Automated SEM-EDS (QEMSCAN®) mineral analysis in forensic soil investigations: Testing instrumental reproducibility

Criminal and Environmental Soil Forensics

Volumn , Issue , 2009, Pages 411-430

  Pirrie, Duncan ^a,b   Power, Matthew R ^b   Rollinson, Gavyn K ^c   Wiltshire, Patricia E J ^d   Newberry, Julia ^e   Campbell, Holly E ^a  

^a HELFORD GEOSCIENCE LLP   (United Kingdom)

^b Intellection UK Ltd   (United Kingdom)

^c UNIVERSITY OF EXETER   (United Kingdom)

^d UNIVERSITY OF ABERDEEN   (United Kingdom)

^e UNIVERSITY OF GLOUCESTERSHIRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 68249132342     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1007/978-1-4020-9204-6_26     Document Type: Chapter

References (34)

1. ASTM (2002). Standard guide for gunshot residue analysis by scanning electron microscopy/energy dispersive spectroscopy. Annual Book of ASTM Standards 2002:528-530.
2. Benvie B (2007). Mineralogical imaging of kimberlites using SEM-based techniques. Minerals Engineering 20:435-443.
3. Brown AG (2006). The use of forensic botany and geology in war crimes investigations in NE Bosnia. Forensic Science International 163:204-210.
4. Brown AG, Smith A and Elmhurst O (2002). The combined use of pollen and soil analyses in a search and subsequent murder investigation. Journal of Forensic Sciences 47:614-618.
5. Brozek-Mucha Z and Jankowicz A (2001). Evaluation of the possibility of differentiation between various types of ammunition by means of GSR examination with SEM-EDX method. Forensic Science International 123:39-47.
6. Bull PA and Morgan RM (2006). Sediment fingerprints. Science and Justice 46:107-124.
7. Camm GS, Butcher AR, Pirrie D, Hughes PK and Glass HJ (2003). Secondary mineral phases associated with a historic arsenic calciner identified using automated scanning electron microscopy: A pilot study from Cornwall, UK. Minerals Engineering 16:1269-1277.
8. Dawson LA, Towers W, Mayes RW, Craig J, Väisänen RK and Waterhouse EC (2004). The use of plant hydrocarbon signatures in characterising soil organic matter. In: Forensic Geoscience: Principles, Techniques and Applications (Eds. K Pye and DJ Croft), pp 269-276. The Geological Society of London Special Publication 232, London.
9. Goodall WR and Scales PJ (2007). An overview of the advantages and disadvantages of the determination of gold mineralogy by automated mineralogy. Minerals Engineering 20:506-517.
10. Knight RD, Klassen RA and Hunt P (2002). Mineralogy of fine-grained sediment by energy-dispersive spectrometry (EDS) image analysis - A methodology. Environmental Geology 42:32-40.
11. Lotter NO, Kowal DL, Tuzun MA, Whittaker PJ and Kormos L (2003). Sampling and flotation testing of Sudbury Basin drill core for process mineralogy modelling. Minerals Engineering 16:857-864.
12. Martin RS, Mather TA, Pyle DM, Power M, Allen AG, Aiuppa A, Horwell CJ and Ward CPJ (in press). Composition resolved size distributions of volcanic aerosols in the Mt Etna plumes. Journal of Geophysical Research.
13. Marumo Y, Nagatsuka S and Oba Y (1986). Clay mineralogical analysis using the <0.05 mm fraction for forensic science investigation - its application to volcanic ash soils and yellow-brown forest soils. Journal of Forensic Sciences 31:92-105.
14. McCrone WC (1992). Forensic soil examination. Microscope 40:109-121.
15. McKinley J and Ruffell A (2007). Contemporaneous spatial sampling at scenes of crime: Advantages and disadvantages. Forensic Science International 172:196-202.
16. McVicar MJ and Graves WJ (1997). The forensic comparison of soils by automated scanning electron microscopy. Journal of the Canadian Society of Forensic Scientists 30:241-261.
17. Mildenhall DC, Wiltshire PEJ and Bryant VM (2006). Forensic palynology: why do it and how it works. Forensic Science International 163:163-172.
18. Morgan RM and Bull PA (2007). Forensic geoscience and crime detection. Minerva Medicolegale 127:73-89.
19. Morgan RM, Wiltshire PEJ, Parker A and Bull PA (2006). The role of geoscience in wildlife crime detection. Forensic Science International 162:152-162.
20. Morgan RM, Little M, Gibson A, Hicks L, Dunkerley S and Bull PA (in press). The preservation of quartz grain surface textures following vehicle fire and their use in forensic enquiry. Science and Justice.
21. Pirrie D, Power MR, Rollinson G, Camm GS, Hughes SH, Butcher AR and Hughes P (2003). The spatial distribution and source of arsenic, copper, tin and zinc within the surface sediments of the Fal Estuary, Cornwall, UK. Sedimentology 50:579-595.
22. Pirrie D, Butcher AR, Power MR, Gottlieb P and Miller GL (2004). Rapid quantitative mineral and phase analysis using automated scanning electron microscopy (QEMSCAN®); potential applications in forensic geoscience. In: Forensic Geoscience: Principles, Techniques and Applications (Eds. K Pye and DJ Croft), pp 123-136. The Geological Society of London Special Publication 232, London.
23. Pye K (2004). Forensic examination of sediments, soils, dusts and rocks using scanning electron microscopy and X-ray chemical microanalysis. In: Forensic Geoscience: Principles, Techniques and Applications (Eds. K Pye and DJ Croft), pp 103-122. The Geological Society of London Special Publication 232, London.
24. Pye K and Croft DJ (2007). Forensic analysis of soil and sediment traces by scanning electron microscopy and energy-dispersive X-ray analysis: An experimental investigation. Forensic Science International 165:52-63.
25. Pye K, Blott SJ and Wray DS (2006a). Elemental analysis of soil samples for forensic purposes by inductively coupled plasma spectrometry - precision considerations. Forensic Science International 160:178-192.
26. Pye K, Blott SJ, Croft DJ and Carter JF (2006b). Forensic comparison of soil samples: Assessment of small-scale spatial variability in elemental composition, carbon and nitrogen isotope ratios, colour, and particle size distribution. Forensic Science International 163:59-80.
27. Rawlins BG, Kemp SJ, Hodgkinson EH, Riding JB, Vane CH, Poulton C and Freeborough K (2006). Potential and pitfalls in establishing the provenance of earth-related samples in forensic investigations. Journal of Forensic Sciences 51:832-845.
28. Reed SJB (2005). Electron Microprobe Analysis and Scanning Electron Microscopy in Geology. Cambridge University Press, Cambridge.
29. Ruffell A and Wiltshire PEJ (2004). Conjunctive use of quantitative and qualitative X-ray diffraction analysis of soils and rocks for forensic analysis. Forensic Science International 145:13-23.
30. Sugita R and Marumo Y (1996). Validity of colour examination for forensic soil identification. Forensic Science International 83:201-210.
31. Sugita R and Marumo Y (2001). Screening of soil evidence by a combination of simple techniques: validity of particle size distribution. Forensic Science International 122:155-158.
32. Wiltshire PEJ (2006). Consideration of some taphonomic variables of relevance to forensic palynological investigations in the United Kingdom. Forensic Science International 163:173-182.
33. Xiao Z and Laplante AR (2004). Characterizing and recovering the platinum group minerals - A review. Minerals Engineering 17:961-979.
34. Xie RK, Seip HM, Leinum JR, Winje T and Xiao JS (2005). Chemical characterization of individual particles (PM10) from ambient air in Guiyang City, China. Science of the Total Environment 343:261-272.