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17
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68949142512
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Compound 8 was prepared by treating 7 (1.00 equiv) with 9-BBN (1.00 equiv) in [D6]benzene. Hydroboration was complete after Standing for 22 h at RT. 1HNMR (499.8 MHz, D6]benzene, 25°C, δ, 0.49 (s, 3H; ZrCH3, 1.20 (m, 2H; 9-BBN, 1.42 (m, 2H; BCH2, 1.64-1.89 (m, 12H; 9-BBN, 1.75 (m, 2H, CH 2, 2.39 (m, 2H; C5H 4CH2, 5.02 (m, 2H; α-C5H4, 5.38 (m, 2H; β-C5H4, 5.40ppm (s, 10H; Cp, 13C{1H} NMR (125.7 MHz, D6]benzene, 25°C, δ, 16.7 (ZrCH3, 23.6 (2×CH2 9-BBN, 27.5 (CH2, 28.5 (br; BCH2, 31.5 (br; CH9-BBN, 33.5 (4×CH29-BBN, 33.8 (C5H4CH2, 107.5 β-C5H4
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15Zr: C 51.50, H 2.40; found: C 51.23, H 2.30.
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