Synthesis, structural characterization and thermal analysis of the cobalt(II) oxalate obtained through the reaction of 1,2-ethanediol with Co(NO3)2 • 6H2O

Journal of Thermal Analysis and Calorimetry

Volumn 96, Issue 3, 2009, Pages 979-986

  Birzescu M ^a   Niculescu, M ^a   Dumitru, Raluca ^a   Carp, Oana ^b   Segal, E ^c  

^a POLITEHNICA UNIVERSITY OF TIMISOARA   (Romania)

^b INSTITUTE OF PHYSICAL CHEMISTRY   (Romania)

^c UNIVERSITY OF BUCHAREST   (Romania)

Author keywords

1,2 Ethanediol; Cobalt(II) oxalate; Nitrate; Nonstoichiometric mixed oxide; Normal spinel

Indexed keywords

1,2-ETHANEDIOL; CLASSICAL METHODS; COBALT NITRATES; COORDINATION COMPOUNDS; DOUBLE-BRIDGE; ETHANEDIOL; HIGH SPINS; HOMOPOLYNUCLEAR COORDINATION COMPOUND; NONSTOICHIOMETRIC; NONSTOICHIOMETRIC MIXED OXIDE; NORMAL SPINEL; OXALATE ANIONS; STRUCTURAL CHARACTERIZATION; TETRADENTATE; THERMAL ANALYSIS; THERMAL DECOMPOSITIONS;

COBALT; COORDINATION REACTIONS; ETHYLENE GLYCOL; NITRIC ACID; PYROLYSIS; REDOX REACTIONS; SYNTHESIS (CHEMICAL); THERMOANALYSIS;

COBALT COMPOUNDS;

EID: 68349089093     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-009-0054-z     Document Type: Article

References (51)

1. M Brezeanu E Safarica E Segal L Patron T Robu 1982 An analysis of thermal-decomposition of coordination polynuclear compounds in Fe(III), Mn(II), Ni(II) systems Rev Roum Chim 24 137 40
2. M Brezeanu E Tatu S Bocai O Brezeanu E Segal L Patron 1984 Non-isothermal decomposition kinetics of polynuclear coordination-compounds Thermochim Acta 78 351 5
3. I Ilie M Brezeanu L Patron E Segal G Filoti 1987 Synthesis of nickel ferrite from polynuclear coordination-compounds. 1. Study of the dry ferritization process Rev Roum Chim 32 1109 15
4. M Brezeanu L Patron O Carp M Andruh N Stanica 1991 Coordination-compounds as raw-materials for spinelic oxides Rev Roum Chim 36 545 50
5. M Brezeanu L Patron E Cristureanu O Carp A Antoniu M Andruch 1993 Coordination-compounds as precursors for manganese ferrite and zinc ferrite. 4 Rev Roum Chim 38 1291 6
6. Brezeanu M, Dinu Gh, Patron L, Segal E, Mincu V. Brevet Nr. 77973. Romania; 1981.
7. Dinu Gh, Brezeanu M, Patron L, Segal E, Mincu V. Brevet Nr. 77972. Romania; 1981.
8. VA Logvinenko 1990 Thermoanalytical approach to the study of the kinetic and thermodynamic stability of coordination-compounds and clathrates J Therm Anal Calorim 36 1973 80
9. E Ingier-Stocka 1989 Thermal decomposition reactions of amminecobalt(III)complexes J Therm Anal Calorim 33 487 93
10. M Lalia-Kantouri GA Katsoulos CC Hadgi-Kostas AD Magri 1989 Kinetic-analysis of thermogravimetric data on some nickel(II) N-alkyldithiocarbamates J Therm Anal Calorim 35 2411 22
11. TV Albu S Plostinaru L Patron E Segal 1997 Thermal behaviour and non-isothermal decomposition kinetics of some Nd(III) coordination compounds J Therm Anal Calorim 50 425 430
12. O Carp E Segal M Brezeanu R Barjega N Stanica 1997 Nonconventional methods for obtaining hexaferrites. 1. Lead hexaferrite J Therm Anal Calorim 50 125 35
13. V Pocol L Patron O Carp M Brezeanu E Segal N Stanica 1999 Some polynuclear coordination compounds precursors of chromites-synthesis, physicochemical characterization and thermal stability J Therm Anal Calorim 55 143 54
14. O Carp R Barjega E Segal M Brezeanu 1998 Nonconventional methods for obtaining hexaferrites-II. Barium hexaferrite Thermochim Acta 318 57 62
15. Vaszilcsin N, Birzescu M, Stefanescu M, Niculescu M. Cathodes of copper skeleton from Cu(II)-Al(III)-glyoxylates generated in situ. Bulg Chem Commun. 1996/1997;29:293-300.
16. 2 (M:Ni(II),Co(II)). Thermal behaviour of the obtained complex intermediates (I) Chem Bull 'Politehnica' Univ Timisoara 43 57 259 74
17. 2 (M=Co,Ni). Characterization of the obtained complex intermediates Chem Bull 'Politehnica' Univ Timisoara 43 145 53
18. 2O Stud Univ Babes-Bolyai Chemia XLIV 1-2 275 86
19. 2O J Therm Anal Calorim 63 181 89
20. 4. Thermochim Acta. doi: 10.1016/j.tca.2008.03. 011.
21. M Niculescu A Kellenberger T Maghet R Dumitru M Birzescu N Vaszilcsin 2002 Molecular and crystalline structure of M(II)-polynuclear coordination compounds with oxidation products of diols as ligands Chem Bull 'Politehnica' Univ Timisoara 47 61 1 6
22. Niculescu M, Vaszilcsin N, Budrugeac P, Birzescu M. Structural studies about Cu(II)-polynuclear coordination compounds with oxidation products of 1,3-propanediol as ligands. I. Coordination compound with 3-hydroxy-propionate. In: Proceedings of the 5th 'international MEEMB 2002' symposium of Roumanian Academy. Timisoara: Publishing House Eurobit; 2002, p. 263-270.
23. M Niculescu N Vaszilcsin CM Davidescu P Negrea M Birzescu P Budrugeac 2003 Structural investigation and thermal analysis of the coordination compound obtained through the reaction of 1,3-propanediol with Co(II)nitrate Rev Roum Chim 48 997 1006
24. M Stefanescu V Sasca M Birzescu 2003 Thermal behaviour of the homopolynuclear glyoxylate complex combinations with Cu(II) and Cr(III) J Therm Anal Calorim 72 515 24
25. Birzescu M. Complexes combinations with ethyleneglycol and their oxidation products. Ph.D. thesis, Bucharest University; 1998.
26. 2O. J Therm Anal Calorim. 2008;94:297-303.
27. Birzescu M, Cristea M, Stefanescu M, Constantin Gh. Brevet Nr. 102501. Romania; 1990.
28. Radoi I, Birzescu M, Golumbioschi Fr, Ferencz A, Stefanescu M. Preparation of anodes with electrocatalytically active films of metallic complexes used in water electrolysis. Rev Chim (Bucharest). 1985;36:832-5.
29. 4 powders via hydrothermal treatment followed by decomposition J Central South Univ (Sci Technol) 37 6 1103 6
30. 4, and mixed Co/CoO nanoparticules Chem Mater 11 2702 8
31. C-B Wang C-W Tang S-J Gau S-H Chien 2005 Effect of the surface area of cobaltic oxide on carbon monoxide oxidation Catal Lett 101 1-2 59 63
32. B Malecka E Drozdz-Cisela A Malecki 2002 Non-isothermal studies on mechanism and kinetics of thermal decomposition of cobalt(II) oxalate dihydrate J Therm Anal Calorim 68 819 31
33. 2] Acta Chem Scand 27 3513 22
34. K Nakamoto Y Morimoto AE Martell 1961 Infrared spectra of aqueous solutions. I. Metal chelate compounds of amino acids J Am Chem Soc 83 4528 32
35. -1. New York: Wiley Interscience; 1968.
36. P Spacu L Patron S Plostinaru A Contescu N Stanica 1989 Coordination-compounds as raw-materials for mixed oxides. 5. Mixed coordination-compounds of lanthanides and Co(II), Ni(II) or Fe(III) with gluconic acid Rev Roum Chim 34 1275 80
37. Diefallah El HM. Kinetic analysis of thermal decomposition reactions: Part VI. Thermal decomposition of manganese(II) acetate tetrahydrate. Thermochim Acta. 1992;202:1-16.
38. Deb N, Gogoi PK, Dass NN. Synthesis and thermal decomposition of cobalt(II) bis(oxalato)cobaltate(II)-tetrahydrate. J Therm Anal Calorim. 1989;35:27-34.
39. Deb N. Cadmium(II)bis(oxalato)cobaltate(II)-pentahydrate. J Therm Anal Calorim. 2004;75:837-46.
40. 2O. J Therm Anal Calorim. 2001;65:881-9
41. Randhawa BS, Gandotra K. A comparative study on the thermal decomposition of some transition metal carboxylates J Therm Anal Calorim. 2006;85:417-24.
42. Randhawa BS, Kaur M, A comparative study on the thermal decomposition of some transition metal maleates and fumarates. J Therm Anal Calorim. 2007;89:251-5.
43. Luisetto I, Pepe F, Bemporad E. Preparation and characterization of nano cobalt oxide. J Nanopart Res. 2008;10:59-67.
44. Morita Y, Poulsena J, Sakaia K, Motohashia T, Fujiib T, Terasakib I, et al. Oxygen nonstoichiometry and cobalt valence in misfit-layered cobalt oxides. J Solid State Chem. 2004;177:3149-55.
45. Mohamed AM, Galwey AK, Halawy SA. A comparative study of the thermal reactivities of some transition metal oxalates in selected atmospheres. Thermochim Acta. 2005;429:57-72.
46. King WJ, Tseung ACC. Reduction of oxygen on nickel-cobalt oxides. I. Influence of composition and preparation method on the activity of nickel-cobalt oxides. Electrochim Acta. 1974;19:485-91.
47. Wendlandt WW, Simmons EL. The thermal decomposition of metal complexes-XVI. Potassium tris(oxalato)cobaltate(III)-trihydrate. J Inorg Nucl Chem. 1965;27:2317-23.
48. Gabal, MA, El-Bellihi AA, Ata-Allah SS. Effect of calcination temperature on Co(II) oxalate dihydrate-iron(II) oxalate dihydrate mixture: DTA-TG, XRD, Mössbauer, FT-IR and SEM studies (Part II). Mater Chem Phys. 2003;81:84-92.
49. Stocka EI, Grabowska A. Thermal analysis of cobalt(II) salts with some carboxylic acids. J Therm Anal Calorim. 1998;54:115-23.
50. Dolimore D, Griffiths DL. Differential thermal analysis study of various oxalates in oxygen and nitrogen. J Therm Anal Calorim. 1970;2:229-50.
51. Belous AG, Yanchevskii OZ, Kramarenko AV. Synthesis of nanosize particles of cobalt and nickel oxides from solutions. Russian J Appl Chem. 2006;79:345-50.