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The presence of CIS-N2F2 was established from its Raman bands at 354(co, 729(sh, 888(co, 946(5, and 1519(co) cm, where the abbreviations denote coincidence (co) and shoulder (sh, The bands at 354 and 888 cm- are coincident with the [δ(N1S1F2, δ(F1S1F3, δ(N2S2F6, δ(F4S2F5, and [δ(S1F2-S1F3, δ(S2F6-S2F4, bands of F3S, N≡SF3)2, and the band at 1519 cm -1 is coincident with the v(S≡N) band of unreacted F4S=N-Xe, N≡SF3, The presence of cis-N2F2 after pumping at -50 °C was surprising in view of the vapor-pressure of CIS-N2F2 at -50 °C 1.19 × 104 mm Hg, suggesting it may be adducted to unreacted F4S=NXe+ remaining in the product mixture: Zaborowski, L. M, De Marco, R. A
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