodynamics of electrolytes. 12. Dielectric properties of water and Debye-huckel parameters to 350.degree.C and 1 kbar
    • Bradley, D. J.; Pitzer, K. S. Thermodynamics of electrolytes. 12. Dielectric properties of water and Debye-Huckel parameters to 350.degree.C and 1 kbar. J. Phys. Chem. 1979, 83, 1599-1603.
    • (1979) J. Phys. Chem. , vol.83 , pp. 1599-1603
    • Bradley, D.J.1    Pitzer, K.S.2
  • 10
    • 0039377478 scopus 로고    scopus 로고
    • A formulation for the static permittivity of water and steam at temperatures from 238 to 873 K at pressures up to 1200 MPa, including derivatives and debye-huckel coefficients
    • Fernandez, D. P.; Goodwin, A. R. H.; Lemmon, E. W.; Sengers, J. M. H. L.; Williams, R. C. A formulation for the static permittivity of water and steam at temperatures from 238 to 873 K at pressures up to 1200 MPa, including derivatives and Debye-Huckel coefficients. J. Phys. Chem. Ref. Data 1997, 26, 1125-1166.
    • (1997) J. Phys. Chem. Ref. Data , vol.26 , pp. 1125-1166
    • Fernandez, D.P.1    Goodwin, A.R.H.2    Lemmon, E.W.3    Sengers, J.M.H.L.4    Williams, R.C.5
  • 11
    • 0036558273 scopus 로고    scopus 로고
    • Heat capacities of concentrated aqueous solutions of sodium sulfate, sodium carbonate, and sodium hydroxide at 25°c
    • Magalhaes, M. C. F.; Konigsberger, E.; May, P. M.; Hefter, G. Heat Capacities of Concentrated Aqueous Solutions of Sodium Sulfate, Sodium Carbonate, and Sodium Hydroxide at 25 °C. J. Chem. Eng. Data 2002, 47, 590-598.
    • (2002) J. Chem. Eng. Data , vol.47 , pp. 590-598
    • Magalhaes, M.C.F.1    Konigsberger, E.2    May, P.M.3    Hefter, G.4
  • 12
    • 0000139728 scopus 로고
    • Apparent molal volumes and heat capacities of some sulfates and carbonates in water at 25°C
    • Perron, G.; Desnoyers, J. E.; Millero, F. J. Apparent Molal Volumes and Heat Capacities of Some Sulfates and Carbonates in Water at 25 °C. Can. J. Chem. 1975, 53, 1134-1138.
    • (1975) Can. J. Chem. , vol.53 , pp. 1134-1138
    • Perron, G.1    Desnoyers, J.E.2    Millero, F.J.3
  • 14
    • 0000169232 scopus 로고
    • An Algorithm for least-squares estimation of nonlinear parameters
    • Marquardt, D. An Algorithm for Least-Squares Estimation of Nonlinear Parameters. SIAM J. Appl. Mathematics 1963, 11, 431-441.
    • (1963) SIAM J. Appl. Mathematics , vol.11 , pp. 431-441
    • Marquardt, D.1
  • 15
    • 0000655020 scopus 로고    scopus 로고
    • Modeling the heat capacities of aqueous 1-1 electrolyte solutions with pitzer's equations
    • Criss, C. M.; Millero, F. J. Modeling the Heat Capacities of Aqueous 1-1 Electrolyte Solutions with Pitzer's Equations. J. Phys. Chem. 1996, 100, 1288-1294.
    • (1996) J. Phys. Chem. , vol.100 , pp. 1288-1294
    • Criss, C.M.1    Millero, F.J.2
  • 16
    • 0000787131 scopus 로고
    • Reexamination of the heat capacities obtained by flow microcalorimetry. Recommendation for the use of a chemical standard
    • Desnoyers, J. E.; de Visser, C.; Perron, G.; Picker, P. Reexamination of the Heat Capacities Obtained by Flow Microcalorimetry. Recommendation for the Use of a Chemical Standard. J. Solution Chem. 1976, 5, 605-616.
    • (1976) J. Solution Chem. , vol.5 , pp. 605-616
    • Desnoyers, J.E.1    De Visser, C.2    Perron, G.3    Picker, P.4
  • 17
    • 0001078724 scopus 로고
    • Heat capacity of aqueous sodium chloride from 320 to 600 K measured with a new flow calorimeter
    • Smith-Magowan, D.; Wood, R. H. Heat capacity of aqueous sodium chloride from 320 to 600 K measured with a new flow calorimeter. J. Chem. Thermodyn. 1981, 13, 1047-1073.
    • (1981) J. Chem. Thermodyn , vol.13 , pp. 1047-1073
    • Smith-Magowan, D.1    Wood, R.H.2
  • 18
    • 0001633031 scopus 로고
    • Specific heats of aqueous solutions of NaCl, NaBr, and KCl: Comparisons with related thermal properties
    • Tanner, J. E.; Lamb, F. W. Specific heats of aqueous solutions of NaCl, NaBr, and KCl: Comparisons with related thermal properties. J. Solution Chem. 1978, 7, 303-316.
    • (1978) J. Solution Chem. , vol.7 , pp. 303-316
    • Tanner, J.E.1    Lamb, F.W.2
  • 19
    • 0001597022 scopus 로고
    • The apparent molar heat capacities and volumes of aqueous NaCl from 0.01 to 3 mol kg-1 in the temperature range 274.65 to 318.15 K
    • Perron, G.; Fortier, J.; Desnoyers, J. E. The apparent molar heat capacities and volumes of aqueous NaCl from 0.01 to 3 mol kg-1 in the temperature range 274.65 to 318.15 K. J. Chem. Thermodyn. 1975, 7, 1177-1184.
    • (1975) J. Chem. Thermodyn , vol.7 , pp. 1177-1184
    • Perron, G.1    Fortier, J.2    Desnoyers, J.E.3
  • 20
    • 0001882696 scopus 로고
    • Apparent molar heat capacity and other thermodynamic properties of aqueous potassium chloride solutions to high temperatures and pressures
    • Pabalan, R. T.; Pitzer, K. S. Apparent molar heat capacity and other thermodynamic properties of aqueous potassium chloride solutions to high temperatures and pressures. J. Chem. Eng. Data 1988, 33, 354-362.
    • (1988) J. Chem. Eng. Data , vol.33 , pp. 354-362
    • Pabalan, R.T.1    Pitzer, K.S.2
  • 21
    • 0019679939 scopus 로고
    • Theoretical prediction of the thermodynamic behavior of aqueous-electrolytes at high- pressures and temperatures 0.4. calculation of activity-coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600-degrees-c and 5 kb
    • Helgeson, H. C.; Kirkham, D. H.; Flowers, G. C. Theoretical Prediction of the Thermodynamic Behavior of Aqueous-Electrolytes at High- Pressures and Temperatures 0.4. Calculation of Activity-Coefficients, Osmotic Coefficients, and Apparent Molal and Standard and Relative Partial Molal Properties to 600-Degrees-C and 5 Kb. Am. J. Sci. 1981, 281, 1249-1516.
    • (1981) Am. J. Sci. , vol.281 , pp. 1249-1516
    • Helgeson, H.C.1    Kirkham, D.H.2    Flowers, G.C.3
  • 22
    • 0024190666 scopus 로고
    • Calculation of the thermodynamic and transport-properties of aqueous species at high-pressures and temperatures - correlation algorithms for ionic species and equation of state predictions to 5-kb and 1000-degrees-C
    • Shock, E. L.; Helgeson, H. C. Calculation of the Thermodynamic and Transport-Properties of Aqueous Species at High-Pressures and Temperatures - Correlation Algorithms for Ionic Species and Equation of State Predictions to 5-Kb and 1000-Degrees-C. Geochim. Cosmochim. Acta 1988, 52, 2009-2036.
    • (1988) Geochim. Cosmochim. Acta , vol.52 , pp. 2009-2036
    • Shock, E.L.1    Helgeson, H.C.2
  • 23
    • 0002815416 scopus 로고
    • Calculation of the thermodynamic and transport-properties of aqueous species at high-pressures and temperatures - revised equations of state for the standard partial molal properties of ions and electrolytes.
    • Tanger, J. C.; Helgeson, H. C. Calculation of the Thermodynamic and Transport-Properties of Aqueous Species at High-Pressures and Temperatures - Revised Equations of State for the Standard Partial Molal Properties of Ions and Electrolytes. Am. J. Sci. 1988, 288, 19-98.
    • (1988) Am. J. Sci. , vol.288 , pp. 19-98
    • Tanger, J.C.1    Helgeson, H.C.2
  • 24
    • 61449243879 scopus 로고    scopus 로고
    • Calculation of the relative metastabilities of proteins using the CHNOSZ software package
    • Dick, J. Calculation of the relative metastabilities of proteins using the CHNOSZ software package. Geochem. Trans. 2008, 9, 10.
    • (2008) Geochem. Trans. , vol.9 , pp. 10
    • Dick, J.1
  • 25
    • 0036592296 scopus 로고    scopus 로고
    • The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use
    • Wagner, W.; Pruss, A. The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. J. Phys. Chem. Ref. Data 2002, 31, 387-535.
    • (2002) J. Phys. Chem. Ref. Data , Issue.31 , pp. 387-535
    • Wagner, W.1    Pruss, A.2
  • 26
    • 84913425878 scopus 로고
    • The dielectric constant of water and debye-huckel limiting law slopes
    • Archer, D. G.; Wang, P. M. The dielectric constant of water and Debye-Huckel limiting law slopes. J. Phys. Chem. Ref. Data 1990, 19, 371-411.
    • (1990) J. Phys. Chem. Ref. Data , vol.19 , pp. 371-411
    • Archer, D.G.1    Wang, P.M.2
  • 27
    • 0035545222 scopus 로고    scopus 로고
    • Thermodynamics for ionization of water at temperatures from 278.15 to 393.15 K and at the pressure 0.35 MPa: apparent molar volumes of aqueous KCl, KOH, and NaOH and apparent molar heat capacities of aqueous HCl, KCl, KOH, and NaOH
    • Patterson, B. A.; Call, T. G.; Jardine, J. J.; Origlia-Luster, M. L.; Woolley, E. M. Thermodynamics for ionization of water at temperatures from 278.15 to 393.15 K and at the pressure 0.35 MPa: apparent molar volumes of aqueous KCl, KOH, and NaOH and apparent molar heat capacities of aqueous HCl, KCl, KOH, and NaOH. J. Chem. Thermodyn. 2001, 33, 1237-1262.
    • (2001) J. Chem. Thermodyn , vol.33 , pp. 1237-1262
    • Patterson, B.A.1    Call, T.G.2    Jardine, J.J.3    Origlia-Luster, M.L.4    Woolley, E.M.5
  • 28
    • 0002880599 scopus 로고
    • The apparent molar heat capacity of aqueous hydrochloric acid from 10 to 140°C
    • Tremaine, P. R.; Sway, K.; Barbero, J. A. The apparent molar heat capacity of aqueous hydrochloric acid from 10 to 140°C. J. Solution Chem. 1986, 15, 1-22.
    • (1986) J. Solution Chem. , vol.15 , pp. 1-22
    • Tremaine, P.R.1    Sway, K.2    Barbero, J.A.3
  • 29
    • 0001506197 scopus 로고
    • Heat capacities of aqueous acetic acid, sodium acetate, ammonia, and ammonium chloride at 283.15, 298.15, and 313.15 K: δCp° for ionization of acetic acid and for dissociation of ammonium ion
    • Allred, G. C.; Woolley, E. M. Heat capacities of aqueous acetic acid, sodium acetate, ammonia, and ammonium chloride at 283.15, 298.15, and 313.15 K: δCp° for ionization of acetic acid and for dissociation of ammonium ion. J. Chem. Thermodyn. 1981, 13, 155-164.
    • (1981) J. Chem. Thermodyn , vol.13 , pp. 155-164
    • Allred, G.C.1    Woolley, E.M.2
  • 30
    • 0000726565 scopus 로고    scopus 로고
    • Volumes and heat capacities of aqueous solutions of hydrochloric acid at temperatures from 298.15 to 623 K and pressures to 28 MPa
    • Sharygin, A. V.; Wood, R. H. Volumes and heat capacities of aqueous solutions of hydrochloric acid at temperatures from 298.15 to 623 K and pressures to 28 MPa. J. Chem. Thermodyn. 1997, 29, 125-148.
    • (1997) J. Chem. Thermodyn , Issue.29 , pp. 125-148
    • Sharygin, A.V.1    Wood, R.H.2
  • 32
    • 33947482929 scopus 로고
    • The Thermodynamic properties of high temperature aqueous solutions. IV. Entropies of the ions up to 200° and the correspondence principle
    • Criss, C. M.; Cobble, J. W. The Thermodynamic Properties of High Temperature Aqueous Solutions. IV. Entropies of the Ions up to 200° and the Correspondence Principle. J. Am. Chem. Soc. 1964, 86, 5385-5390.
    • (1964) J. Am. Chem. Soc. , vol.86 , pp. 5385-5390
    • Criss, C.M.1    Cobble, J.W.2
  • 33
    • 0001418833 scopus 로고
    • The enthalpy of dilution and apparent molar heat capacity of NaOH(aq) to 523 K and 40 MPa
    • Simonson, J. M.; Mesmer, R. E.; Rogers, P. S. Z. The enthalpy of dilution and apparent molar heat capacity of NaOH(aq) to 523 K and 40 MPa. J. Chem. Thermodyn. 1989, 21, 561-584.
    • (1989) J. Chem. Thermodyn , vol.21 , pp. 561-584
    • Simonson, J.M.1    Mesmer, R.E.2    Rogers, P.S.Z.3
  • 34
    • 0002854486 scopus 로고
    • Apparent molar heat-capacity and relative enthalpy of aqueous naoh between 323 and 523 K
    • Conti, G.; Gianni, P.; Papini, A.; Matteoli, E. Apparent Molar Heat- Capacity and Relative Enthalpy of Aqueous NaOH between 323 and 523 K. J. Solution Chem. 1988, 17, 481-497.
    • (1988) J. Solution Chem. , vol.17 , pp. 481-497
    • Conti, G.1    Gianni, P.2    Papini, A.3    Matteoli, E.4
  • 35
    • 0000303455 scopus 로고    scopus 로고
    • Calibration of a fixed-cell temperature-scanning calorimeter to measure precisesolution heat capacities from 275 to 398 K at 0.35 MPa
    • Ballerat-Busserolles, K.; Origlia, M. L.; Woolley, E. M. Calibration of a fixed-cell temperature-scanning calorimeter to measure precisesolution heat capacities from 275 to 398 K at 0.35 MPa. Thermochim. Acta 2000, 347, 3-7.
    • (2000) Thermochim. Acta , vol.347 , pp. 3-7
    • Ballerat-Busserolles, K.1    Origlia, M.L.2    Woolley, E.M.3
  • 37
    • 84953649642 scopus 로고
    • Ion product of water substance, 0-1000 °C, 1-10, 000 bar. New international formulation and its background
    • Marshall, W. L.; Franck, E. U. Ion product of water substance, 0- 1000 °C, 1-10, 000 bar. New international formulation and its background. J. Phys. Chem. Ref. Data 1981, 10, 295.
    • (1981) J. Phys. Chem. Ref. Data , vol.10 , pp. 295
    • Marshall, W.L.1    Franck, E.U.2
  • 38
    • 0000087138 scopus 로고
    • Self-ionization of water at high temperature and thermodynamic properties of ions
    • Pitzer, K. S. Self-ionization of water at high temperature and thermodynamic properties of ions. J. Phys. Chem. 1982, 86, 4704-4708.
    • (1982) J. Phys. Chem. , vol.86 , pp. 4704-4708
    • Pitzer, K.S.1
  • 40
    • 0000716091 scopus 로고
    • Thermodynamic data for ligand interaction with protons and metal ions in aqueous solutions at high temperatures
    • Chen, X.; Izatt, R. M.; Oscarson, J. L. Thermodynamic data for ligand interaction with protons and metal ions in aqueous solutions at high temperatures. Chem. ReV. 1994, 94, 467-517.
    • (1994) Chem. ReV. , vol.94 , pp. 467-517
    • Chen, X.1    Izatt, R.M.2    Oscarson, J.L.3
  • 41
    • 0029639074 scopus 로고
    • Theoretical calculation of the water ion product Kw
    • Tawa, G. J.; Pratt, L. R. Theoretical calculation of the water ion product KW. J. Am. Chem. Soc. 1995, 117, 1625-1628.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 1625-1628
    • Tawa, G.J.1    Pratt, L.R.2
  • 42
    • 33748503596 scopus 로고    scopus 로고
    • The ionization constant of water over wide ranges of temperature and density
    • Bandura, A. V.; Lvov, S. N. The ionization constant of water over wide ranges of temperature and density. J. Phys. Chem. Ref. Data 2006, 35, 16-30.
    • (2006) J. Phys. Chem. Ref. Data , vol.35 , pp. 16-30
    • Bandura, A.V.1    Lvov, S.N.2
  • 43
    • 44949106192 scopus 로고    scopus 로고
    • Heat capacities of aqueous solutions of sodium hydroxide and water ionization up to 300 °C at 10 MPa
    • Schrödle, S.; Königsberger, E.; May, P. M.; Hefter, G. Heat capacities of aqueous solutions of sodium hydroxide and water ionization up to 300 °C at 10 MPa. Geochim. Cosmochim. Acta 2008, 72, 3124-3138.
    • (2008) Geochim. Cosmochim. Acta , vol.72 , pp. 3124-3138
    • Schrödle, S.1    Königsberger, E.2    May, P.M.3    Hefter, G.4


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