Ambient temperature Atom Transfer Radical copolymerization of tetrahydrofurfuryl methacrylate and methyl methacrylate: Reactivity ratio determination

European Polymer Journal

Volumn 45, Issue 9, 2009, Pages 2685-2694

  Rajendrakumar, Kannapiran ^a   Dhamodharan, R ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

Author keywords

Ambient temperature ATRP; Cross linking; Monomer catalyst interaction; Reactivity ratio; Tetrahydrofurfuryl methacrylate

Indexed keywords

AMBIENT TEMPERATURE ATRP; AMBIENT TEMPERATURES; ATOM TRANSFER RADICAL COPOLYMERIZATION; BULK POLYMERIZATION; CATALYTIC SYSTEM; CONVENTIONAL FREE-RADICAL POLYMERIZATION; COPOLYMER COMPOSITIONS; HETEROCYCLIC MONOMERS; IR SPECTROSCOPY; KELEN-TUDOS METHOD; METHYL METHACRYLATES; OXYGEN ATOM; RAPID POLYMERIZATION; REACTIVITY RATIO; TETRAHYDROFURFURYL; TETRAHYDROFURFURYL METHACRYLATE; TETRAHYDROFURFURYL METHACRYLATES;

ACRYLIC MONOMERS; ATOMS; CATALYSIS; CATALYSTS; COPOLYMERIZATION; ESTERS; FREE RADICAL POLYMERIZATION; FREE RADICALS; MONOMERS; NUCLEAR MAGNETIC RESONANCE; OXYGEN; POLYMERS; TEMPERATURE;

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 68549101692     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.05.025     Document Type: Article

References (28)

1. Matyjaszewski K., and Xia J.H. Atom transfer radical polymerization. Chem Rev 101 (2001) 2921-2990
2. Kamigaito M., Ando T., and Sawamoto M. Metal catalyzed living radical polymerization. Chem Rev 101 (2001) 3689-3746
3. Ramakrishnan A., and Dhamodharan R. Facile synthesis of ABC and CBABC multiblock copolymers of styrene, tert-butyl acrylate and methyl methacrylate via room temperature ATRP of MMA. Macromolecules 36 (2003) 1039-1046
4. Munirasu S., and Dhamodharan R. Very rapid copper-mediated atom transfer radical polymerization of benzyl methacrylate at ambient temperature. J Polym Sci, Part A: Polym Chem 42 (2004) 1053-1057
5. Dayananda K., Ramakrishnan A., and Dhamodharan R. Synthesis and characterization of block copolymers of P(MMA-b-n-BA-b-MMA) via ambient temperature ATRP of MMA. J Macromol Sci Pure Appl Chem A42 (2005) 471-484
6. Jeetan L., Harrison S., Mantovani G., and Haddleton D.M. Copper mediated living radical polymerization: interactions between monomer and catalyst. Dalton Trans (2003) 4175-4180
7. Kavitha A.A., Choudhury A., and Singha N.K. Controlled radical polymerization of furfuryl methacrylate. Macromol Symp 240 (2006) 232-237
8. Kavitha A.A., Choudhury A., and Singha N.K. A tailor made polymethacrylate bearing a reactive diene in reversible diels-alder reaction. J Polym Sci, Part A: Polym Chem 45 (2007) 4441-4449
9. Kavitha A.A., Choudhury A., and Singha N.K. Atom transfer radical copolymerizationof furfuryl methacrylate (FMA) and methyl methacrylate(MMA): a thermally amendable copolymer. Macromol Chem Phys 208 (2007) 2569-2577
10. Krishnan R., and Srinivasan K.S.V.C. Ontrolled/"Living" polymerization of glycidyl methacrylate at ambient temperature. Macromolecules 36 (2003) 1769-1771
11. Cañamero P.F., Fuente J.L., Madruga E.L., Garcia MF M., and Davy K.W.M. Atom transfer radical polymerization of glycidyl methacrylate: a functional monomer. Macromol Chem Phys 205 (2004) 2221-2228
12. Patel M.P., Braden M., and Davy K.W.M. Polymerization shrinkage of methacrylate esters. Biomaterials 8 (1987) 53-56
13. Nazhat S.N., Parkar S., Patel M.P., and Braden M. Isoprene-styrene copolymer elastomer and tetrahydrofurfuryl methacrylate mixtures for soft prosthetic applications. Biomaterials 22 (2001) 411-416
14. Phuong Y.G., David J.T.H., and Whittaker A.K. A study of copolymerization of hydroxyethyl methacrylate and tetrahydrofurfuryl methacrylate. J Polym Sci, Part A: Polym Chem 37 (1999) 3730-3737
15. Lee S.Y., Loh K.Y., Leong L.S., and Goh S.H. Copolymerizations of tetrahydrofurfuryl methacrylate with styrene and p-methyl styrene. Eur Polym J 3 (1992) 229-232
16. Phuong Y.G., David J.T.H., O'Donnel J.H., Pomery P.J., and Whittaker A.K. The copolymerization of tetrahydrofurfuryl methacrylate and methyl methacrylate. Polym Gels Networks 4 (1996) 253-256
17. 12 or aspirin. Polym Int 54 2 (2005) 264-273
18. Lee Jr HL, Orlowski JA. Adhesive compositions for dental applications. United States Patent Number 4001483, 1973.
19. Ibsen RL, Glace WR. Provisional crown and bridge resin. European Patent Speciation 0032249, 1984.
20. Orlowski JA. Self-curing artificial fingernails. United States Patent Number 4104333, 1973.
21. Patel M.P., and Braden M. Crosslinking and ring opening during polymerization of heterocyclic methacrylates and acrylates. Biomaterials 10 (1989) 277-280
22. Fineman M., and Ross S.D. Linear method for determining monomer reactivity ratios in copolymerization. J Polym Sci 5 2 (1950) 259-265
23. Tüdös K.T., Földes-Berezsnich T., and Turcsanyl B. Analysis of linear methods for determining copolymerization reactivity ratios III. Linear graphic method for evaluating data obtained at high conversion levels. J Macromol Sci Chem A10 (1976) 1513-1540
24. 1H NMR spectroscopy to investigate solvent effects. Macromolecules 22 (2000) 8246-8251
25. Haddleton D.M., Clarkr A., Crossman M.C., Duncalf D.J., Heming A.M., Morsely S.R., et al. Atom transfer radical polymerisation (ATRP) of methyl methacrylate in the presence of radical inhibitors. Chem Commun (1997) 1173-1174
26. Sophie M., Vincent D., and Haddleton D.M. Effect of DMSO used as solvent in copper mediated living radical polymerization. J Polym Sci, Part A: Polym Chem 42 (2004) 6309-6317
27. Wang X.S., Luo N., and Ying S.K. Controlled/living polymerization of MMA promoted by heterogeneous initiation system (EPN-X-CuX-bpy). J Polym Sci, Part A: Polym Chem 37 (1999) 1255-1263
28. Matyjaszewski K., Nakagawa Y., and Jasieczek C.B. Polymerization of n-butyl acrylate by atom transfer radical polymerization. Remarkable effect of ethylene carbonate and other solvents. Macromolecules 31 (1998) 1535-1541