A Raman study of the sulfated cement hydrates: Ettringite and monosulfoaluminate

Journal of Advanced Concrete Technology

Volumn 5, Issue 3, 2007, Pages 299-312

  Renaudin, Guillaume ^a   Segni, Rachid ^a   Mentel, Dorota ^a   Nedelec, Jean Marie ^a   Leroux, Fabrice ^a   Taviot Gueho, Christine ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AFM; CEMENT CHEMISTRY; CEMENT HYDRATES; COPRECIPITATION METHOD; ETTRINGITES; HYDRATED CEMENT; HYDRATED COMPOUNDS; HYDROGEN BOND NETWORKS; IRON SUBSTITUTION; LOCAL ENVIRONMENTS; MICRO RAMAN SPECTROSCOPY; POINT SYMMETRY; RAMAN SPECTRA; RAMAN STUDIES; SAMPLE PREPARATION; SPACE GROUPS; STRUCTURAL PARTS; SULFATE ANIONS; THERMAL BEHAVIORS;

CALCIUM; CEMENTS; COMPLEXATION; HYDRATES; HYDRATION; HYDROGEN; HYDROGEN BONDS; PRECIPITATION (CHEMICAL); RAMAN SCATTERING; RAMAN SPECTROSCOPY;

LAMELLAR STRUCTURES;

EID: 68349089572     PISSN: 13468014     EISSN: None     Source Type: Journal    
DOI: 10.3151/jact.5.299     Document Type: Article

References (43)

1. 2O." Neues Jahrbuch für Mineralogie Monatshefte, 217, 136-144.
2. Bannister, F. A., Hey, M. H. and Bernai, J. D. (1936). "Ettringite from Scawt Hill."'Mineralogical Magazine, 24, 324-328.
3. Bensted, J. (1976a). "Uses of Raman spectroscopy in cement chemistry." Journal of the American Ceramic Society, 59 (3-4), 140-143.
4. Bensted, J. (1976b). "Appraisal of the calcium sulfate water system by Raman spectroscopy." Zement Kalk Gips, 29 (9), 416-418.
5. Bensted, J. (1977). "Raman spectral studies of carbonation phenomena." Cement and Concrete Research, 1 (2), 161-164.
6. Bensted, J. (1999). Colloquium on Techniques for Characterization of Cement Hydration-New and Old Techniques, Society of Chemical Industry Constructions Materials Group, London (1999).
7. 4AF pastes in presence and absence of sulfate." Advances in Applied Ceramics, 1005 (4), 209-216.
8. 3A) in the presence and absence of gypsum - studied by Raman spectroscopy and X-ray diffraction." Journal of Materials Chemistry, 16, 1263-1272.
9. Black, L., Breen, C., Yarwood, J., Garbev, K., Stemmermann, P. and Gasharova, B. (2007). "Structural features of C-S-H (I) and its carbonation in air - A Raman spectroscopic study. Part II: Carbonated phases." Journal of the American Ceramic Society, 90 (3), 908-917.
10. 2O." Zeitschrift fuer Kristallographie, 111, 9-10.
11. Brough, A. R. and Atkinson, A. (2001). "Micro-Raman spectroscopy of thaumasite." Cement and Concrete Research, 31 (3), 421-424.
12. Conjeaud, M. and Boyer, H. (1980). "Some possibilities of Raman microprobe in cement chemistry." Cement and Concrete Research, 10 (1), 61-70.
13. 3+ in ettringite." Zement Kalk Gips, 2, 83-85.
14. Courtois, A., Dusausoy, Y., Lafaille, A. and Protas, J. (1968). "Preliminary study of the crystal structure of ettringite." Comptes rendus de I Académie des Sciences de Paris - Série D, 266 (19), 1911-1913. (in French)
15. Deb, S. K., Manghnani, M. H., Ross, K., Livingston, R. A. and Monteiro, P. J. M. (2003). "Raman scattering and X-ray diffraction study of the thermal decomposition of an ettringite-group crystal." Physics and Chemistry of Minerals, 30, 31-38.
16. El-Turki, A., Ball, R. J. and Allen, G. C. (2007). "The influence of relative humidity on structural and chemical changes during carbonation of hydraulic lime." Cement and Concrete Research, 37 (8), 1233-1240.
17. Falk, M. (1975). In: W. A. Adams Ed. Chemistry and physics of aqueous gas solution. Princeton: Electrochem. Soc. Inc., 19.
18. Garbev, K., Stemmermann, P., Black, L., Breen, C., Yarwood, J. and Gasharova, B. (2007). "Structural features of C-S-H (I) and its carbonation in air - A Raman spectroscopic study. Part I: Fresh phases." Journal of the American Ceramic Society, 90 (3), 900-907.
19. Gastaldi, D., Boccaleri, E., Canonico, F and Bianchi, M. (2007). "The use of Raman spectroscopy as a versatile characterization tool for calcium sulfoaluminate cements: a compositional and hydration study." Journal of Materials Science, 42 (20), 8426-8432.
20. Ghosh, S. N. and Handoo, S. K. (1980). "Infrared and Raman spectral studies in cement and concrete (review)." Cement and Concrete Research, 10 (6), 771-782.
21. Hartman, M. R. and Berliner, R. (2006). "Investigation of the structure of ettringite by time-of-flight neutron powder diffraction techniques." Cement and Concrete Research, 36, 364-370.
22. 3S studied by Raman spectroscopy." Journal of Raman Spectroscopy, 38 (1), 61-67.
23. Jallad, K. N., Santhanam, M., Cohen, M. D. and Ben-Amotz, D. (2001). "Chemical mapping of thaumasite in sulfate-attacked cement mortar using near-infrared Raman imaging microscopy." Cement and Concrete Research, 31(6), 953-958.
24. Kirkpatrick, R. J., Yarger, J. L., McMillan, P. F., Yu, P. and Cong, X. (1997). "Raman spectroscopy of C-S-H, Tobermorite, and Jennite." Advanced Cement Based Materials, 5 (3-4), 93-99.
25. Lovy, D. (1996). Program SPECTRAW, Version 1.40, Département de Chimie Physique, University of Geneva, Switzerland.
26. Ma, B., Gao, X., Byars, E. A. and Zhou, Q. (2006). "Thaumasite formation in a tunnel of Bapanxia Dam in Western China." Cement and Concrete Research, 36 (4), 716-722.
27. Martinez-Ramirez, S., Sanchez-Cortes, S., Garcia-Ramos, J. V., Domingo, C., Fortes, C. And Blanco-Varela, M. T. (2003). "Micro-Raman spectroscopy applied to depth profiles of carbonates formed in lime mortar." Cement and Concrete Research, 33 (12), 2063-2068.
28. Martinez-Ramirez, S., Frias, M. and Domingo, C. (2006). "Micro-Raman spectroscopy in white portland cement hydration: long-term study at room temperature." Journal of Raman Spectroscopy, 37 (5), 555-561.
29. Moore, A. E. and Taylor, H. F. W. (1968). "Crystal structure of ettringite." Nature, 218, 1048-1049.
30. Moore, A. E. and Taylor, H. F. W. (1970). "Crystal structure of ettringite." Acta Crystallographica, B26, 386-393.
31. Myneny, S. C., Traina, S. J., Waychunas, G. A. and Logan, T. J. (1998). "Vibrational spectroscopy of functional group chemistry and arsenate coordination in ettringite." Geochimica and Cosmchimica Acta, 62 (21-22), 3499-3514.
32. Newman, S. P., Clifford, S. J., Coveney, P. V., Gupta, V., Blanchard, J. D., Serafin, F., Ben-Amotz, D. and Diamond, S. (2005). "Anomalous fluorescence in near-infrared Raman spectroscopy of cementitious materials." Cement and Concrete Research, 35 (8), 1620-1628.
33. Pöllmann, H., Kuzel, H.-J. and Wenad, R. (1989). "Compounds with ettringite structure." Neues Jahrbuch fur Mineralogie Monatshefte, 160 (2), 133-158.
34. Potgieter-Vermaak, S. S., Potgieter, J. H. and Van Grieken R. (2006). "The application of Raman spectrometry to investigate and characterize cement, Part I: A review." Cement and Concrete Research, 36(4), 656-662.
35. Poupard, O., L'Hostis, V., Catinaud, S. and Petre-Lazar, I. (2006). "Corrosion damage diagnosis of a reinforced concrete beam after 40 years natural exposure in marine environment." Cement and Concrete Research, 36(3), 504-520.
36. Prasad, P. S. R., Pradhan, A. and Gowd, T. N. (2001). "In situ micro-Raman investigation of dehydration mechanism in natural gypsum." Current Science, 80 (9), 1203-1207.
37. 4." Journal of Applied Crystallography, 29, 42-47.
38. 2O." Cement and Concrete Research, 30 (2), 307-314.
39. Rodriguez-Carvajal, J. (2005). PROGRAM FullProf.2k, version 3.20, Laboratoire Léon Brillouin (CEACNRS), France, (FullProf.2k manual available on http://www-llb.cea.fr/fullweb/fp2k/fp2k-divers.htm).
40. Sahu, S., Exline, D. L. and Nelson, M. P. (2002). "Identification of thaumasite in concrete by Raman chemical imaging." Cement and Concrete Composites, 24 (3-4), 347-350.
41. Shimada, Y. and Young, J. F. (2001). "Structural changes during thermal dehydration of ettringite." Advances in Cement Research, 13 (2), 77-81.
42. th International Congress on the Chemistry of Cement, Montreal 8-13 July 2007.
43. Tarrida, M., Madon, M., Le Rolland, B. and Colombet, P (1995). "An in-situ Raman spectroscopy study of the hydration of tricalcium silicate." Advanced Cement Based Materials, 2 (1), 15-20.