Flame retardant study of cotton coated with intumescents: Kinetics and effect of metal ions

Journal of Scientific and Industrial Research

Volumn 68, Issue 6, 2009, Pages 548-554

  Dahiya, J B ^a   Kumar, Krishan ^a  

^a GURU JAMBHESHWAR UNIVERSITY OF SCIENCE AND TECHNOLOGY   (India)

Author keywords

Cotton Fabric; Flame retardant; Intumescent; Kinetics; Thermal degradation

Indexed keywords

CHAR YIELD; COATED FABRICS; COATS-REDFERN METHOD; DIFFERENTIAL-THERMAL ANALYSIS; INTUMESCENT; LIMITING OXYGEN INDEX; NANO CLAYS; PURE COTTON FABRICS; THERMAL DEGRADATION; THERMAL DEGRADATIONS; THERMOGRAVIMETRY;

ACTIVATION ENERGY; CHROMIUM; COTTON; COTTON FABRICS; DEGRADATION; FIRE FIGHTING EQUIPMENT; FLAMMABILITY; METAL IONS; OXYGEN; PROTECTIVE COATINGS; THERMOGRAVIMETRIC ANALYSIS; ZINC;

FABRICS;

COTTON; KINETICS; OXIDATION; THERMAL DECOMPOSITION; THERMOGRAVIMETRY;

GOSSYPIUM HIRSUTUM;

EID: 68649097560     PISSN: 00224456     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (24)

1. Fire Statistics United Kingdom (Government Statistical Office London, UK) 1998.
2. lomakin S M, Zaikov G E & Artsis M I, Advances in Nylon 6,6 flame retardancy, IntJ Polm Mater, 32 (1996) 173-202.
3. Camino G, in, Fire Retardant Polymeric Materials, edited by G Nelson (ACS, USA) 1995, 461-492 (chap 10).
4. Kandola B K, Horrocks A R, Price D & Coleman G V, Flame - retardant treatments of cellulose and their influence on the mechanism of cellulose pyrolysis, J M V-Rev Macromol Chem Phys, C36 (1996) 721-794. (Pubitemid 126567367)
5. Gao M, Sun C & Zhu K, Thermal degradation of wood treated with guanidine in air, J Therm Anal Cal, 75 (2004) 221-232.
6. Tian C M, Xie J X, Guo H Z & Xu J Z, The effect of metal ions on thermal oxidative degradation of cotton cellulose ammonium phosphate, J Therm Anal Cal, 73 (2003) 827-834.
7. Horrocks A R, Development in flame retardants for heat and fire resistant textiles-the role of char formation and intumescence, Polym Degrad Stab, 54 (1996) 143-154.
8. Kandola B K & Horrocks A R, Complex char formation in flame-retarded fibre-intumescent combinations: physical and chemical nature of char, Text Res J, 69 (1999) 374-381.
9. Kandola B K & Horrocks A R, Complex char formation in flame-retarded fibre-intumescent combinations-IV.Mass loss and thermal barrier properties, Fire Mater, 24 (2000) 265-275.
10. Horrocks, A R & Price, D, Fire Retardant Materials (Woodhead Publication Ltd, England) 2001,425.
11. Stein, B, Reynolds, J S, Grondzik, W T, & Kwok, A G, Mechanical and Electrical Equipment for Buildings, 10th edn (Wiley & Sons, Germany) 2005, 1724.
12. Coats A W & Redfern J P, Kinetic parameters from thermodynamic data. Nature, 201 (1964) 68-69.
13. Dahiya J B & Rana S, Thermal degradation and morphological studies on cotton cellulose modified with various arylphosphorodichloridites, Polym Int, 53 (2004) 995-1002. (Pubitemid 38884200)
14. Kaur B, Jain R K, Gur IS & Bhatnagar H L, Thermal stability of phosphorylated cellulose modified with various transition metals, J Anal Appl Pyrol, 9 (1986) 173-206. (Pubitemid 16505586)
15. Nada A M A, Yousef H A & El-Gohary S, Thermal degradation of hydrolysed & oxidized lignins, J Therm Anal Cal, 68 (2002) 265-273. (Pubitemid 34515068)
16. Kandola B K & Horrocks A R, Complex char formation in flame-retarded fibre- intumescent combinations-II. Thermal analytical studies, Polym DegradStab, 54 (1996) 289-303.
17. 2 & CO evolution from cotton and flame retarded cotton: part 2. Behaviour of single layer fabrics in air at elevated temperatures, J Fire Sci, 8 (1990) 135-151.
18. Davies P J, Horrocks A R & Alderson A, The sensitization of thermal decomposition of ammonium polyphosphate by selected metal ions and their potential for improved cotton fabric flame retardancy, Polym Degrad Stab, 88 (2005) 114-122. (Pubitemid 40245007)
19. Price D, Horrocks A R, Akalin M & Faroq A A, Influence of flame retardants on the mechanism of pyrolysis of cotton (cellulose) fabrics in air, J Anal Appl Pyrol, 40-41 (1997) 511-524. (Pubitemid 127393559)
20. Horrocks A R, Price D & Akalin M, FTIR analysis of gases evolved from cotton and flame retarded cotton fabrics pyrolysed in air, Polym Degrad Stab, 52 (1996) 205-213. (Pubitemid 126373281)
21. Sekiguchi Y & Shafizadeh F, The effect of inorganic additives on the formation, composition & combustion of cellulosic char, J Appl Polym Sci, 29 (1984) 1267-1286. (Pubitemid 14544361)
22. Soares S, Camino G & Levchik S, Comparative study of the thermal decomposition of pure cellulose and pulp paper, Polym Degrad Stab, 49 (1995) 275-283.
23. Jimenez M, Duquesne S & Bourbigot S, Intumescent fire protecting coating: Toward a better understanding of their mechanism of action, Thermochim Acta, 449 (2006) 16-26. (Pubitemid 44415923)
24. Lecoeur E, Vroman I, Bourbigot S & Delobel R, Optimization of monoguanidine dihydrogen phosphate and aminopropylethoxysilane based flame retardant formulations for cotton, Polym Degrad Stab, 91 (2006) 1909-1914. (Pubitemid 44262277)